191
4. Lv N, Liu Y, Xiong C, Liu Z, Zhang Y (2017) Cobalt-catalyzed oxidant-free spirocycle synthesis by liberation of hydrogen. Org Lett 19:4640–4643
5. Yang D, Zhu Y, Yang N, Jiang Q, Liu R (2016) One-step synthesis of substituted Benzofurans
fromortho- alkenylphenols via palladium-catalyzed C-H functionalization. Adv Synth Catal
358:1731–1735
6. Manikandan R, Madasamy P, Jeganmohan M (2016) Ruthenium-catalyzed ortho alkenylation
of aromatics with alkenes at room temperature with hydrogen evolution. ACS Catal 6:230–234
7. Li WH, Wu L, Li SS, Liu CF, Zhang GT, Dong L (2016) Rhodium-catalyzed hydrogenreleasing ortho-alkenylation of 7-azaindoles. Chemistry 22:17926–17929
8. Chen C, Chen X, Zhao H, Jiang H, Zhang M (2017) Direct access to nitrogen bi-heteroarenes
via iridium-catalyzed hydrogen-evolution cross-coupling reaction. Org Lett 19:3390–3393
9. Zhou A-X, Mao L-L, Wang G-W, Yang S-D (2014) A unique copper-catalyzed cross-coupling
reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles.
Chem Commun 50:8529–8532
10. Meng QY, Zhong JJ, Liu Q, Gao XW, Zhang HH, Lei T, Li ZJ, Feng K, Chen B, Tung CH,
Wu LZ (2013) A cascade cross-coupling hydrogen evolution reaction by visible light catalysis.
J Am Chem Soc 135:19052–19055
11. Zhong JJ, Meng QY, Liu B, Li XB, Gao XW, Lei T, Wu CJ, Li ZJ, Tung CH, Wu LZ (2014)
Cross-coupling hydrogen evolution reaction in homogeneous solution without noble metals.
Org Lett 16:1988–1991
12. Gao X-W, Meng Q-Y, Li J-X, Zhong J-J, Lei T, Li X-B, Tung C-H, Wu L-Z (2015) Visible light
catalysis assisted site-specific functionalization of amino acid derivatives by C–H bond activation without oxidant: cross-coupling hydrogen evolution reaction. ACS Catal 5:2391–2396
13. Xiang M, Meng QY, Li JX, Zheng YW, Ye C, Li ZJ, Chen B, Tung CH, Wu LZ (2015)
Activation of CH bonds through oxidant-free photoredox catalysis: cross-coupling hydrogenevolution transformation of isochromans and beta-keto esters. Chem-Eur J 21:18080–18084
14. Wu C-J, Meng Q-Y, Lei T, Zhong J-J, Liu W-Q, Zhao L-M, Li Z-J, Chen B, Tung C-H, Wu L-Z
(2016) An oxidant-free strategy for indole synthesis via intramolecular C–C bond construction under visible light irradiation: cross-coupling hydrogen evolution reaction. ACS Catal
6:4635–4639
15. Zhang G, Liu C, Yi H, Meng Q, Bian C, Chen H, Jian JX, Wu LZ, Lei A (2015) External
oxidant-free oxidative cross-coupling: a Photoredox cobalt-catalyzed aromatic C-H thiolation
for constructing C-S bonds. J Am Chem Soc 137:9273–9280
16. Zhang G, Zhang L, Yi H, Luo Y, Qi X, Tung C-H, Wu L-Z, Lei A (2016) Visible-light induced
oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic
acids. Chem Commun 52:10407–10410
17. Downing RS, Kunkeler PJ, van Bekkum H (1997) Catalytic syntheses of aromatic amines.
Catal Today 37:121–136
18. Liu Y, Lu Y, Prashad M, Repič O, Blacklock TJ (2005) A practical and chemoselective reduction of nitroarenes to anilines using activated iron. Adv Synth Catal 347:217–219
19. Schmidt RJ (2005) Industrial catalytic processes—phenol production. Appl Catal A Gen
280:89–103
20. Zheng Y-W, Chen B, Ye P, Feng K, Wang W, Meng Q-Y, Wu L-Z, Tung C-H (2016)
Photocatalytic hydrogen-evolution cross-couplings: benzene C–H amination and hydroxylation. J Am Chem Soc 138:10080–10083
21. Niu L, Yi H, Wang S, Liu T, Liu J, Lei A (2017) Photo-induced oxidant-free oxidative C-H/
N-H cross-coupling between arenes and azoles. Nat Commun 8:14226
22. Zheng YW, Ye P, Chen B, Meng QY, Feng K, Wang W, Wu LZ, Tung CH (2017) Benzene
C-H etherification via photocatalytic hydrogen-evolution cross-coupling reaction. Org Lett
19:2206–2209
23. Zhang G, Hu X, Chiang CW, Yi H, Pei P, Singh AK, Lei A (2016) Anti-Markovnikov oxidation
of beta-alkyl styrenes with H 2 O as the terminal oxidant. J Am Chem Soc 138:12037–12040
24. Yi H, Niu L, Song C, Li Y, Dou B, Singh AK, Lei A (2017) Photocatalytic dehydrogenative
cross-coupling of alkenes with alcohols or azoles without external oxidant. Angew Chem Int
Ed 56:1120–1124
5 Fourth-Generation Oxidative Cross-Coupling Reactions
4. Lv N, Liu Y, Xiong C, Liu Z, Zhang Y (2017) Cobalt-catalyzed oxidant-free spirocycle synthesis by liberation of hydrogen. Org Lett 19:4640–4643
5. Yang D, Zhu Y, Yang N, Jiang Q, Liu R (2016) One-step synthesis of substituted Benzofurans
fromortho- alkenylphenols via palladium-catalyzed C-H functionalization. Adv Synth Catal
358:1731–1735
6. Manikandan R, Madasamy P, Jeganmohan M (2016) Ruthenium-catalyzed ortho alkenylation
of aromatics with alkenes at room temperature with hydrogen evolution. ACS Catal 6:230–234
7. Li WH, Wu L, Li SS, Liu CF, Zhang GT, Dong L (2016) Rhodium-catalyzed hydrogenreleasing ortho-alkenylation of 7-azaindoles. Chemistry 22:17926–17929
8. Chen C, Chen X, Zhao H, Jiang H, Zhang M (2017) Direct access to nitrogen bi-heteroarenes
via iridium-catalyzed hydrogen-evolution cross-coupling reaction. Org Lett 19:3390–3393
9. Zhou A-X, Mao L-L, Wang G-W, Yang S-D (2014) A unique copper-catalyzed cross-coupling
reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles.
