154
36. Tran BL, Li B, Driess M, Hartwig JF (2014) Copper-catalyzed intermolecular amidation and
imidation of unactivated alkanes. J Am Chem Soc 136:2555
37. Zeng HT, Huang JM (2015) Copper-catalyzed ligand-free amidation of benzylic hydrocarbons
and inactive aliphatic alkanes. Org Lett 17:4276
38. Wang L, Priebbenow DL, Zou LH, Bolm C (2013) The copper-catalyzed oxidative N-acylation
of sulfoximines. Adv Synth Catal 355:1490
39. Zhou L, Tang S, Qi X, Lin C, Liu K, Liu C, Lan Y, Lei A (2014) Transition-metal-assisted
radical/radical cross-coupling: a new strategy to the oxidative C(sp3)–H/N–H cross-coupling.
Org Lett 16:3404
40. Zhou L, Yi H, Zhu L, Qi X, Jiang H, Liu C, Feng Y, Lan Y, Lei A (2015) Tuning the reactivity
of radical through a triplet diradical cu(II) intermediate in radical oxidative cross-coupling. Sci
Rep 5:15934
41. Wang CY, Song RJ, Wei WT, Fan JH, Li JH (2015) Copper-catalyzed oxidative coupling of
acids with alkanes involving dehydrogenation: facile access to allylic esters and alkylalkenes.
Chem Commun 51:2361
42. Zhao J, Fang H, Zhou W, Han J, Pan Y (2014) Iron-catalyzed cross-dehydrogenative coupling
esterification of unactive C(sp3)–H bonds with carboxylic acids for the synthesis of α-acyloxy
ethers. J Org Chem 79:3847
43. Huang Z, Jin L, Feng Y, Peng P, Yi H, Lei A (2013) Iron-catalyzed oxidative radical crosscoupling/cyclization between phenols and olefins. Angew Chem Int Ed 52:7151
44. Huang Z, Lumb JP (2016) A catalyst-controlled aerobic coupling of ortho-quinones and phenols applied to the synthesis of aryl ethers. Angew Chem Int Ed 55:11543
45. Guo SR, Yuan YQ, Xiang JN (2013) Metal-free oxidative C(sp3)–H bond thiolation of ethers
with disulfides. Org Lett 15:4654
46. Yan G, Borah AJ, Wang L (2014) Efficient silver-catalyzed direct sulfenylation and selenylation of rich arenes. Org Biomol Chem 12:9557
47. Huang Z, Zhang D, Qi X, Yan Z, Wang M, Yan H, Lei A (2016) Radical–radical cross-coupling
for C–S bond formation. Org Lett 18:2351
48. Yang B, Yang T, Li X, Wang J, Yang S (2013) A mild, selective copper-catalyzed oxidative
phosphonation of α-amino ketones. Org Lett 15:5024
49. Ke J, Tang Y, Yi H, Li Y, Cheng Y, Liu C, Lei A (2015) Copper-catalyzed radical/radical
C(sp3)-H/P-H cross-coupling: alpha-phosphorylation of aryl ketone O-acetyloximes. Angew
Chem Int Ed 54:6604
50. Effenberger F, Kottmann H (1985) Oxidative phosphonylation of aromatic compounds.
Tetrahedron 41:4171
51. Mao X, Ma X, Zhang S, Hu H, Zhu C, Cheng Y (2013) Silver-catalyzed highly regioselective
phosphonation of arenes bearing electron-withdrawing groups. Eur J Org Chem 2013:4245
52. Gao M, Li Y, Xie L, Chauvin R, Cui X (2016) Direct phosphonation of quinoxalin-2(1H)-ones
under transition-metal-free conditions. Chem Commun 52:2846
53. Gui Q, Hu L, Chen X, Liu J, Tan Z (2015) Stereoselective synthesis of vinylphosphonates
and phosphine oxides via silver-catalyzed phosphorylation of styrenes. Chem Commun
51:13922
54. Li YM, Sun M, Wang HL, Tian QP, Yang SD (2013) Direct annulations toward phosphorylated
oxindoles: silver-catalyzed carbon-phosphorus functionalization of alkenes. Angew Chem Int
Ed 52:3972
55. Li YM, Shen Y, Chang KJ, Yang SD (2014) Metal-free oxidative arylphosphination of activated N-substituted-N-arylacrylamide derivatives using K 2 S 2 O 8 . Tetrahedron 70:1991
56. Zhao J, Li P, Li X, Xia C, Li F (2016) Straightforward synthesis of functionalized chroman4- ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes. Chem
Commun 52:3661
57. Xu J, Yu X, Song Q (2017) Silver-catalyzed radical-involved cascade cyclization of diphenylphosphine with cinnamamides: access to 2-phosphinoyl-3H-pyrrolo[1,2-α]indoles. Org
Lett 19:980
W. Liu
36. Tran BL, Li B, Driess M, Hartwig JF (2014) Copper-catalyzed intermolecular amidation and
imidation of unactivated alkanes. J Am Chem Soc 136:2555
37. Zeng HT, Huang JM (2015) Copper-catalyzed ligand-free amidation of benzylic hydrocarbons
and inactive aliphatic alkanes. Org Lett 17:4276
38. Wang L, Priebbenow DL, Zou LH, Bolm C (2013) The copper-catalyzed oxidative N-acylation
of sulfoximines. Adv Synth Catal 355:1490
39. Zhou L, Tang S, Qi X, Lin C, Liu K, Liu C, Lan Y, Lei A (2014) Transition-metal-assisted
radical/radical cross-coupling: a new strategy to the oxidative C(sp3)–H/N–H cross-coupling.
