10 Surface-Aligned Femtochemistry: Dynamics on Oxide Surfaces
257
34. V.J. Barclay, D.B. Jack, J.C. Polanyi, Y. Zeiri, Dynamics of surface-aligned photochemistry
(theory). 2. Localized h-atom scattering in the HBr(ad)/LiF(001)+hν system. J. Chem. Phys.
97, 9458–9467 (1992)
35. J. Kiss, D.J. Alberas, J.M. White, Surface-aligned photoreaction of DBr with C 2 H 4 on
Pt(111). J. Am. Chem. Soc. 114, 10486–10492 (1992)
36. S.J. Garrett, D.V. Heyd, J.C. Polanyi, Photochemistry of adsorbed molecules. XVIII. Photodissociation and exchange reaction in CH 3 Br/MgO(001) at 193 nm. J. Chem. Phys. 106,
7847–7855 (1997)
37. T. Yamanaka, Y. Inoue, T. Matsushima, An aligned oxidation of carbon monoxide induced
by 193 nm irradiation on platinum(113). Chem. Phys. Lett. 264, 180–185 (1997)
38. J.B. Giorgi, R. Kühnemuth, J.C. Polanyi, Surface-aligned photochemistry: photolysis of HCl
adsorbed on LiF(001) studied by Rydberg-atom time-of-flight spectroscopy. J. Chem. Phys.
110, 598–605 (1999)
39. J.B. Giorgi, F.Y. Naumkin, J.C. Polanyi, S.A. Raspopov, N.S.K. Sze, Surface aligned photochemistry: photodissociation of Cl 2 and Cl 2 · · ·Cl adsorbed on LiF(001). J. Chem. Phys.
112, 9569–9581 (2000)
40. J.B. Giorgi, R. Kühnemuth, J.C. Polanyi, Surface-aligned photochemistry: photodissociation
of H 2 S adsorbed on LiF(001) studied by Rydberg-atom time-of-flight spectroscopy. J. Chem.
Phys. 113, 807–814 (2000)
41. C.E. Tripa, J.T. Yates Jr., Surface-aligned reaction of photogenerated oxygen atoms with
carbonmonoxide targets. Nature 398, 591–593 (1999)
42. M. Kim, J.N. Hohman, Y. Cao, K.N. Houk, H. Ma, A.K.-Y. Jen, P.S. Weiss, Creating favorable geometries for directing organic photoreactions in alkanethiolate monolayers. Science
331, 1312–1315 (2011)
43. S.-W. Hla, L. Bartels, G. Meyer, K.H. Rieder, Inducing all steps of a chemical reaction with
the scanning tunneling microscope tip: towards single molecule engineering. Phys. Rev. Lett.
85, 2777–2780 (2000)
44. S.W. Hla, G. Meyer, K.H. Rieder, Inducing single-molecule chemical reactions with a UHVSTM: a new dimension for nano-science and technology. Chem. Phys. Chem. 2, 361–366
(2001)
45. P. Maksymovych, J.T. Yates Jr., Propagation of conformation in the surface-aligned dissociation of single CH 3 SSCH 3 molecules on Au(111). J. Am. Chem. Soc. 128, 10642 (2006)
46. K.R. Harikumar, J.C. Polanyi, A. Zabet-Khosousi, P. Czekala, H. Lin, W.A. Hofer, Directed long-range molecular migration energized by surface reaction. Nat. Chem. 3, 400–408
(2011)
47. K. Huang, I.R. McNab, J.C. Polanyi, S.Y. Yang, Adsorbate alignment in surface halogenation: standing up is better than lying down. Angew. Chem., Int. Ed. Engl. 51, 9061–9065
(2012)
48. J.-G. Lee, S.-H. Hong, J. Ahner, J.T. Yates Jr., Surface aligned ion-molecule reaction: direct
observation of initial and final ion momenta. Phys. Rev. Lett. 89, 253202 (2002)
49. J.-G. Lee, J.T. Yates Jr., Surface-aligned ion-molecule reaction on the surface of a molecular
crystal CD
+
3 + CD 3 I → C 2 D
+
5 + DI. J. Am. Chem. Soc. 126, 13071–13078 (2004)
50. C. Akerlund, I. Zoric, B. Kasemo, A collision induced reaction: CO 2 production on O 2 and
CO covered Pt(111). J. Chem. Phys. 104, 7359–7362 (1996)
51. P. Maksymovych, D.C. Sorescu, K.D. Jordan, J.T. Yates Jr., Collective reactivity of molecular
chains self-assembled on a surface. Science 322, 1664–1667 (2008)
52. S. Dobrin, K.R. Harikumar, J.C. Polanyi, An STM study of the localized atomic reaction of
1, 2- and 1, 4-dibromobenzene at Si(111) − 7 × 7. Surf. Sci. 561, 11–24 (2004)
53. S. Dobrin, K.R. Harikumar, C.F. Matta, J.C. Polanyi, An STM study of the localized atomic
reaction of 1, 2- and 1, 4-dibromoxylene with Si(111) − 7 × 7. Surf. Sci. 580, 39–50 (2005)
54. H. Guo, J. Wei, J.C. Polanyi, S.Y. Yang, Molecular dynamics of localized reaction, experiment and theory: methyl bromide on Si(111) − 7 × 7. ACS Nano 2, 699–706 (2008)
55. L. Leung, T. Lim, Z. Ning, J.C. Polanyi, Localized reaction at a smooth metal surface: pdiiodobenzene at Cu(110). J. Am. Chem. Soc. 134, 9320–9326 (2012)
257
34. V.J. Barclay, D.B. Jack, J.C. Polanyi, Y. Zeiri, Dynamics of surface-aligned photochemistry
(theory). 2. Localized h-atom scattering in the HBr(ad)/LiF(001)+hν system. J. Chem. Phys.
