Quantum Study of Helium Clusters Doped with Electronically Excited …
101
about the possibility of Cs
He n exciplexes with n = 2 or 3. Moreover, Moroshkin
et al. [34] estimated that in solid helium the Cs(6P 3/2 )
He n=2 exciplex is quenched
by a radiationless transformation into the larger Cs(6P 1/2 )
He n=6,7 complex through
the attachment of additional He atoms. For these reasons a more meticulous study
of first and second excited states of Cs in helium clusters is now in progress [72]. At
the moment I can observe that both triatomic Cs(6P 1/2,3/2 )
He n=2 exciplexes have
a linear structure with the Cs atom halfway between the He atoms and a closure at
seven He atoms for the first shell of the Cs(6P 1/2 )
He n=2 system. Both findings are
in agreement with the experiments [34].
References
1. Toennies J, Vilesov A (1998) Annu Rev Phys Chem 49:1
2. Lehmann K, Scoles G (1998) Science 279:2065
3. Reynolds PJ, Ceperley DM, Alder BJ, Lester WA (1982) J Chem Phys 77:5593
4. Germer EHTA, Stephenson JC, Cavanagh R (1994) Int Rev Phys Chem 13:41
5. Hartmann M, Miller RE, Toennies JP, Vilesov A (1995) Phys Rev Lett 75:1566
6. Hartmann M, Mielke F, Toennies JP, Vilesov AF, Benedek G (1996) Phys Rev Lett 76:4560
7. Levy D (2001) Special topic on helium nanodroplets: a novel medium for chemistry and physics.
J Chem Phys 115
8. Chatterley AS, Schouder C, Christiansen L, Shepperson B, Rasmussen MH, Stapelfeldt H
(2019) Nat Commun 10:133
9. Toennies JP, Vilesov AF, Whaley KB (2001) Phys Today 54:31
10. Higgins J, Callegari C, Reho J, Stienkemeier F, Ernst W, Lehmann K, Gutowski M, Scoles G
(1996) Science 273:629
11. Callegari C, Ernst WE (2011) In: Quack M, Merkt F (eds) Handbook of high-resolution spectroscopy. Wiley, Chichester
12. Pototschnig JV, Lackner F, Hauser AW, Ernst WE (2017) Phys Chem Chem Phys 19:14718
13. Stienkemeier F, Higgins J, Callegari C, Kanorsky S, Ernst W, Scoles G (1996) Z Phys D: At
Mol Clusters 38:253
14. Callegari C, Higgins J, Stienkemeier F, Scoles G (1998) J Phys Chem A 102:95
15. Bünermann O, Droppelmann G, Hernando A, Mayol R, Stienkemeier F (2007) J Phys Chem
A 111:12684
16. Lackner F, Poms J, Krois G, Pototschnig JV, Ernst WE (2013) J Phys Chem A 117:11866
17. Reho J, Callegari C, Higgins J, Lehmann KK, Scoles G, Ernst W (1997) Faraday Discuss
108:161
18. Reho J, Higgins J, Lehmann KK, Scoles G (2000) J Chem Phys 113:9686
19. Loginov E, Callegari C, Ancilotto F, Drabbels M (2011) J Phys Chem A 115:6779
20. Reho J, Higgins J, Lehmann KK, Scoles G (2000) J Chem Phys 113:9694
21. Pifrader A, Allard O, Auböck G, Callegari C, Ernst WE, Huber R, Ancilotto F (2010) J Chem
Phys 133:164502
22. Brühl F, Trasca R, Ernst W (2001) J Chem Phys 115:10220
23. Nagl J, Auböck G, Callegari C, Ernst WE (2007) Phys Rev Lett 98:075301
24. Auböck G, Nagl J, Callegari C, Ernst WE (2008) Phys Rev Lett 101:035301
25. Bünermann O, Mudrich M, Weidemüller M, Stienkemeier F (2004) J Chem Phys 121:8880
26. Kinoshita T, Takahashi Y, Yabuzaki T (1994) Phys Rev B 49:3648
27. Hirano K, Enomoto K, Kumakura M, Takahashi Y, Yabuzaki T (2003) Phys Rev A 68:012722
28. Enomoto K, Hirano K, Kumakura M, Takahashi Y, Yabuzaki T (2002) Phys Rev A 66:042505
29. Mudrich M, Stienkemeier F (2014) Int Rev Phys Chem 33:301
101
about the possibility of Cs
He n exciplexes with n = 2 or 3. Moreover, Moroshkin
et al. [34] estimated that in solid helium the Cs(6P 3/2 )
He n=2 exciplex is quenched
by a radiationless transformation into the larger Cs(6P 1/2 )
He n=6,7 complex through
the attachment of additional He atoms. For these reasons a more meticulous study
of first and second excited states of Cs in helium clusters is now in progress [72]. At
the moment I can observe that both triatomic Cs(6P 1/2,3/2 )
He n=2 exciplexes have
a linear structure with the Cs atom halfway between the He atoms and a closure at
seven He atoms for the first shell of the Cs(6P 1/2 )
He n=2 system. Both findings are
in agreement with the experiments [34].
