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orthogonal supramolecular chain cross-linking. Macromolecules 47(12):4028–4036. https://
doi.org/10.1021/ma5008573
39. Ji X, Jie K, Zimmerman SC, Huang F (2015) A double supramolecular crosslinked polymer
gel exhibiting macroscale expansion and contraction behavior and multistimuli responsiveness. Polym Chem 6(11):1912–1917. https://doi.org/10.1039/C4PY01715C
40. Wang Q, Mynar JL, Yoshida M, Lee E, Lee M, Okuro K, Kinbara K, Aida T (2010)
High-water-content mouldable hydrogels by mixing clay and a dendritic molecular binder.
Nature 463(7279):339–343
41. Partridge KS, Smith DK, Dykes GM, McGrail PT (2001) Supramolecular dendritic
two-component gel. Chem Commun 4:319–320. https://doi.org/10.1039/B009672P
42. Ge Z, Hu J, Huang F, Liu S (2009) Responsive supramolecular gels constructed by crown
ether based molecular recognition. Angew Chem 121(10):1830–1834. https://doi.org/10.
1002/ange.200805712
43. Noro A, Matsushita Y, Lodge TP (2009) Gelation mechanism of thermoreversible
supramacromolecular ion gels via hydrogen bonding. Macromolecules 42(15):5802–5810.
https://doi.org/10.1021/ma900820g
44. Noro A, Hayashi M, Ohshika A, Matsushita Y (2011) Simple preparation of supramolecular
polymer gels viahydrogen bonding by blending two liquid polymers. Soft Matter 7(5):1667–
1670. https://doi.org/10.1039/C0SM01334J
45. Jung JH, Lee JH, Silverman JR, John G (2013) Coordination polymer gels with important
environmental and biological applications. Chem Soc Rev 42(3):924–936. https://doi.org/10.
1039/C2CS35407A
46. Rubin DJ, Miserez A, Waite JH (2010) Diverse strategies of protein sclerotization in marine
invertebrates. Adv Insect Physiol 38:75–133. https://doi.org/10.1016/S0065-2806(10)38003-9
47. Harrington MJ, Masic A, Holten-Andersen N, Waite JH, Fratzl P (2010) Iron-clad fibers: a
metal-based biological strategy for hard flexible coatings. Science 328(5975):216–220.
https://doi.org/10.1126/science.1181044
48. Holten-Andersen N, Harrington MJ, Birkedal H, Lee BP, Messersmith PB, Lee KYC,
Waite JH (2011) pH-induced metal-ligand cross-links inspired by mussel yield self-healing
polymer networks with near-covalent elastic moduli. Proc Natl Acad Sci USA 108(7):2651–
2655. https://doi.org/10.1073/pnas.1015862108
49. Piepenbrock M-OM, Lloyd GO, Clarke N, Steed JW (2010) Metal-and anion-binding
supramolecular gels. Chem Rev 110(4):1960–2004. https://doi.org/10.1021/cr9003067
50. Zhang J, Su C-Y (2013) Metal-organic gels: from discrete metallogelatros to coordination
polymers. Coord Chem Rev 257:1373–1408. https://doi.org/10.1016/j.ccr.2013.01.005
51. Dubey M, Kumar A, Pandey DS (2014) Homochiral coordination polymeric gel: Zn
2+ -
induced conformational changes leading to J-aggregated helical fibres formation. Chem
Commun 50(14):1675–1677. https://doi.org/10.1039/C3CC47359G
52. Xu F, Padhy H, Al-Dossary M, Zhang G, Behzad AR, Stingl U, Rothenberger A (2014)
Synthesis and properties of the metallo-supramolecular polymer hydrogel poly[methyl vinyl
ether-alt-mono-sodium maleate] AgNO 3 : Ag
+ /Cu
2+ ion exchange and effective antibacterial
activity. J Mater Chem B 2(37):6406–6411. https://doi.org/10.1039/C4TB00611A
53. Zhukhovitskiy AV, Zhong M, Keeler EG, Michaelis VK, Sun JEP, Hore MJA, Pochan DJ,
Griffin RG, Willard AP, Johnson JA (2016) Highly branched and loop-rich gels via formation
of metal–organic cages linked by polymers. Nat Chem 8(1):33–41. https://doi.org/10.1038/
nchem.2390
54. Foster JA, Parker RM, Belenguer AM, Kishi N, Sutton S, Abell C, Nitschke JR (2015)
Differentially addressable cavities within metal-organic cage-cross-linked polymeric hydrogels. J Am Chem Soc 137(30):9722–9729. https://doi.org/10.1021/jacs.5b05507
55. Wang Y, Zhong M, Park JV, Zhukhovitskiy AV, Shi W, Johnson JA (2016) Block
co-polyMOCs by stepwise self-assembly. J Am Chem Soc 138(33):10708–10715. https://doi.
org/10.1021/jacs.6b06712
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187