Index
A
Active site number, 99
Advanced cascade process (ACP), 70, 75
Alkyl aluminum, 6
Aluminum alkyls, 59, 64, 93
B
Benzoate, 81–84, 91
Bis(triphenylsilyl) chromate (BC), 140
Bis(perhydroquinolino)dimethoxysilane, 85
Bis(cyclopentadienyl) group IV, 6
Bivariate distribution, 241
C
Catalysts, bimetallic, 195
main group metal-alkyl-free (MAF), 39
metallocene/MAO, 26
multiple-site, 206
Ni-based, 41
organometallic mixed, 2
single-site, 20, 206, 208
superactive, 61, 63
TiCl 3 , 37, 42, 44, 85
Chain propagation constant, 17
Chemical composition distribution (CCD), 218
Chromate, hexavalent, 138
Chromocene, 140
Comonomer effect (CEF), 114
Composition distribution breadth index
(CDBI), 227
Cossee–Arlman chain propagation, 45, 140,
151, 185
Cr-alkylidene, 13
Cr-carbene, 139
Cr–C bond, 185
Cross-fractionation chromatography, 203
Crystallization analysis fractionation, 203
Crystallization elution fractionation (CEF),
203, 219, 233
Crystallization temperatures in solution
(CRYSTAF), 210, 219, 228
Cyclohexyl(methyl)dimethoxysilane, 93
Cyclopentylisoquinolinodimethoxysilane, 85
D
Density functional theory (DFT), 22, 52, 88,
92, 107, 178
Dialkoxysilane, 84
Dichromate, 138
Dicyclopentyldimethoxysilane, 93
Diethylaluminum chloride (DEAC), 82
Differential scanning calorimetry (DSC), 220
Dimethylaminotriethoxysilane, 85
Disobutylphthalate, 93
Donor, 81
Drop-in catalysts, 26
Dynamic crystallization (DC), 233
E
Equivalent circle diameter (ECD), 30
Equivalent sphere volume (ESV), 30
Ethene/α-olefin copolymerization, 113
Ethene polymerization, 64
Ethylbenzoate (EB), 83
Ethylene glycol monobutyl ether (EGMBE),
237
Ethylenemethyl acrylate (EMA), 237
Ethylene, polymerization, 7, 135, 138
mechanisms, 135
NMR tube, 10
255