Index
A
Absolute integral quantum yield, 84, 85
Absolute quantum yield, 83, 84
Absolute quantum yield of luminescence, 101
Absorbed radiation density, 83, 96
Absorprion cross-section, 145
Absorption, 1, 79–81, 84, 86, 88, 97, 102, 132,
140
Absorption coefficient, 97, 98, 133
Absorption cross-section, 85, 96, 98, 147
Activation energy, 26–28
Adiabatic approximation, 37, 41, 43, 44, 47,
59, 60, 70, 73, 75, 132, 133, 158, 167
Adiabatic principle, 158, 167
Adiabatic representation, 179
Adiabatic term, 44, 48, 59, 73, 75
Arrhenius equation, 24, 26–28
Attractive term, 57, 58
Average relative velocity, 25, 40, 154
B
Bimolecular, 12, 25, 29, 34, 62, 269, 278
Binding energies, 205, 214, 215, 221, 224,
228, 235, 240, 244, 246, 247, 250, 253
Boltzmann constant, 14
Branching ratio (Br.r.), 220, 222, 228, 237
C
Capture cross-section, 62
Chemical equilibrium, 15
Chemiluminescence, 2, 3, 202, 265
Chemiluminescence rate constant, 269–272,
278
CINAT cross-sections, 167, 168, 184
CINAT rate constants, 184, 189
Collision complex, 10, 30, 166, 189
Collision-induced, 82, 83, 169, 189, 190, 271,
273, 278
Collision-induced intramolecular energy
transfer, 162
Collision-Induced Nonadiabatic Transition
(CINAT), 2, 57, 81, 82, 153, 167, 168,
174–176, 178, 186, 189
Collision-induced optical transition, 266, 267
Collision-induced predissociation, 81, 82, 174,
189
Convolution quantum yield, 85, 143
Coriolis interaction, 89
D
De Broglie wavelength, 41, 105
Degeneracies, 17, 18, 20, 22, 23, 43, 97, 98
Detailed balance principle, 18, 37, 43, 157,
159, 190, 276
Diabatic representation, 178
Diabatic term, 75
Differential cross-section, 38
Differential reaction cross-section, 39
Dispersion interaction, 54, 58, 60, 178, 240,
251
Dissociation, 1, 81
Dissociation energy, 10, 14, 81, 94, 240, 271
Dissociation of a polyatomic molecule, 141
Dissociation of a triatomic molecule, 66, 70
Distribution functions, 39, 40
© Springer Nature Switzerland AG 2021
A. Pravilov, Gas-Phase Photoprocesses, Springer Series in Chemical Physics 123,
https://doi.org/10.1007/978-3-030-65570-9
289
A
Absolute integral quantum yield, 84, 85
Absolute quantum yield, 83, 84
Absolute quantum yield of luminescence, 101
Absorbed radiation density, 83, 96
Absorprion cross-section, 145
Absorption, 1, 79–81, 84, 86, 88, 97, 102, 132,
140
Absorption coefficient, 97, 98, 133
Absorption cross-section, 85, 96, 98, 147
Activation energy, 26–28
Adiabatic approximation, 37, 41, 43, 44, 47,
59, 60, 70, 73, 75, 132, 133, 158, 167
Adiabatic principle, 158, 167
Adiabatic representation, 179
Adiabatic term, 44, 48, 59, 73, 75
Arrhenius equation, 24, 26–28
Attractive term, 57, 58
Average relative velocity, 25, 40, 154
B
Bimolecular, 12, 25, 29, 34, 62, 269, 278
Binding energies, 205, 214, 215, 221, 224,
228, 235, 240, 244, 246, 247, 250, 253
Boltzmann constant, 14
Branching ratio (Br.r.), 220, 222, 228, 237
C
Capture cross-section, 62
Chemical equilibrium, 15
Chemiluminescence, 2, 3, 202, 265
Chemiluminescence rate constant, 269–272,
278
CINAT cross-sections, 167, 168, 184
CINAT rate constants, 184, 189
Collision complex, 10, 30, 166, 189
Collision-induced, 82, 83, 169, 189, 190, 271,
273, 278
Collision-induced intramolecular energy
transfer, 162
Collision-Induced Nonadiabatic Transition
(CINAT), 2, 57, 81, 82, 153, 167, 168,
174–176, 178, 186, 189
Collision-induced optical transition, 266, 267
Collision-induced predissociation, 81, 82, 174,
189
Convolution quantum yield, 85, 143
Coriolis interaction, 89
D
De Broglie wavelength, 41, 105
Degeneracies, 17, 18, 20, 22, 23, 43, 97, 98
Detailed balance principle, 18, 37, 43, 157,
159, 190, 276
Diabatic representation, 178
Diabatic term, 75
Differential cross-section, 38
Differential reaction cross-section, 39
Dispersion interaction, 54, 58, 60, 178, 240,
251
Dissociation, 1, 81
Dissociation energy, 10, 14, 81, 94, 240, 271
Dissociation of a polyatomic molecule, 141
Dissociation of a triatomic molecule, 66, 70
Distribution functions, 39, 40
© Springer Nature Switzerland AG 2021
A. Pravilov, Gas-Phase Photoprocesses, Springer Series in Chemical Physics 123,
https://doi.org/10.1007/978-3-030-65570-9
289