References
1. Toennies J, Vilesov A (1998) Annu Rev Phys Chem 49:1
2. Lehmann K, Scoles G (1998) Science 279:2065
3. Reynolds PJ, Ceperley DM, Alder BJ, Lester WA (1982) J Chem Phys 77:5593
4. Germer EHTA, Stephenson JC, Cavanagh R (1994) Int Rev Phys Chem 13:41
5. Hartmann M, Miller RE, Toennies JP, Vilesov A (1995) Phys Rev Lett 75:1566
6. Hartmann M, Mielke F, Toennies JP, Vilesov AF, Benedek G (1996) Phys Rev Lett 76:4560
7. Levy D (2001) Special topic on helium nanodroplets: a novel medium for chemistry and physics.
J Chem Phys 115
8. Chatterley AS, Schouder C, Christiansen L, Shepperson B, Rasmussen MH, Stapelfeldt H
(2019) Nat Commun 10:133
9. Toennies JP, Vilesov AF, Whaley KB (2001) Phys Today 54:31
10. Higgins J, Callegari C, Reho J, Stienkemeier F, Ernst W, Lehmann K, Gutowski M, Scoles G
(1996) Science 273:629
11. Callegari C, Ernst WE (2011) In: Quack M, Merkt F (eds) Handbook of high-resolution spectroscopy. Wiley, Chichester
12. Pototschnig JV, Lackner F, Hauser AW, Ernst WE (2017) Phys Chem Chem Phys 19:14718
13. Stienkemeier F, Higgins J, Callegari C, Kanorsky S, Ernst W, Scoles G (1996) Z Phys D: At
Mol Clusters 38:253
14. Callegari C, Higgins J, Stienkemeier F, Scoles G (1998) J Phys Chem A 102:95
15. Bünermann O, Droppelmann G, Hernando A, Mayol R, Stienkemeier F (2007) J Phys Chem
A 111:12684
16. Lackner F, Poms J, Krois G, Pototschnig JV, Ernst WE (2013) J Phys Chem A 117:11866
17. Reho J, Callegari C, Higgins J, Lehmann KK, Scoles G, Ernst W (1997) Faraday Discuss
108:161
18. Reho J, Higgins J, Lehmann KK, Scoles G (2000) J Chem Phys 113:9686
19. Loginov E, Callegari C, Ancilotto F, Drabbels M (2011) J Phys Chem A 115:6779
20. Reho J, Higgins J, Lehmann KK, Scoles G (2000) J Chem Phys 113:9694
21. Pifrader A, Allard O, Auböck G, Callegari C, Ernst WE, Huber R, Ancilotto F (2010) J Chem
Phys 133:164502
22. Brühl F, Trasca R, Ernst W (2001) J Chem Phys 115:10220
23. Nagl J, Auböck G, Callegari C, Ernst WE (2007) Phys Rev Lett 98:075301
24. Auböck G, Nagl J, Callegari C, Ernst WE (2008) Phys Rev Lett 101:035301
25. Bünermann O, Mudrich M, Weidemüller M, Stienkemeier F (2004) J Chem Phys 121:8880
26. Kinoshita T, Takahashi Y, Yabuzaki T (1994) Phys Rev B 49:3648
27. Hirano K, Enomoto K, Kumakura M, Takahashi Y, Yabuzaki T (2003) Phys Rev A 68:012722
28. Enomoto K, Hirano K, Kumakura M, Takahashi Y, Yabuzaki T (2002) Phys Rev A 66:042505
29. Mudrich M, Stienkemeier F (2014) Int Rev Phys Chem 33:301