Ethylene propylene (EP), 210
diene, 238
Ethylene-vinyl acetate (EVA), 237
Ethyl p-ethoxybenzoate, 93
Evaporative light scattering detector (ELSD), 236
F
Field flow fractionation (FFF), 203, 211, 217
G
Gas-phase polymerization, video microscopy, 30
Gel permeation chromatography (GPC), 203,
206, 211
H
Heterogeneous model catalysts, 135
High-performance liquid chromatography
(HPLC), 222, 236
High-temperature liquid chromatography, 203
Homogeneous model catalysts, 135
HPLC. See High-performance liquid
chromatography (HPLC)
Hydrogen effect, 110, 122
I
Isotacticity, 81
Ivin–Rooney–Green chain propagation, 139
K
Kinetic analysis, 1, 99
M
Malonate, 85
MAO, 20
Martin, Heinz, 5
Metal-alkyl-free (MAF) catalysts, 39
Metallocenes, 20, 138
MAO catalysts, silica-supported, 26
propene polymerization, 106
stereorigid bridged, 20
Metallorganic catalysts, 99
Metallorganische Mischkatalysatoren, 2, 40
Molar mass distribution (MMD), 211
Molecular mechanics (MM), 22, 47
Molecular modeling, 135
Monochromate, 138
N
Natta, Giulio, 37, 54
Ni-based catalysts, 40
O
Olefin polymerization, 99
kinetics, 101
P
Phillips catalysts, activation, 142, 147
molecular models, 178
Ti-modified, 153, 187
Phillips Cr/silica catalyst, 135
Phthalate, 84, 91
Plug flow reactor, 13
Poly(methyl methacrylate) (PMMA), 217
Polychromate, 138
Polyethylene, 135
high-density, 59, 60, 74, 138, 207
linear low-density (LLDPE), 207
low-density (LDPE), 208
microstructure, 207
Polymer fractionation, 219
Polymerization kinetics, 135
Polyolefins, 2
Polypropylene, atactic, 209
isotactic, 37, 81, 209
microstructure, 209
propene insertion, 41
syntactic, 209
ZN catalysts, 39
Process control/design/modelling, 59
Product portfolio, 59
Propene insertion, 41
Propylene polymerization, 81
stereospecific, 23
Q
Quantum mechanics (QM), 22, 43
S
Silica-supported metallocene/MAO catalysts, 1
Single-site catalysts, 20
Size-exclusion chromatography (SEC),
203, 211
Slurry polymerization, 59
Solubility distribution breadth index (SDBI),
227
256
Index