Org Lett 16:3404
40. Zhou L, Yi H, Zhu L, Qi X, Jiang H, Liu C, Feng Y, Lan Y, Lei A (2015) Tuning the reactivity
of radical through a triplet diradical cu(II) intermediate in radical oxidative cross-coupling. Sci
Rep 5:15934
41. Wang CY, Song RJ, Wei WT, Fan JH, Li JH (2015) Copper-catalyzed oxidative coupling of
acids with alkanes involving dehydrogenation: facile access to allylic esters and alkylalkenes.
Chem Commun 51:2361
42. Zhao J, Fang H, Zhou W, Han J, Pan Y (2014) Iron-catalyzed cross-dehydrogenative coupling
esterification of unactive C(sp3)–H bonds with carboxylic acids for the synthesis of α-acyloxy
ethers. J Org Chem 79:3847
43. Huang Z, Jin L, Feng Y, Peng P, Yi H, Lei A (2013) Iron-catalyzed oxidative radical crosscoupling/cyclization between phenols and olefins. Angew Chem Int Ed 52:7151
44. Huang Z, Lumb JP (2016) A catalyst-controlled aerobic coupling of ortho-quinones and phenols applied to the synthesis of aryl ethers. Angew Chem Int Ed 55:11543
45. Guo SR, Yuan YQ, Xiang JN (2013) Metal-free oxidative C(sp3)–H bond thiolation of ethers
with disulfides. Org Lett 15:4654
46. Yan G, Borah AJ, Wang L (2014) Efficient silver-catalyzed direct sulfenylation and selenylation of rich arenes. Org Biomol Chem 12:9557
47. Huang Z, Zhang D, Qi X, Yan Z, Wang M, Yan H, Lei A (2016) Radical–radical cross-coupling
for C–S bond formation. Org Lett 18:2351
48. Yang B, Yang T, Li X, Wang J, Yang S (2013) A mild, selective copper-catalyzed oxidative
phosphonation of α-amino ketones. Org Lett 15:5024
49. Ke J, Tang Y, Yi H, Li Y, Cheng Y, Liu C, Lei A (2015) Copper-catalyzed radical/radical
C(sp3)-H/P-H cross-coupling: alpha-phosphorylation of aryl ketone O-acetyloximes. Angew
Chem Int Ed 54:6604
50. Effenberger F, Kottmann H (1985) Oxidative phosphonylation of aromatic compounds.
Tetrahedron 41:4171
51. Mao X, Ma X, Zhang S, Hu H, Zhu C, Cheng Y (2013) Silver-catalyzed highly regioselective
phosphonation of arenes bearing electron-withdrawing groups. Eur J Org Chem 2013:4245
52. Gao M, Li Y, Xie L, Chauvin R, Cui X (2016) Direct phosphonation of quinoxalin-2(1H)-ones
under transition-metal-free conditions. Chem Commun 52:2846
53. Gui Q, Hu L, Chen X, Liu J, Tan Z (2015) Stereoselective synthesis of vinylphosphonates
and phosphine oxides via silver-catalyzed phosphorylation of styrenes. Chem Commun
51:13922
54. Li YM, Sun M, Wang HL, Tian QP, Yang SD (2013) Direct annulations toward phosphorylated
oxindoles: silver-catalyzed carbon-phosphorus functionalization of alkenes. Angew Chem Int
Ed 52:3972
55. Li YM, Shen Y, Chang KJ, Yang SD (2014) Metal-free oxidative arylphosphination of activated N-substituted-N-arylacrylamide derivatives using K 2 S 2 O 8 . Tetrahedron 70:1991
56. Zhao J, Li P, Li X, Xia C, Li F (2016) Straightforward synthesis of functionalized chroman4- ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes. Chem
Commun 52:3661
57. Xu J, Yu X, Song Q (2017) Silver-catalyzed radical-involved cascade cyclization of diphenylphosphine with cinnamamides: access to 2-phosphinoyl-3H-pyrrolo[1,2-α]indoles. Org
Lett 19:980
W. Liu