258
M.E. Vaida and T.M. Bernhardt
56. I.R. McNab, J.C. Polanyi, Patterned atomic reaction at surfaces. Chem. Rev. 106, 4321–4354
(2006)
57. K.R. Harikumar, I.R. McNab, J.C. Polanyi, A. Zabet-Khosousi, W.A. Hofer, Imprinting selfassembled patterns of lines at a semiconductor surface, using heat, light, or electrons. Proc.
Natl. Acad. Sci. USA 108, 950–955 (2011)
58. D.P. Zhong, A.H. Zewail, Femtosecond real-time probing of reactions. 23. Studies of temporal, velocity, angular, and state dynamics from transition states to final products by
femtosecond-resolved mass spectrometry. J. Phys. Chem. A 102, 4031–4058 (1998)
59. R. de Nalda, J.G. Izquierdo, J. Durá, L. Bañares, Femtosecond multichannel photodissociation dynamics of CH 3 I from the A band by velocity map imaging. J. Chem. Phys. 126,
021101 (2007)
60. R. de Nalda, J. Durá, A. Garcia-Vela, J.G. Izquierdo, J. González-Vázquez, L. Bañares, A detailed experimental and theoretical study of the femtosecond A-band photodissociation of
CH 3 I. J. Chem. Phys. 128, 244309 (2008)
61. J. Durá, R. De Nalda, J. Álvarez, J.G. Izquierdo, G.A. Amaral, L. Bañares, Femtosecond
transition-state imaging of the A-band CH 3 I photodissociation. Chem. Phys. Chem. 9, 1245–
1249 (2008)
62. J. Durá, R. de Nalda, G.A. Amaral, L. Bañares, Imaging transient species in the femtosecond
A-band photodissociation of CH 3 I. J. Chem. Phys. 131, 134311 (2009)
63. L. Rubio-Lago, J.D. Rodrigues, A. García-Vela, M.G. Gonzàlez, G.A. Amaral, L. Bañares,
A slice imaging and multisurface wave packet study of the photodissociation of CH 3 I at
304 nm. Phys. Chem. Chem. Phys. 13, 8186–8194 (2011)
64. M.E. Vaida, T. Gleitsmann, R. Tchitnga, T.M. Bernhardt, Femtosecond-laser photoemission
spectroscopy of Mo(100) covered by ultrathin MgO(100) films of variable thickness. J. Phys.
Chem. C 113, 10264–10268 (2009)
65. M.-C. Wu, J.S. Corneille, C.A. Estrada, J.-W. He, D.W. Goodman, Synthesis and characterization of ultra-thin MgO films on Mo(100). Chem. Phys. Lett. 182, 472–478 (1991)
66. U. Heiz, F. Vanolli, L. Trento, W.-D. Schneider, Chemical reactivity of size-selected supported clusters: an experimental setup. Rev. Sci. Instrum. 68, 1986–1994 (1997)
67. M. Sterrer, E. Fischbach, T. Risse, H.-J. Freund, Geometric characterization of a singly
charged oxygen vacancy on a single-crystalline MgO(001) film by electron paramagnetic
resonance spectroscopy. Phys. Rev. Lett. 94, 186101 (2005)
68. M.E. Vaida, T.M. Bernhardt, Surface-aligned femtochemistry: photoinduced reaction dynamics of CH 3 I and CH 3 Br on MgO(100). Faraday Discuss. 157, 437–449 (2012)
69. V.P. Holbert, S.J. Garrett, J.C. Bruns, P.C. Stair, E. Weitz, A novel method for determining
absolute coverages by temperature programmed desorption with application to the adsorption
of CH 3 I on MgO(100). Surf. Sci. 314, 107–113 (1994)
70. D.H. Fairbrother, K.A. Trentelman, P.G. Strupp, P.C. Stair, E. Weitz, Orientation of methyliodide adsorbed on MgO(100)—results from 257 nm photodissociation studies. J. Vac. Sci.
Technol. A 10, 2243–2247 (1992)
71. K.A. Trentelman, D.H. Fairbrother, P.G. Strupp, P.C. Stair, E. Weitz, 257 nm photoinduced
chemistry of methyl iodide adsorbed on MgO(100). J. Chem. Phys. 96, 9221–9232 (1992)
72. S.J. Garrett, D.V. Heyd, J.C. Polanyi, Photochemistry of adsorbed molecules. XVII. Photodissociation at 193 nm of CH 3 Br adsorbed on LiF(001) and NaCl(001). J. Chem. Phys.
106, 7834–7846 (1997)
73. J. Kutzner, G. Lindeke, K.H. Welge, D. Feldmann, Dissociative desorption from CH 3 I by
ultraviolet-laser radiation. J. Chem. Phys. 90, 548–555 (1989)
74. K.A. Trentelman, D.H. Fairbrother, P.C. Stair, P.G. Strupp, E. Weitz, A photofragment spectrometer for studying photodissociation of molecules adsorbed on surfaces: the 257 nm photolysis of CD 3 I on MgO(100). J. Vac. Sci. Technol. A 9, 1820–1822 (1991)
75. D.H. Fairbrother, K.A. Briggman, P.C. Stair, E. Weitz, Molecular orientation and surface morphology in methyl iodide films grown on MgO(100) probed by photodissociation.
