121. Luo Z, Poyraz AS, Kuo CH et al (2015) Crystalline mixed phase (anatase/rutile) mesoporous
titanium dioxides for visible light photocatalytic activity. Chem Mater 27(1):6–17
122. Zhao B, Chen F, Jiao Y et al (2011) Ag 0-loaded brookite/anatase composite with enhanced
photocatalytic performance towards the degradation of methyl orange. J Mol Catal A Chem
348(1):114–119
123. Liao Y, Que W, Jia Q et al (2012) Controllable synthesis of brookite/anatase/rutile TiO 2
nanocomposites and single-crystalline rutile nanorods array. J Mater Chem 22(16):7937–7944
124. Grabowska E, Reszczyńska J, Zaleska A (2012) Mechanism of phenol photodegradation in the
presence of pure and modified-TiO 2 : a review. Water Res 46(17):5453–5471
125. Ding Z, Lu GQ, Greenfield PF (2000) Role of the crystallite phase of TiO 2 in heterogeneous
photocatalysis for phenol oxidation in water. J Phys Chem B 104(19):4815–4820
126. Tian B, Li C, Zhang J (2012) One-step preparation, characterization and visible-light
photocatalytic activity of Cr-doped TiO 2 with anatase and rutile bicrystalline phases. Chem
Eng J 191:402–409
127. Deák P, Aradi B, Frauenheim T (2011) Band lineup and charge carrier separation in mixed
rutile-anatase systems. J Phys Chem C 115(8):3443–3446
128. Scanlon DO, Dunnill CW, Buckeridge J et al (2013) Band alignment of rutile and anatase
TiO 2 . Nat Mater 12(9):798–801
129. Datye AK, Riegel G, Bolton JR et al (1995) Microstructural characterization of a fumed
titanium dioxide photocatalyst. J Solid State Chem 115(1):236–239
130. Zhang Z, Wang CC, Zakaria R et al (1998) Role of particle size in nanocrystalline TiO 2 -based
photocatalysts. J Phys Chem B 102(52):10871–10878
131. Ohno T, Sarukawa K, Tokieda K et al (2001) Morphology of a TiO 2 photocatalyst (Degussa,
P-25) consisting of anatase and rutile crystalline phases. J Catal 203(1):82–86
132. Kawahara T, Konishi Y, Tada H et al (2002) A patterned TiO 2 (anatase)/TiO 2 (rutile) bilayertype photocatalyst: effect of the anatase/rutile junction on the photocatalytic activity. Angew
Chem 114(15):2935–2937
133. Li G, Gray KA (2007) The solid–solid interface: explaining the high and unique photocatalytic
reactivity of TiO 2 -based nanocomposite materials. Chem Phys 339(1):173–187
134. Sun B, Vorontsov AV, Smirniotis PG (2003) Role of platinum deposited on TiO 2 in phenol
photocatalytic oxidation. Langmuir 19(8):3151–3156
135. Sun B, Smirniotis PG (2003) Interaction of anatase and rutile TiO 2 particles in aqueous
photooxidation. Catal Today 88(1):49–59
136. Liu B, Peng L (2013) Facile formation of mixed phase porous TiO 2 nanotubes and enhanced
visible-light photocatalytic activity. J Alloys Compd 571:145–152
137. Li G, Chen L, Graham ME et al (2007) A comparison of mixed phase titania photocatalysts
prepared by physical and chemical methods: the importance of the solid–solid interface. J Mol
Catal A Chem 275(1):30–35
138. Wang CY, Pagel R, Dohrmann JK et al (2006) Antenna mechanism and deaggregation
concept: novel mechanistic principles for photocatalysis. C R Chim 9(5):761–773
172
6 Phase Control of TiO 2 Photocatalyst
titanium dioxides for visible light photocatalytic activity. Chem Mater 27(1):6–17
122. Zhao B, Chen F, Jiao Y et al (2011) Ag 0-loaded brookite/anatase composite with enhanced
photocatalytic performance towards the degradation of methyl orange. J Mol Catal A Chem
348(1):114–119
123. Liao Y, Que W, Jia Q et al (2012) Controllable synthesis of brookite/anatase/rutile TiO 2
nanocomposites and single-crystalline rutile nanorods array. J Mater Chem 22(16):7937–7944
124. Grabowska E, Reszczyńska J, Zaleska A (2012) Mechanism of phenol photodegradation in the
presence of pure and modified-TiO 2 : a review. Water Res 46(17):5453–5471
125. Ding Z, Lu GQ, Greenfield PF (2000) Role of the crystallite phase of TiO 2 in heterogeneous
photocatalysis for phenol oxidation in water. J Phys Chem B 104(19):4815–4820
126. Tian B, Li C, Zhang J (2012) One-step preparation, characterization and visible-light
photocatalytic activity of Cr-doped TiO 2 with anatase and rutile bicrystalline phases. Chem
Eng J 191:402–409
127. Deák P, Aradi B, Frauenheim T (2011) Band lineup and charge carrier separation in mixed
rutile-anatase systems. J Phys Chem C 115(8):3443–3446
128. Scanlon DO, Dunnill CW, Buckeridge J et al (2013) Band alignment of rutile and anatase
TiO 2 . Nat Mater 12(9):798–801
129. Datye AK, Riegel G, Bolton JR et al (1995) Microstructural characterization of a fumed
titanium dioxide photocatalyst. J Solid State Chem 115(1):236–239
130. Zhang Z, Wang CC, Zakaria R et al (1998) Role of particle size in nanocrystalline TiO 2 -based
photocatalysts. J Phys Chem B 102(52):10871–10878
131. Ohno T, Sarukawa K, Tokieda K et al (2001) Morphology of a TiO 2 photocatalyst (Degussa,
P-25) consisting of anatase and rutile crystalline phases. J Catal 203(1):82–86
132. Kawahara T, Konishi Y, Tada H et al (2002) A patterned TiO 2 (anatase)/TiO 2 (rutile) bilayertype photocatalyst: effect of the anatase/rutile junction on the photocatalytic activity. Angew
Chem 114(15):2935–2937
133. Li G, Gray KA (2007) The solid–solid interface: explaining the high and unique photocatalytic
reactivity of TiO 2 -based nanocomposite materials. Chem Phys 339(1):173–187
134. Sun B, Vorontsov AV, Smirniotis PG (2003) Role of platinum deposited on TiO 2 in phenol
photocatalytic oxidation. Langmuir 19(8):3151–3156
135. Sun B, Smirniotis PG (2003) Interaction of anatase and rutile TiO 2 particles in aqueous
photooxidation. Catal Today 88(1):49–59
136. Liu B, Peng L (2013) Facile formation of mixed phase porous TiO 2 nanotubes and enhanced
visible-light photocatalytic activity. J Alloys Compd 571:145–152
137. Li G, Chen L, Graham ME et al (2007) A comparison of mixed phase titania photocatalysts
prepared by physical and chemical methods: the importance of the solid–solid interface. J Mol
Catal A Chem 275(1):30–35
138. Wang CY, Pagel R, Dohrmann JK et al (2006) Antenna mechanism and deaggregation
concept: novel mechanistic principles for photocatalysis. C R Chim 9(5):761–773
172
6 Phase Control of TiO 2 Photocatalyst