Selectfluor fluorinating reagent, 127
Silver, 56, 98, 104, 109, 115–129
Silver hexafluoroantimonate(V), 117
Silylation, 20
iron-catalyzed, 13
Solenopsin A, 145
Spirooxindoles, 98
Sulfoximine, 55
Surface organometallic chemistry (SOMC),
155, 157
Syngas, 190
T
Tantalum, 159, 163, 170, 200, 205
Tantalum carbene, 162, 163
Tantalum hydrides, 155, 156, 164, 170–172,
180–183
Teleocidin B4, 135
Terephthalic acid, dimethyl ester, 198
Tetrahydrofuran, dehydrogenation, 201
Tetrahydroprotoberberine, 147
Tetrahydroquinolines (THQs), 95, 106, 140
Tetramethyltetrahydrofuran, 93
Tetraneopentylzirconium, 160
Thermodynamics, 67
Thiolation, 32, 40, 58
Titanium, 86, 160, 161
Toluene, 198
Toluene/methane, cross metathesis, 181
Total synthesis, 133
[Tp
0 Rh(CNR)], 68
Transfer dehydrogenations, 190
alkanes, 189
Transition metals, 2, 48, 68, 92, 133, 155
Trifluoromethylthiolation, silver-mediated,
128
Triisopropylsilyl (TIPS), 28
Trimethylphosphite, 82
Tris(pyrazolyl)borate (Tp) silver complexes,
117
Tungsten, 159, 165, 170, 173
Tunsten carbyne, 166, 167
Tungsten hydrides, 172, 176
Tungsten methylidyne, 168
Tungsten polyhydride, 166
V
Vanadium, 95
Verapamil, 147
X
Xylenes, 180, 196–198
Z
Zirconium tris-neopentyl surface
complex, 160
212
Index