J. Phys. Chem. 98, 13042–13049 (1994)
M.E. Vaida and T.M. Bernhardt
56. I.R. McNab, J.C. Polanyi, Patterned atomic reaction at surfaces. Chem. Rev. 106, 4321–4354
(2006)
57. K.R. Harikumar, I.R. McNab, J.C. Polanyi, A. Zabet-Khosousi, W.A. Hofer, Imprinting selfassembled patterns of lines at a semiconductor surface, using heat, light, or electrons. Proc.
Natl. Acad. Sci. USA 108, 950–955 (2011)
58. D.P. Zhong, A.H. Zewail, Femtosecond real-time probing of reactions. 23. Studies of temporal, velocity, angular, and state dynamics from transition states to final products by
femtosecond-resolved mass spectrometry. J. Phys. Chem. A 102, 4031–4058 (1998)
59. R. de Nalda, J.G. Izquierdo, J. Durá, L. Bañares, Femtosecond multichannel photodissociation dynamics of CH 3 I from the A band by velocity map imaging. J. Chem. Phys. 126,
021101 (2007)
60. R. de Nalda, J. Durá, A. Garcia-Vela, J.G. Izquierdo, J. González-Vázquez, L. Bañares, A detailed experimental and theoretical study of the femtosecond A-band photodissociation of
CH 3 I. J. Chem. Phys. 128, 244309 (2008)
61. J. Durá, R. De Nalda, J. Álvarez, J.G. Izquierdo, G.A. Amaral, L. Bañares, Femtosecond
transition-state imaging of the A-band CH 3 I photodissociation. Chem. Phys. Chem. 9, 1245–
1249 (2008)
62. J. Durá, R. de Nalda, G.A. Amaral, L. Bañares, Imaging transient species in the femtosecond
A-band photodissociation of CH 3 I. J. Chem. Phys. 131, 134311 (2009)
63. L. Rubio-Lago, J.D. Rodrigues, A. García-Vela, M.G. Gonzàlez, G.A. Amaral, L. Bañares,
A slice imaging and multisurface wave packet study of the photodissociation of CH 3 I at
304 nm. Phys. Chem. Chem. Phys. 13, 8186–8194 (2011)
64. M.E. Vaida, T. Gleitsmann, R. Tchitnga, T.M. Bernhardt, Femtosecond-laser photoemission
spectroscopy of Mo(100) covered by ultrathin MgO(100) films of variable thickness. J. Phys.
Chem. C 113, 10264–10268 (2009)
65. M.-C. Wu, J.S. Corneille, C.A. Estrada, J.-W. He, D.W. Goodman, Synthesis and characterization of ultra-thin MgO films on Mo(100). Chem. Phys. Lett. 182, 472–478 (1991)
66. U. Heiz, F. Vanolli, L. Trento, W.-D. Schneider, Chemical reactivity of size-selected supported clusters: an experimental setup. Rev. Sci. Instrum. 68, 1986–1994 (1997)
67. M. Sterrer, E. Fischbach, T. Risse, H.-J. Freund, Geometric characterization of a singly
charged oxygen vacancy on a single-crystalline MgO(001) film by electron paramagnetic
resonance spectroscopy. Phys. Rev. Lett. 94, 186101 (2005)
68. M.E. Vaida, T.M. Bernhardt, Surface-aligned femtochemistry: photoinduced reaction dynamics of CH 3 I and CH 3 Br on MgO(100). Faraday Discuss. 157, 437–449 (2012)
69. V.P. Holbert, S.J. Garrett, J.C. Bruns, P.C. Stair, E. Weitz, A novel method for determining
absolute coverages by temperature programmed desorption with application to the adsorption
of CH 3 I on MgO(100). Surf. Sci. 314, 107–113 (1994)
70. D.H. Fairbrother, K.A. Trentelman, P.G. Strupp, P.C. Stair, E. Weitz, Orientation of methyliodide adsorbed on MgO(100)—results from 257 nm photodissociation studies. J. Vac. Sci.
Technol. A 10, 2243–2247 (1992)
71. K.A. Trentelman, D.H. Fairbrother, P.G. Strupp, P.C. Stair, E. Weitz, 257 nm photoinduced
chemistry of methyl iodide adsorbed on MgO(100). J. Chem. Phys. 96, 9221–9232 (1992)
72. S.J. Garrett, D.V. Heyd, J.C. Polanyi, Photochemistry of adsorbed molecules. XVII. Photodissociation at 193 nm of CH 3 Br adsorbed on LiF(001) and NaCl(001). J. Chem. Phys.
106, 7834–7846 (1997)
73. J. Kutzner, G. Lindeke, K.H. Welge, D. Feldmann, Dissociative desorption from CH 3 I by
ultraviolet-laser radiation. J. Chem. Phys. 90, 548–555 (1989)
74. K.A. Trentelman, D.H. Fairbrother, P.C. Stair, P.G. Strupp, E. Weitz, A photofragment spectrometer for studying photodissociation of molecules adsorbed on surfaces: the 257 nm photolysis of CD 3 I on MgO(100). J. Vac. Sci. Technol. A 9, 1820–1822 (1991)
75. D.H. Fairbrother, K.A. Briggman, P.C. Stair, E. Weitz, Molecular orientation and surface morphology in methyl iodide films grown on MgO(100) probed by photodissociation.
J. Phys. Chem. 98, 13042–13049 (1994)