36
Fahri F, Bacha K, Chiki FF, Mbakidi J-P, Panda S, Bouquillon S, Fourmentin S (2020) Air pollution: new bio-based ionic liquids absorb both hydrophobic and hydrophilic volatile organic
compounds with high efficiency. Environ Chem Lett 18:1403–1411. https://doi.org/10.1007/
s10311-020-01007-8
Fetisov EO, Harwood DB, Kuo I-FW, Warrag SEE, Kroon MC, Peters CJ, Siepmann JI (2018)
First-principles molecular dynamics study of a deep eutectic solvent: choline chloride/urea
and its mixture with water. J Phys Chem B 122(3):1245–1254. https://doi.org/10.1021/acs.
jpcb.7b10422
Florindo C, Oliveira FS, Rebelo LPN, Fernandes AM, Marrucho IM (2014) Insights into the synthesis and properties of deep eutectic solvents based on Cholinium chloride and carboxylic
acids. ACS Sustain Chem Eng 2(10):2416–2425. https://doi.org/10.1021/sc500439w
Florindo C, McIntosh AJS, Welton T, Branco LC, Marrucho MI (2018) A closer look into deep
eutectic solvents: Exploring intermolecular interactions using solvatochromic probes. Phys
Chem Chem Phys 20(1):206–213. https://doi.org/10.1039/C7CP06471C
Florindo C, Branco LC, Marrucho IM (2019) Quest for green-solvent design: from hydrophilic
to hydrophobic (deep) eutectic solvents. ChemSusChem 12(8):1549–1559. https://doi.
org/10.1002/cssc.201900147
Francisco M, van den Bruinhorst A, Kroon MC (2012) New natural and renewable low transition
temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing.
Green Chem 14(8):2153–2157. https://doi.org/10.1039/C2GC35660K
Gabriele F, Chiarini M, Germani R, Tiecco M, Spreti N (2019) Effect of water addition on choline
chloride/glycol deep eutectic solvents: characterization of their structural and physicochemical
properties. J Mol Liq 291:111301. https://doi.org/10.1016/j.molliq.2019.111301
Gao Q, Zhu Y, Ji X, Zhu W, Lu L, Lu X (2018) Effect of water concentration on the microstructures
of choline chloride/urea (1:2) /water mixture. Fluid Phase Equilib 470:134–139. https://doi.
org/10.1016/j.fluid.2018.01.031
García G, Aparicio S, Ullah R, Atilhan M (2015) Deep eutectic solvents: physicochemical properties and gas separation applications. Energy Fuel 29(4):2616–2644. https://doi.org/10.1021/
ef5028873
Germani R, Orlandini M, Tiecco M, Del Giacco T (2017) Novel low viscous, green and amphiphilic N-oxides/phenylacetic acid based deep eutectic solvents. J Mol Liq 240:233–239. https://
doi.org/10.1016/j.molliq.2017.05.084
Gomez FJV, Espino M, Fernández MA, Silva MF (2018) A greener approach to prepare natural
deep eutectic solvents. Chem Select 3(22):6122–6125. https://doi.org/10.1002/slct.201800713
González CG, Mustafa NR, Wilson EG, Verpoorte R, Choi YH (2018) Application of natural
deep eutectic solvents for the “green”extraction of vanillin from vanilla pods. Flavour Fragr J
33(1):91–96. https://doi.org/10.1002/ffj.3425
Gutiérrez MC, Ferrer ML, Mateo CR, del Monte F (2009) Freeze-drying of aqueous solutions
of deep eutectic solvents: a suitable approach to deep eutectic suspensions of self-assembled
structures. Langmuir 25(10):5509–5515. https://doi.org/10.1021/la900552b
Hadj-Kali MK, Al-khidir KE, Wazeer I, El-blidi L, Mulyono S, AlNashef IM (2015) Application
of deep eutectic solvents and their individual constituents as surfactants for enhanced oil
recovery. Colloids Surf A Physicochem Eng Asp 487:221–231. https://doi.org/10.1016/j.
