37
Hammond OS, Bowron DT, Jackson AJ, Arnold T, Sanchez-Fernandez A, Tsapatsaris N, Garcia
Sakai V, Edler KJ (2017b) Resilience of malic acid natural deep eutectic solvent nanostructure
to solidification and hydration. J Phys Chem B 121(31):7473–7483. https://doi.org/10.1021/
acs.jpcb.7b05454
Haraźna K, Walas K, Urbańska P, Witko T, Snoch W, Siemek A, Jachimska B, Krzan M,
Napruszewska BD, Witko M, Bednarz S, Guzik M (2019) Polyhydroxyalkanoate-derived
hydrogen-bond donors for the synthesis of new deep eutectic solvents. Green Chem
21(11):3116–3126. https://doi.org/10.1039/C9GC00387H
Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi T, Al-Wahaibi YM, Hashim MA (2012) Fruit
sugar-based deep eutectic solvents and their physical properties. Thermochim Acta 541:70–75.
https://doi.org/10.1016/j.tca.2012.04.030
Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi YM, Al-Wahaibi T, Hashim MA (2013) Glucosebased deep eutectic solvents: physical properties. J Mol Liq 178:137–141. https://doi.
org/10.1016/j.molliq.2012.11.025
Ibrahim RK, Hayyan M, AlSaadi MA, Ibrahim S, Hayyan A, Hashim MA (2019) Physical properties of ethylene glycol-based deep eutectic solvents. J Mol Liq 276:794–800. https://doi.
org/10.1016/j.molliq.2018.12.032
Jani A, Sohier T, Morineau D (2020) Phase behavior of aqueous solutions of ethaline deep eutectic
solvent. J Mol Liq 304:112701. https://doi.org/10.1016/j.molliq.2020.112701
Kamlet MJ, Taft RW (1976) The solvatochromic comparison method. I. the .Beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities. J Am Chem Soc 98(2):377–383. https://doi.
org/10.1021/ja00418a009
Kamlet MJ, Abboud JL, Taft RW (1977) The solvatochromic comparison method. 6. The .Pi.* scale
of solvent polarities. J Am Chem Soc 99(18):6027–6038. https://doi.org/10.1021/ja00460a031
Kareem MA, Mjalli FS, Hashim MA, AlNashef IM (2010) Phosphonium-based ionic liquids
analogues and their physical properties. J Chem Eng Data 55(11):4632–4637. https://doi.
org/10.1021/je100104v
Kaur S, Gupta A, Kashyap HK (2020) How hydration affects the microscopic structural morphology in a deep eutectic solvent. J Phys Chem B 124(11):2230–2237. https://doi.org/10.1021/
acs.jpcb.9b11753
Kim SH, Park S, Yu H, Kim JH, Kim HJ, Yang Y-H, Kim YH, Kim KJ, Kan E, Lee SH (2016)
Effect of deep eutectic solvent mixtures on lipase activity and stability. J Mol Catal B Enzym
128:65–72. https://doi.org/10.1016/j.molcatb.2016.03.012
Kumari P, Shobhna, Kaur S, Kashyap HK (2018) Influence of hydration on the structure of reline
deep eutectic solvent: a molecular dynamics study. ACS Omega 3(11):15246–15255. https://
doi.org/10.1021/acsomega.8b02447
Lapeña D, Lomba L, Artal M, Lafuente C, Giner B (2019) The NADES glyceline as a potential green solvent: a comprehensive study of its thermophysical properties and effect of water
inclusion. J Chem Thermodyn 128:164–172. https://doi.org/10.1016/j.jct.2018.07.031
López-Salas N, Vicent-Luna JM, Imberti S, Posada E, Roldán MJ, Anta JA, Balestra SRG,
Madero Castro RM, Calero S, Jiménez-Riobóo RJ, Gutiérrez MC, Ferrer ML, del Monte
F (2019) Looking at the “water-in-deep-eutectic-solvent” system: a dilution range for high
performance eutectics. ACS Sustain Chem Eng 7(21):17565–17573. https://doi.org/10.1021/
acssuschemeng.9b05096
Martins MAR, Crespo EA, Pontes PVA, Silva LP, Bülow M, Maximo GJ, Batista EAC, Held
C, Pinho SP, Coutinho JAP (2018) Tunable hydrophobic eutectic solvents based on terpenes
and monocarboxylic acids. ACS Sustain Chem Eng 6(7):8836–8846. https://doi.org/10.1021/
acssuschemeng.8b01203
Martins MAR, Pinho SP, Coutinho JAP (2019) Insights into the nature of eutectic and deep eutectic mixtures. J Solut Chem 48(7):962–982. https://doi.org/10.1007/s10953-018-0793-1
1 Understanding the Basics and Properties of Deep Eutectic Solvents
Hammond OS, Bowron DT, Jackson AJ, Arnold T, Sanchez-Fernandez A, Tsapatsaris N, Garcia
Sakai V, Edler KJ (2017b) Resilience of malic acid natural deep eutectic solvent nanostructure
to solidification and hydration. J Phys Chem B 121(31):7473–7483. https://doi.org/10.1021/
acs.jpcb.7b05454
Haraźna K, Walas K, Urbańska P, Witko T, Snoch W, Siemek A, Jachimska B, Krzan M,
Napruszewska BD, Witko M, Bednarz S, Guzik M (2019) Polyhydroxyalkanoate-derived
hydrogen-bond donors for the synthesis of new deep eutectic solvents. Green Chem
21(11):3116–3126. https://doi.org/10.1039/C9GC00387H
Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi T, Al-Wahaibi YM, Hashim MA (2012) Fruit
sugar-based deep eutectic solvents and their physical properties. Thermochim Acta 541:70–75.
