1-Indanols, 148
Indaziflam, 149
Iridium, 2, 20, 116
pincer catalysts, 177, 189
Iridium triptycene, 193
Iron, 1
Iron–isocyanide, 11
Iron–xantphos, 15
Isocyanide, 11
Isonitrile, 11
K
Kinetic isotope effect (KIE), 60
Kinetics, 67
L
Lactamase inhibitor, 145
Lactams, 135, 143, 145
β-, 41, 138
γ-, 93
Late-transition metals, 2
M
Metal-alkylidynes, 155
Metal-hydrides, 155
Metallacyclobutanes, 171
Metathesis catalysts, 155, 199, 205
Methane/propane, cross metathesis, 182
2-Methoxyiminoacetyl (MIA), 143
N-Methylbenzamides, 3
Methylene isoindolinone, 50
2-Methylpropane, metathesis, 179
Methylthioanilide, 102
MK-8712, 145
Molybdenum, 199
N
Naphthalenes, 13
Natural products, 133
Neopentylisocyanide, 82
Nickel, 19, 20
Nitrosylation, 43
Nucleophiles, 1, 48, 57, 92, 107
O
Obafluorin, 140
Olefins, 68, 170, 175, 196, 200
cyclic, 147
isomerization, 177
metathesis, 155
poly-, 157
Organomagnesium, 6
Organozinc, 6
Oxazolinylaniline, 50
P
Palladacycles, 97, 100, 106, 109, 135, 138, 142
Palladium, 2, 20, 49, 91
Papaverine, 144
Paspaline, 145
Peptidomimetics, 143
2-Phenylpyridine, 55, 58
Phthalimide, 56
Picolinamide, 102
Piperarborenines, 138
Pipercyclobutanamide, 138
Piperylene, 198
Platinum, 134
Podophyllotoxin, 138
Polyethylene terephthalate (PET), 198
Polyfluoroarenes, 51, 55
Polyhydrides, phosphine-stabilized, 190
Prefunctionalization, 48
Proline, cis-3-substituted, 139
Propane, 69, 180, 181
metathesis, 172, 175, 182
Propene, 171, 182, 196, 203
hydro-metathesis, 182, 183
o-Propyltoluene, 197
Pseudo-Wittig reaction, 164
2-Pyridinylisopropyl (PIP), 149
Pyridinylpropylamine, 50
N-(2-Pyrimidyl)indoles, 56
Pyrroles, 12
Q
Quinolylamine directing group, 6
R
Reductive elimination, 67
Rh–C bonds, 72, 80, 84
Rhazinilam, 134
Rhodium, 2, 20, 67
Ring-opening–ring-closing metathesis
reactions (RO-RCM), 178
Ruthenium, 2, 20
S
Schrock-type metathesis catalysts (Mo/W),
177, 197
Schwartz’s reagent, 42
Index
211
Indaziflam, 149
Iridium, 2, 20, 116
pincer catalysts, 177, 189
Iridium triptycene, 193
Iron, 1
Iron–isocyanide, 11
Iron–xantphos, 15
Isocyanide, 11
Isonitrile, 11
K
Kinetic isotope effect (KIE), 60
Kinetics, 67
L
Lactamase inhibitor, 145
Lactams, 135, 143, 145
β-, 41, 138
γ-, 93
Late-transition metals, 2
M
Metal-alkylidynes, 155
Metal-hydrides, 155
Metallacyclobutanes, 171
Metathesis catalysts, 155, 199, 205
Methane/propane, cross metathesis, 182
2-Methoxyiminoacetyl (MIA), 143
N-Methylbenzamides, 3
Methylene isoindolinone, 50
2-Methylpropane, metathesis, 179
Methylthioanilide, 102
MK-8712, 145
Molybdenum, 199
N
Naphthalenes, 13
Natural products, 133
Neopentylisocyanide, 82
Nickel, 19, 20
Nitrosylation, 43
Nucleophiles, 1, 48, 57, 92, 107
O
Obafluorin, 140
Olefins, 68, 170, 175, 196, 200
cyclic, 147
isomerization, 177
metathesis, 155
poly-, 157
Organomagnesium, 6
Organozinc, 6
Oxazolinylaniline, 50
P
Palladacycles, 97, 100, 106, 109, 135, 138, 142
Palladium, 2, 20, 49, 91
Papaverine, 144
Paspaline, 145
Peptidomimetics, 143
2-Phenylpyridine, 55, 58
Phthalimide, 56
Picolinamide, 102
Piperarborenines, 138
Pipercyclobutanamide, 138
Piperylene, 198
Platinum, 134
Podophyllotoxin, 138
Polyethylene terephthalate (PET), 198
Polyfluoroarenes, 51, 55
Polyhydrides, phosphine-stabilized, 190
Prefunctionalization, 48
Proline, cis-3-substituted, 139
Propane, 69, 180, 181
metathesis, 172, 175, 182
Propene, 171, 182, 196, 203
hydro-metathesis, 182, 183
o-Propyltoluene, 197
Pseudo-Wittig reaction, 164
2-Pyridinylisopropyl (PIP), 149
Pyridinylpropylamine, 50
N-(2-Pyrimidyl)indoles, 56
Pyrroles, 12
Q
Quinolylamine directing group, 6
R
Reductive elimination, 67
Rh–C bonds, 72, 80, 84
Rhazinilam, 134
Rhodium, 2, 20, 67
Ring-opening–ring-closing metathesis
reactions (RO-RCM), 178
Ruthenium, 2, 20
S
Schrock-type metathesis catalysts (Mo/W),
177, 197
Schwartz’s reagent, 42
Index
211