370
Table 12.1 Data summary of the instrumental condition and validation of the applied methodology
Element Isotope
ORS
mode
Integration
time
(s)
Linear
range
(μg/L)
Slope Intercept R
LOD
(μg/L)
LOQ
(μg/L)
Li
7
Normal 0.1
0.05–10 0.045 0.023
0.9997 0.042 0.140
Be
9
Normal 0.1
0.05–10 0.010 0.166
0.9960 0.012 0.040
B
11
Normal 0.1
5–50
0.295 −7.648
0.9989 0.98
3.273
Na
23
Normal 0.1
30–1000 2.125 391.2
0.9992 8.12
27.12
Mg
24
Normal 0.1
20–1000 1240 13785
0.9995 5.77
19.27
Al
27
Normal 0.1
5–100
0.882 19.36
0.9990 1.22
4.075
P
31
Helium 0.5
20–1000 13455 12963
0.9991 5.96
19.91
K
39
Normal 0.1
30–1000 35964 40552
0.9995 10.2
34.07
Ca
42
Normal 0.1
10–1000 1796 3995
0.9991 2.34
7.816
Ti
48
Helium 0.5
0.5–10
1.36
5.998
0.9996 0.12
0.401
V
51
Normal 0.1
0,5–10
0.022 0.799
0.9999 0.096 0.321
Cr
53
Helium 0.5
0.055–10 0.024 −0.051
0.9991 0.0063 0.021
Mn
55
Normal 0.1
0.2–10
1.754 −9.321
0.9993 0.074 0.247
Fe
56
Helium 0.5
0.1–100 0.55
1.90
1.0000 0.017 0.057
Co
59
Normal 0.1
0.01–10 1.528 −0.724
0.9996 0.0031 0.010
Ni
60
Normal 0.1
0.015–50 0.042 1.33
0.9993 0.0044 0.015
Cu
63
Helium 0.5
0.5–10
0.66
10.24
0.9991 0.199 0.665
Zn
64
Helium 0.5
0.01–10 0.322 7.82
0.9995 0.0017 0.006
Ga
69
Normal 0.1
0.05–10 0.037 −0.0059 0.9994 0.013 0.043
Ge
72
Normal 0.1
0.015–10 0.0014 0.0055
0.9990 0.0046 0.015
As
75
Helium 0.5
0.005–10 0.010 0.0022
0.9993 0.0011 0.004
Se
77
Helium 0.5
0.01–10 0.0069 −0.0037 0.9997 0.0019 0.006
Rb
85
Normal 0.1
0,5–10
1.150 2.483
1.0000 0.10
0.334
Sr
88
Normal 0.1
2–100
1.680 10.27
0.9995 0.77
2.572
Mo
95
Normal 0.1
0.01–5
0.0079 0.0022
0.9991 0.0033 0.011
Ag
107
Normal 0.1
0.05–5
0.0037 −0.0059 0.9995 0.012 0.040
Cd
111
Normal 0.1
0.01–5
0.021 0.0025
1.0000 0.0044 0.015
Sn
118
Normal 0.1
0.01–5
0.0011 0.00069 0.9994 0.0012 0.004
Sb
121
Helium 0.5
0.1–10
0.038 10.47
0.9998 0.054 0.180
Cs
133
Normal 0.1
0.5–5
0.144 18.59
0.9991 0.13
0.434
Ba
137
Normal 0.1
1–10
0.058 −0.0063 0.9994 0.29
0.969
Tl
205
Normal 0.1
0.2–5
2.019 −5.94
1.0000 0.062 0.207
Pb
206/207/208 Normal 0.1
0.1–10
0.023 0.0647
0.9991 0.019 0.063
Bi
209
Helium 0.5
0.1–5
0.0092 −0.1046 0.9992 0.54
1.804
ORS octopole reaction system (normal, Ar gas is applied)
L. Fan et al.
Table 12.1 Data summary of the instrumental condition and validation of the applied methodology
Element Isotope
ORS
mode
Integration
time
(s)
Linear
range
(μg/L)
Slope Intercept R
LOD
(μg/L)
LOQ
(μg/L)
Li
7
Normal 0.1
0.05–10 0.045 0.023
0.9997 0.042 0.140
Be
9
Normal 0.1
0.05–10 0.010 0.166
0.9960 0.012 0.040
B
11
Normal 0.1
5–50
0.295 −7.648
0.9989 0.98
3.273
Na
23
Normal 0.1
30–1000 2.125 391.2
0.9992 8.12
27.12
Mg
24
Normal 0.1
20–1000 1240 13785
0.9995 5.77
19.27
Al
27
Normal 0.1
5–100
0.882 19.36
0.9990 1.22
4.075
P
31
Helium 0.5
20–1000 13455 12963
0.9991 5.96
19.91
K
39
Normal 0.1
30–1000 35964 40552
0.9995 10.2
34.07
Ca
42
Normal 0.1
10–1000 1796 3995
0.9991 2.34
7.816
Ti
48
Helium 0.5
0.5–10
1.36
5.998
0.9996 0.12
0.401
V
51
Normal 0.1
0,5–10
0.022 0.799
0.9999 0.096 0.321
Cr
53
Helium 0.5
0.055–10 0.024 −0.051
0.9991 0.0063 0.021
Mn
55
Normal 0.1
0.2–10
1.754 −9.321
0.9993 0.074 0.247
Fe
56
Helium 0.5
0.1–100 0.55
1.90
1.0000 0.017 0.057
Co
59
Normal 0.1
0.01–10 1.528 −0.724
0.9996 0.0031 0.010
Ni
60
Normal 0.1
0.015–50 0.042 1.33
0.9993 0.0044 0.015
Cu
63
Helium 0.5
0.5–10
0.66
10.24
0.9991 0.199 0.665
Zn
64
Helium 0.5
0.01–10 0.322 7.82
0.9995 0.0017 0.006
Ga
69
Normal 0.1
0.05–10 0.037 −0.0059 0.9994 0.013 0.043
Ge
72
Normal 0.1
0.015–10 0.0014 0.0055
0.9990 0.0046 0.015
As
75
Helium 0.5
0.005–10 0.010 0.0022
0.9993 0.0011 0.004
Se
77
Helium 0.5
0.01–10 0.0069 −0.0037 0.9997 0.0019 0.006
Rb
85
Normal 0.1
0,5–10
1.150 2.483
1.0000 0.10
0.334
Sr
88
Normal 0.1
2–100
1.680 10.27
0.9995 0.77
2.572
Mo
95
Normal 0.1
0.01–5
0.0079 0.0022
0.9991 0.0033 0.011
Ag
107
Normal 0.1
0.05–5
0.0037 −0.0059 0.9995 0.012 0.040
Cd
111
Normal 0.1
0.01–5
0.021 0.0025
1.0000 0.0044 0.015
Sn
118
Normal 0.1
0.01–5
0.0011 0.00069 0.9994 0.0012 0.004
Sb
121
Helium 0.5
0.1–10
0.038 10.47
0.9998 0.054 0.180
Cs
133
Normal 0.1
0.5–5
0.144 18.59
0.9991 0.13
0.434
Ba
137
Normal 0.1
1–10
0.058 −0.0063 0.9994 0.29
0.969
Tl
205
Normal 0.1
0.2–5
2.019 −5.94
1.0000 0.062 0.207
Pb
206/207/208 Normal 0.1
0.1–10
0.023 0.0647
0.9991 0.019 0.063
Bi
209
Helium 0.5
0.1–5
0.0092 −0.1046 0.9992 0.54
1.804
ORS octopole reaction system (normal, Ar gas is applied)
L. Fan et al.