https://doi.org/10.1016/j.tca.2012.04.030
Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi YM, Al-Wahaibi T, Hashim MA (2013) Glucosebased deep eutectic solvents: physical properties. J Mol Liq 178:137–141. https://doi.
org/10.1016/j.molliq.2012.11.025
Ibrahim RK, Hayyan M, AlSaadi MA, Ibrahim S, Hayyan A, Hashim MA (2019) Physical properties of ethylene glycol-based deep eutectic solvents. J Mol Liq 276:794–800. https://doi.
org/10.1016/j.molliq.2018.12.032
Jani A, Sohier T, Morineau D (2020) Phase behavior of aqueous solutions of ethaline deep eutectic
solvent. J Mol Liq 304:112701. https://doi.org/10.1016/j.molliq.2020.112701
Kamlet MJ, Taft RW (1976) The solvatochromic comparison method. I. the .Beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities. J Am Chem Soc 98(2):377–383. https://doi.
org/10.1021/ja00418a009
Kamlet MJ, Abboud JL, Taft RW (1977) The solvatochromic comparison method. 6. The .Pi.* scale
of solvent polarities. J Am Chem Soc 99(18):6027–6038. https://doi.org/10.1021/ja00460a031
Kareem MA, Mjalli FS, Hashim MA, AlNashef IM (2010) Phosphonium-based ionic liquids
analogues and their physical properties. J Chem Eng Data 55(11):4632–4637. https://doi.
org/10.1021/je100104v
Kaur S, Gupta A, Kashyap HK (2020) How hydration affects the microscopic structural morphology in a deep eutectic solvent. J Phys Chem B 124(11):2230–2237. https://doi.org/10.1021/
acs.jpcb.9b11753
Kim SH, Park S, Yu H, Kim JH, Kim HJ, Yang Y-H, Kim YH, Kim KJ, Kan E, Lee SH (2016)
Effect of deep eutectic solvent mixtures on lipase activity and stability. J Mol Catal B Enzym
128:65–72. https://doi.org/10.1016/j.molcatb.2016.03.012
Kumari P, Shobhna, Kaur S, Kashyap HK (2018) Influence of hydration on the structure of reline
deep eutectic solvent: a molecular dynamics study. ACS Omega 3(11):15246–15255. https://
doi.org/10.1021/acsomega.8b02447
Lapeña D, Lomba L, Artal M, Lafuente C, Giner B (2019) The NADES glyceline as a potential green solvent: a comprehensive study of its thermophysical properties and effect of water
inclusion. J Chem Thermodyn 128:164–172. https://doi.org/10.1016/j.jct.2018.07.031
López-Salas N, Vicent-Luna JM, Imberti S, Posada E, Roldán MJ, Anta JA, Balestra SRG,
Madero Castro RM, Calero S, Jiménez-Riobóo RJ, Gutiérrez MC, Ferrer ML, del Monte
F (2019) Looking at the “water-in-deep-eutectic-solvent” system: a dilution range for high
performance eutectics. ACS Sustain Chem Eng 7(21):17565–17573. https://doi.org/10.1021/
acssuschemeng.9b05096
Martins MAR, Crespo EA, Pontes PVA, Silva LP, Bülow M, Maximo GJ, Batista EAC, Held
C, Pinho SP, Coutinho JAP (2018) Tunable hydrophobic eutectic solvents based on terpenes
and monocarboxylic acids. ACS Sustain Chem Eng 6(7):8836–8846. https://doi.org/10.1021/
acssuschemeng.8b01203
Martins MAR, Pinho SP, Coutinho JAP (2019) Insights into the nature of eutectic and deep eutectic mixtures. J Solut Chem 48(7):962–982. https://doi.org/10.1007/s10953-018-0793-1
1 Understanding the Basics and Properties of Deep Eutectic Solvents