153
12. Perry A, Taylor RJK (2009) Oxindole synthesis by direct C–H, Ar–H coupling. Chem Commun
22:3249
13. Klein JEMN, Perry A, Pugh DS, Taylor RJK (2012) First C−H activation route to oxindoles
using copper catalysis. Org Lett 12:3446
14. Liu RR, Hong JJ, Lu CJ, Xu M, Gao JR, Jia YX (2015) Indolizine synthesis via oxidative crosscoupling/cyclization of alkenes and 2-(Pyridin-2-yl)acetate derivatives. Org Lett 17:3050
15. Tang S, Liu K, Long Y, Gao X, Gao M, Lei A (2015) Iodine-catalyzed radical oxidative annulation for the construction of dihydrofurans and indolizines. Org Lett 17:2404
16. Qin G, Chen X, Yang L, Huang H (2015) Copper-catalyzed α-benzylation of enones via radical-triggered oxidative coupling of two C–H bonds. ACS Catal 5:2882
17. Borduas N, Powell DA (2008) Copper-catalyzed oxidative coupling of benzylic C−H bonds
with 1,3-dicarbonyl compounds. J Org Chem 73:7822
18. Zhang Y, Li CJ (2007) Highly efficient direct alkylation of activated methylene by cycloalkanes. Eur J Org Chem 28:4654
19. Cheng K, Huang L, Zhang Y (2009) CuBr-mediated oxyalkylation of vinylarenes under aerobic conditions via cleavage of sp3 C−H bonds α to oxygen. Org Lett 11:2908
20. Song CX, Cai GX, Farrell TR, Jiang ZP, Li H, Gan LB, Shi ZJ (2009) Direct functionalization
of benzylic C–Hs with vinyl acetates via Fe catalysis. Chem Commun 44:6002
21. Liu D, Liu C, Li H, Lei A (2014) Copper-catalysed oxidative C–H/C–H coupling between
olefins and simple ethers. Chem Commun 50:3623
22. More NY, Jeganmohan M (2015) Oxidative cross-coupling of two different phenols: an efficient route to unsymmetrical biphenols. Org Lett 17:3042
23. Wang J, Liu C, Yuan J, Lei A (2013) Copper-catalyzed oxidative coupling of alkenes with
aldehydes: direct access to α,β -unsaturated ketones. Angew Chem Int Ed 52:2256
24. Ma Y, Zhang D, Yan Z, Wang M, Bian C, Gao X, Bunel EE, Lei A (2015) Iron-catalyzed oxidative C–H/C–H cross-coupling between electron-rich arenes and alkenes. Org Lett 17:2174
25. Zhou MB, Song RJ, Ouyang XH, Liu Y, Wei WT, Deng GB, Li JH (2013) Metal-free oxidative
tandem coupling of activated alkenes with carbonyl C(sp2)–H bonds and aryl C(sp2)–H bonds
using TBHP. Chem Sci 4:2690
26. Zhou SL, Guo LN, Wang H, Duan XH (2013) Copper-catalyzed oxidative benzylarylation of
acrylamides by benzylic C-H bond functionalization for the synthesis of oxindoles. Chem Eur
J 19:12970
27. Wang H, Guo LN, Duan XH (2013) Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds. Chem Commun 49:10370
28. Wang H, Guo LN, Duan XH (2013) Metal-free oxidative spirocyclization of hydroxymethylacrylamide with 1,3-dicarbonyl compounds: a new route to spirooxindoles. Org Lett 15:5254
29. Li Z, Zhang Y, Zhang L, Liu ZQ (2014) Free-radical cascade alkylarylation of alkenes with
simple alkanes: highly efficient access to oxindoles via selective (sp3)C–H and (sp2)C–H bond
functionalization. Org Lett 16:382
30. Wang H, Zhou SL, Guo LN, Duan XH (2015) Diacylation of coumarins by silver-catalyzed
decarboxylative cross-coupling. Tetrahedron 71:630
31. Wang H, Guo LN, Duan XH (2013) Silver-catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids in aqueous media. Adv Synth Catal 355:2222
32. Mai WP, Wang JT, Yang LR, Yuan JW, Xiao YM, Mao P, Qu LB (2014) Silver-catalyzed radical tandem cyclization for the synthesis of 3, 4-disubstituted dihydroquinolin-2(1H)-ones. Org
Lett 16:204
33. Mai WP, Sun GC, Wang JT, Song G, Mao P, Yang LR, Yuan JW, Xiao YM, Qu LB (2014)
Silver-catalyzed radical tandem cyclization: an approach to direct synthesis of 3-acyl-4-arylquinolin-2(1H)-ones. J Org Chem 79:8094
34. Tang RJ, He Q, Yang L (2015) Metal-free oxidative decarbonylative coupling of aromatic
aldehydes with arenes: direct access to biaryls. Chem Commun 51:5925
35. Kumar A, Shah BA (2015) Synthesis of biaryls via benzylic C–C bond cleavage of styrenes
and benzyl alcohols. Org Lett 17:5232
4 Oxidative Radical Couplings