97, 9458–9467 (1992)
35. J. Kiss, D.J. Alberas, J.M. White, Surface-aligned photoreaction of DBr with C 2 H 4 on
Pt(111). J. Am. Chem. Soc. 114, 10486–10492 (1992)
36. S.J. Garrett, D.V. Heyd, J.C. Polanyi, Photochemistry of adsorbed molecules. XVIII. Photodissociation and exchange reaction in CH 3 Br/MgO(001) at 193 nm. J. Chem. Phys. 106,
7847–7855 (1997)
37. T. Yamanaka, Y. Inoue, T. Matsushima, An aligned oxidation of carbon monoxide induced
by 193 nm irradiation on platinum(113). Chem. Phys. Lett. 264, 180–185 (1997)
38. J.B. Giorgi, R. Kühnemuth, J.C. Polanyi, Surface-aligned photochemistry: photolysis of HCl
adsorbed on LiF(001) studied by Rydberg-atom time-of-flight spectroscopy. J. Chem. Phys.
110, 598–605 (1999)
39. J.B. Giorgi, F.Y. Naumkin, J.C. Polanyi, S.A. Raspopov, N.S.K. Sze, Surface aligned photochemistry: photodissociation of Cl 2 and Cl 2 · · ·Cl adsorbed on LiF(001). J. Chem. Phys.
112, 9569–9581 (2000)
40. J.B. Giorgi, R. Kühnemuth, J.C. Polanyi, Surface-aligned photochemistry: photodissociation
of H 2 S adsorbed on LiF(001) studied by Rydberg-atom time-of-flight spectroscopy. J. Chem.
Phys. 113, 807–814 (2000)
41. C.E. Tripa, J.T. Yates Jr., Surface-aligned reaction of photogenerated oxygen atoms with
carbonmonoxide targets. Nature 398, 591–593 (1999)
42. M. Kim, J.N. Hohman, Y. Cao, K.N. Houk, H. Ma, A.K.-Y. Jen, P.S. Weiss, Creating favorable geometries for directing organic photoreactions in alkanethiolate monolayers. Science
331, 1312–1315 (2011)
43. S.-W. Hla, L. Bartels, G. Meyer, K.H. Rieder, Inducing all steps of a chemical reaction with
the scanning tunneling microscope tip: towards single molecule engineering. Phys. Rev. Lett.
85, 2777–2780 (2000)
44. S.W. Hla, G. Meyer, K.H. Rieder, Inducing single-molecule chemical reactions with a UHVSTM: a new dimension for nano-science and technology. Chem. Phys. Chem. 2, 361–366
(2001)
45. P. Maksymovych, J.T. Yates Jr., Propagation of conformation in the surface-aligned dissociation of single CH 3 SSCH 3 molecules on Au(111). J. Am. Chem. Soc. 128, 10642 (2006)
46. K.R. Harikumar, J.C. Polanyi, A. Zabet-Khosousi, P. Czekala, H. Lin, W.A. Hofer, Directed long-range molecular migration energized by surface reaction. Nat. Chem. 3, 400–408
(2011)
47. K. Huang, I.R. McNab, J.C. Polanyi, S.Y. Yang, Adsorbate alignment in surface halogenation: standing up is better than lying down. Angew. Chem., Int. Ed. Engl. 51, 9061–9065
(2012)
48. J.-G. Lee, S.-H. Hong, J. Ahner, J.T. Yates Jr., Surface aligned ion-molecule reaction: direct
observation of initial and final ion momenta. Phys. Rev. Lett. 89, 253202 (2002)
49. J.-G. Lee, J.T. Yates Jr., Surface-aligned ion-molecule reaction on the surface of a molecular
crystal CD
+
3 + CD 3 I → C 2 D
+
5 + DI. J. Am. Chem. Soc. 126, 13071–13078 (2004)
50. C. Akerlund, I. Zoric, B. Kasemo, A collision induced reaction: CO 2 production on O 2 and
CO covered Pt(111). J. Chem. Phys. 104, 7359–7362 (1996)
51. P. Maksymovych, D.C. Sorescu, K.D. Jordan, J.T. Yates Jr., Collective reactivity of molecular
chains self-assembled on a surface. Science 322, 1664–1667 (2008)
52. S. Dobrin, K.R. Harikumar, J.C. Polanyi, An STM study of the localized atomic reaction of
1, 2- and 1, 4-dibromobenzene at Si(111) − 7 × 7. Surf. Sci. 561, 11–24 (2004)
53. S. Dobrin, K.R. Harikumar, C.F. Matta, J.C. Polanyi, An STM study of the localized atomic
reaction of 1, 2- and 1, 4-dibromoxylene with Si(111) − 7 × 7. Surf. Sci. 580, 39–50 (2005)
54. H. Guo, J. Wei, J.C. Polanyi, S.Y. Yang, Molecular dynamics of localized reaction, experiment and theory: methyl bromide on Si(111) − 7 × 7. ACS Nano 2, 699–706 (2008)
55. L. Leung, T. Lim, Z. Ning, J.C. Polanyi, Localized reaction at a smooth metal surface: pdiiodobenzene at Cu(110). J. Am. Chem. Soc. 134, 9320–9326 (2012)