colsurfa.2015.10.005
Häkkinen R, Willberg-Keyriläinen P, Ropponen J, Virtanen T (2019) Effect of composition and
water content on physicochemical properties of choline chloride-boric acid low-melting mixtures. J Mol Liq 280:104–110. https://doi.org/10.1016/j.molliq.2019.02.011
Hammond OS, Bowron DT, Edler KJ (2017a) The effect of water upon deep eutectic solvent nanostructure: an unusual transition from ionic mixture to aqueous solution. Angew Chem Int Ed
56(33):9782–9785. https://doi.org/10.1002/anie.201702486
T. El Achkar et al.
Fahri F, Bacha K, Chiki FF, Mbakidi J-P, Panda S, Bouquillon S, Fourmentin S (2020) Air pollution: new bio-based ionic liquids absorb both hydrophobic and hydrophilic volatile organic
compounds with high efficiency. Environ Chem Lett 18:1403–1411. https://doi.org/10.1007/
s10311-020-01007-8
Fetisov EO, Harwood DB, Kuo I-FW, Warrag SEE, Kroon MC, Peters CJ, Siepmann JI (2018)
First-principles molecular dynamics study of a deep eutectic solvent: choline chloride/urea
and its mixture with water. J Phys Chem B 122(3):1245–1254. https://doi.org/10.1021/acs.
jpcb.7b10422
Florindo C, Oliveira FS, Rebelo LPN, Fernandes AM, Marrucho IM (2014) Insights into the synthesis and properties of deep eutectic solvents based on Cholinium chloride and carboxylic
acids. ACS Sustain Chem Eng 2(10):2416–2425. https://doi.org/10.1021/sc500439w
Florindo C, McIntosh AJS, Welton T, Branco LC, Marrucho MI (2018) A closer look into deep
eutectic solvents: Exploring intermolecular interactions using solvatochromic probes. Phys
Chem Chem Phys 20(1):206–213. https://doi.org/10.1039/C7CP06471C
Florindo C, Branco LC, Marrucho IM (2019) Quest for green-solvent design: from hydrophilic
to hydrophobic (deep) eutectic solvents. ChemSusChem 12(8):1549–1559. https://doi.
org/10.1002/cssc.201900147
Francisco M, van den Bruinhorst A, Kroon MC (2012) New natural and renewable low transition
temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing.
Green Chem 14(8):2153–2157. https://doi.org/10.1039/C2GC35660K
Gabriele F, Chiarini M, Germani R, Tiecco M, Spreti N (2019) Effect of water addition on choline
chloride/glycol deep eutectic solvents: characterization of their structural and physicochemical
properties. J Mol Liq 291:111301. https://doi.org/10.1016/j.molliq.2019.111301
Gao Q, Zhu Y, Ji X, Zhu W, Lu L, Lu X (2018) Effect of water concentration on the microstructures
of choline chloride/urea (1:2) /water mixture. Fluid Phase Equilib 470:134–139. https://doi.
org/10.1016/j.fluid.2018.01.031
García G, Aparicio S, Ullah R, Atilhan M (2015) Deep eutectic solvents: physicochemical properties and gas separation applications. Energy Fuel 29(4):2616–2644. https://doi.org/10.1021/
ef5028873
Germani R, Orlandini M, Tiecco M, Del Giacco T (2017) Novel low viscous, green and amphiphilic N-oxides/phenylacetic acid based deep eutectic solvents. J Mol Liq 240:233–239. https://
doi.org/10.1016/j.molliq.2017.05.084
Gomez FJV, Espino M, Fernández MA, Silva MF (2018) A greener approach to prepare natural
deep eutectic solvents. Chem Select 3(22):6122–6125. https://doi.org/10.1002/slct.201800713
González CG, Mustafa NR, Wilson EG, Verpoorte R, Choi YH (2018) Application of natural
deep eutectic solvents for the “green”extraction of vanillin from vanilla pods. Flavour Fragr J
33(1):91–96. https://doi.org/10.1002/ffj.3425
Gutiérrez MC, Ferrer ML, Mateo CR, del Monte F (2009) Freeze-drying of aqueous solutions
of deep eutectic solvents: a suitable approach to deep eutectic suspensions of self-assembled
structures. Langmuir 25(10):5509–5515. https://doi.org/10.1021/la900552b
Hadj-Kali MK, Al-khidir KE, Wazeer I, El-blidi L, Mulyono S, AlNashef IM (2015) Application
of deep eutectic solvents and their individual constituents as surfactants for enhanced oil
recovery. Colloids Surf A Physicochem Eng Asp 487:221–231. https://doi.org/10.1016/j.
colsurfa.2015.10.005
Häkkinen R, Willberg-Keyriläinen P, Ropponen J, Virtanen T (2019) Effect of composition and
water content on physicochemical properties of choline chloride-boric acid low-melting mixtures. J Mol Liq 280:104–110. https://doi.org/10.1016/j.molliq.2019.02.011
Hammond OS, Bowron DT, Edler KJ (2017a) The effect of water upon deep eutectic solvent nanostructure: an unusual transition from ionic mixture to aqueous solution. Angew Chem Int Ed
56(33):9782–9785. https://doi.org/10.1002/anie.201702486
T. El Achkar et al.