Chem Commun 50:8529–8532
10. Meng QY, Zhong JJ, Liu Q, Gao XW, Zhang HH, Lei T, Li ZJ, Feng K, Chen B, Tung CH,
Wu LZ (2013) A cascade cross-coupling hydrogen evolution reaction by visible light catalysis.
J Am Chem Soc 135:19052–19055
11. Zhong JJ, Meng QY, Liu B, Li XB, Gao XW, Lei T, Wu CJ, Li ZJ, Tung CH, Wu LZ (2014)
Cross-coupling hydrogen evolution reaction in homogeneous solution without noble metals.
Org Lett 16:1988–1991
12. Gao X-W, Meng Q-Y, Li J-X, Zhong J-J, Lei T, Li X-B, Tung C-H, Wu L-Z (2015) Visible light
catalysis assisted site-specific functionalization of amino acid derivatives by C–H bond activation without oxidant: cross-coupling hydrogen evolution reaction. ACS Catal 5:2391–2396
13. Xiang M, Meng QY, Li JX, Zheng YW, Ye C, Li ZJ, Chen B, Tung CH, Wu LZ (2015)
Activation of CH bonds through oxidant-free photoredox catalysis: cross-coupling hydrogenevolution transformation of isochromans and beta-keto esters. Chem-Eur J 21:18080–18084
14. Wu C-J, Meng Q-Y, Lei T, Zhong J-J, Liu W-Q, Zhao L-M, Li Z-J, Chen B, Tung C-H, Wu L-Z
(2016) An oxidant-free strategy for indole synthesis via intramolecular C–C bond construction under visible light irradiation: cross-coupling hydrogen evolution reaction. ACS Catal
6:4635–4639
15. Zhang G, Liu C, Yi H, Meng Q, Bian C, Chen H, Jian JX, Wu LZ, Lei A (2015) External
oxidant-free oxidative cross-coupling: a Photoredox cobalt-catalyzed aromatic C-H thiolation
for constructing C-S bonds. J Am Chem Soc 137:9273–9280
16. Zhang G, Zhang L, Yi H, Luo Y, Qi X, Tung C-H, Wu L-Z, Lei A (2016) Visible-light induced
oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic
acids. Chem Commun 52:10407–10410
17. Downing RS, Kunkeler PJ, van Bekkum H (1997) Catalytic syntheses of aromatic amines.
Catal Today 37:121–136
18. Liu Y, Lu Y, Prashad M, Repič O, Blacklock TJ (2005) A practical and chemoselective reduction of nitroarenes to anilines using activated iron. Adv Synth Catal 347:217–219
19. Schmidt RJ (2005) Industrial catalytic processes—phenol production. Appl Catal A Gen
280:89–103
20. Zheng Y-W, Chen B, Ye P, Feng K, Wang W, Meng Q-Y, Wu L-Z, Tung C-H (2016)
Photocatalytic hydrogen-evolution cross-couplings: benzene C–H amination and hydroxylation. J Am Chem Soc 138:10080–10083
21. Niu L, Yi H, Wang S, Liu T, Liu J, Lei A (2017) Photo-induced oxidant-free oxidative C-H/
N-H cross-coupling between arenes and azoles. Nat Commun 8:14226
22. Zheng YW, Ye P, Chen B, Meng QY, Feng K, Wang W, Wu LZ, Tung CH (2017) Benzene
C-H etherification via photocatalytic hydrogen-evolution cross-coupling reaction. Org Lett
19:2206–2209
23. Zhang G, Hu X, Chiang CW, Yi H, Pei P, Singh AK, Lei A (2016) Anti-Markovnikov oxidation
of beta-alkyl styrenes with H 2 O as the terminal oxidant. J Am Chem Soc 138:12037–12040
24. Yi H, Niu L, Song C, Li Y, Dou B, Singh AK, Lei A (2017) Photocatalytic dehydrogenative
cross-coupling of alkenes with alcohols or azoles without external oxidant. Angew Chem Int
Ed 56:1120–1124
5 Fourth-Generation Oxidative Cross-Coupling Reactions