12. Perry A, Taylor RJK (2009) Oxindole synthesis by direct C–H, Ar–H coupling. Chem Commun
22:3249
13. Klein JEMN, Perry A, Pugh DS, Taylor RJK (2012) First C−H activation route to oxindoles
using copper catalysis. Org Lett 12:3446
14. Liu RR, Hong JJ, Lu CJ, Xu M, Gao JR, Jia YX (2015) Indolizine synthesis via oxidative crosscoupling/cyclization of alkenes and 2-(Pyridin-2-yl)acetate derivatives. Org Lett 17:3050
15. Tang S, Liu K, Long Y, Gao X, Gao M, Lei A (2015) Iodine-catalyzed radical oxidative annulation for the construction of dihydrofurans and indolizines. Org Lett 17:2404
16. Qin G, Chen X, Yang L, Huang H (2015) Copper-catalyzed α-benzylation of enones via radical-triggered oxidative coupling of two C–H bonds. ACS Catal 5:2882
17. Borduas N, Powell DA (2008) Copper-catalyzed oxidative coupling of benzylic C−H bonds
with 1,3-dicarbonyl compounds. J Org Chem 73:7822
18. Zhang Y, Li CJ (2007) Highly efficient direct alkylation of activated methylene by cycloalkanes. Eur J Org Chem 28:4654
19. Cheng K, Huang L, Zhang Y (2009) CuBr-mediated oxyalkylation of vinylarenes under aerobic conditions via cleavage of sp3 C−H bonds α to oxygen. Org Lett 11:2908
20. Song CX, Cai GX, Farrell TR, Jiang ZP, Li H, Gan LB, Shi ZJ (2009) Direct functionalization
of benzylic C–Hs with vinyl acetates via Fe catalysis. Chem Commun 44:6002
21. Liu D, Liu C, Li H, Lei A (2014) Copper-catalysed oxidative C–H/C–H coupling between
olefins and simple ethers. Chem Commun 50:3623
22. More NY, Jeganmohan M (2015) Oxidative cross-coupling of two different phenols: an efficient route to unsymmetrical biphenols. Org Lett 17:3042
23. Wang J, Liu C, Yuan J, Lei A (2013) Copper-catalyzed oxidative coupling of alkenes with
aldehydes: direct access to α,β -unsaturated ketones. Angew Chem Int Ed 52:2256
24. Ma Y, Zhang D, Yan Z, Wang M, Bian C, Gao X, Bunel EE, Lei A (2015) Iron-catalyzed oxidative C–H/C–H cross-coupling between electron-rich arenes and alkenes. Org Lett 17:2174
25. Zhou MB, Song RJ, Ouyang XH, Liu Y, Wei WT, Deng GB, Li JH (2013) Metal-free oxidative
tandem coupling of activated alkenes with carbonyl C(sp2)–H bonds and aryl C(sp2)–H bonds
using TBHP. Chem Sci 4:2690
26. Zhou SL, Guo LN, Wang H, Duan XH (2013) Copper-catalyzed oxidative benzylarylation of
acrylamides by benzylic C-H bond functionalization for the synthesis of oxindoles. Chem Eur
J 19:12970
27. Wang H, Guo LN, Duan XH (2013) Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds. Chem Commun 49:10370
28. Wang H, Guo LN, Duan XH (2013) Metal-free oxidative spirocyclization of hydroxymethylacrylamide with 1,3-dicarbonyl compounds: a new route to spirooxindoles. Org Lett 15:5254
29. Li Z, Zhang Y, Zhang L, Liu ZQ (2014) Free-radical cascade alkylarylation of alkenes with
simple alkanes: highly efficient access to oxindoles via selective (sp3)C–H and (sp2)C–H bond
functionalization. Org Lett 16:382
30. Wang H, Zhou SL, Guo LN, Duan XH (2015) Diacylation of coumarins by silver-catalyzed
decarboxylative cross-coupling. Tetrahedron 71:630
31. Wang H, Guo LN, Duan XH (2013) Silver-catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids in aqueous media. Adv Synth Catal 355:2222
32. Mai WP, Wang JT, Yang LR, Yuan JW, Xiao YM, Mao P, Qu LB (2014) Silver-catalyzed radical tandem cyclization for the synthesis of 3, 4-disubstituted dihydroquinolin-2(1H)-ones. Org
Lett 16:204
33. Mai WP, Sun GC, Wang JT, Song G, Mao P, Yang LR, Yuan JW, Xiao YM, Qu LB (2014)
Silver-catalyzed radical tandem cyclization: an approach to direct synthesis of 3-acyl-4-arylquinolin-2(1H)-ones. J Org Chem 79:8094
34. Tang RJ, He Q, Yang L (2015) Metal-free oxidative decarbonylative coupling of aromatic
aldehydes with arenes: direct access to biaryls. Chem Commun 51:5925
35. Kumar A, Shah BA (2015) Synthesis of biaryls via benzylic C–C bond cleavage of styrenes
and benzyl alcohols. Org Lett 17:5232
4 Oxidative Radical Couplings