Index
A
Ammonium nitrate decomposition, 43
Atmospheres during synthesis
air, 49, 95, 97, 99, 100, 107
oxygen, 35, 37-43, 45-48, 61, 65-67, 71–76,
82, 89, 93, 117, 121, 122, 124–126,
129, 130
low oxygen partial pressure, 117
B
Bulk sample synthesis, 19, 22, 23, 29, 31, 38,
40, 42, 76, 95, 97, 104
C
Capacity, 4, 101, 103, 105, 114–120, 124–126,
129, 130, 135, 136
Co-existence regions, 28
two-phase
layered-layered, 82
layered-spinel, 78–81
spinel-rocksalt, 11
spinel-Mn 2 O 3 , 71–73
three-phase
quenched, 85–87
slow-cooled, 88–91
Coin cell assembly, 29, 96, 107
Combinatorial synthesis, 21, 22, 48, 77, 134
Commercial positive electrode materials, 1–3,
116, 137, 138
Constant oxidation state lines, 79, 106
Co-precipitation reactions, 19–21, 35
Cooling rates
quenching, 21, 51, 53, 66, 70, 86–88, 92,
96, 98, 103–106, 113, 119, 134, 137
regular cooling, 21, 49, 53, 56, 61, 65, 72,
74, 76, 88, 92, 119–122, 125, 129,
137
slow cooling, 11, 14, 17, 21, 33, 34, 49, 56,
59, 83, 88–90, 92, 93, 95, 99, 100,
103, 109, 117, 134, 137
Crystallite size, 8, 14, 20, 25, 26, 46, 50, 53,
56, 126
Crystallite strain, 25, 46
D
dQ/dV, 103, 114, 126
E
Electrochemical measurements, 124–126
Elemental analysis, 30, 31, 81, 101, 104, 107,
110, 120, 122, 126
L
Integral Breadth Method
quadratic approximation, 26
J
JCPDS database, 25, 36, 42
L
Lattice parameter contour plots, 14, 76,
104, 135
Lattice parameters, 9, 14, 24, 25, 27–29, 40,
50, 53, 55, 58, 65, 71, 72, 76, 78, 80,
81, 83, 86–88, 100, 107, 121, 135
Layered-layered nano-composites, 17, 93, 103,
104, 117, 121, 130, 134, 135
Lever rule, 29, 52, 72, 73, 75, 76, 81, 82, 86,
87, 91, 92
Li[Ni 1/6 P 1/6 Mn 2/3 ]O 2 , 107, 113, 114,
116, 136
Li 2 MnO 3 , 5, 6, 8, 9, 12, 29, 32, 51, 58, 59,
77, 81, 83, 92, 93, 101, 106, 107,
109–111, 113, 116, 135, 136
Li-Co-Mn-Ni-O Gibbs pyramid, 3, 138
145
E. McCalla, Consequences of Combinatorial Studies of Positive Electrodes
for Li-ion Batteries, Springer Theses, DOI 10.1007/978-3-319-05849-8,
© Springer International Publishing Switzerland 2014
A
Ammonium nitrate decomposition, 43
Atmospheres during synthesis
air, 49, 95, 97, 99, 100, 107
oxygen, 35, 37-43, 45-48, 61, 65-67, 71–76,
82, 89, 93, 117, 121, 122, 124–126,
129, 130
low oxygen partial pressure, 117
B
Bulk sample synthesis, 19, 22, 23, 29, 31, 38,
40, 42, 76, 95, 97, 104
C
Capacity, 4, 101, 103, 105, 114–120, 124–126,
129, 130, 135, 136
Co-existence regions, 28
two-phase
layered-layered, 82
layered-spinel, 78–81
spinel-rocksalt, 11
spinel-Mn 2 O 3 , 71–73
three-phase
quenched, 85–87
slow-cooled, 88–91
Coin cell assembly, 29, 96, 107
Combinatorial synthesis, 21, 22, 48, 77, 134
Commercial positive electrode materials, 1–3,
116, 137, 138
Constant oxidation state lines, 79, 106
Co-precipitation reactions, 19–21, 35
Cooling rates
quenching, 21, 51, 53, 66, 70, 86–88, 92,
96, 98, 103–106, 113, 119, 134, 137
regular cooling, 21, 49, 53, 56, 61, 65, 72,
74, 76, 88, 92, 119–122, 125, 129,
137
slow cooling, 11, 14, 17, 21, 33, 34, 49, 56,
59, 83, 88–90, 92, 93, 95, 99, 100,
103, 109, 117, 134, 137
Crystallite size, 8, 14, 20, 25, 26, 46, 50, 53,
56, 126
Crystallite strain, 25, 46
D
dQ/dV, 103, 114, 126
E
Electrochemical measurements, 124–126
Elemental analysis, 30, 31, 81, 101, 104, 107,
110, 120, 122, 126
L
Integral Breadth Method
quadratic approximation, 26
J
JCPDS database, 25, 36, 42
L
Lattice parameter contour plots, 14, 76,
104, 135
Lattice parameters, 9, 14, 24, 25, 27–29, 40,
50, 53, 55, 58, 65, 71, 72, 76, 78, 80,
81, 83, 86–88, 100, 107, 121, 135
Layered-layered nano-composites, 17, 93, 103,
104, 117, 121, 130, 134, 135
Lever rule, 29, 52, 72, 73, 75, 76, 81, 82, 86,
87, 91, 92
Li[Ni 1/6 P 1/6 Mn 2/3 ]O 2 , 107, 113, 114,
116, 136
Li 2 MnO 3 , 5, 6, 8, 9, 12, 29, 32, 51, 58, 59,
77, 81, 83, 92, 93, 101, 106, 107,
109–111, 113, 116, 135, 136
Li-Co-Mn-Ni-O Gibbs pyramid, 3, 138
145
E. McCalla, Consequences of Combinatorial Studies of Positive Electrodes
for Li-ion Batteries, Springer Theses, DOI 10.1007/978-3-319-05849-8,
© Springer International Publishing Switzerland 2014