56
In the last four decades, numerous cyclodextrin-based materials have also been
synthetized. The list includes modified polymers obtained using grafting reactions
(Crini and Morcellet 2002; Kozlowski and Sliwa 2010); cross-linked materials
using reticulation or polymerization reaction, e.g., soluble or insoluble polymers
(gels/hydrogels, beads, sponges) and fibers (Fenyvesi 1988; Armspach et al. 1999;
Mocanu et al. 2001; Crini and Morcellet 2002; Crini 2005; Li 2009; Yang and Yang
2013; Aytac and Uyar 2017); functionalized materials prepared through coating or
grafting such as silica beads, e.g., Cyclobond
®
columns, or resins (Crini and
Morcellet 2002; Landy et al. 2012); and nanoporous frameworks containing cyclodextrins (Mahmud and Wilson 2016; Morin-Crini et al. 2018). These materials have
been proposed for potential applications in pharmacy (Fenyvesi 1988; Van de
Manakker et al. 2009; Muankaew and Loftsson 2018), chromatography (Ward and
Armstrong 1988; Schneiderman and Stalcup 2000; Szejtli 2002; Vetter and Bester
2006; Xiao et al. 2012), electrophoresis (Fanali 1993; Chankvetadze 2004; EscuderGilabert et al. 2014), textile (Buschmann et al. 1998; Szejtli 2003; Buschmann and
Schollmeyer 2004; Ammayappan and Moses 2009; Andreaus et al. 2010; Voncina
2011), supramolecular chemistry (Wenz 1994; Nepogodiev and Stoddart 1998;
Schneider and Yatsimirsky 2000; Wenz et al. 2006; Schneider 2012; Zhang and Ma
2013), enzymology (Komiyama 1996; Villalonga et al. 2007; Sonnendecker and
Zimmermann 2019a), food industry (Han 2005; Fenyvesi et al. 2016), and cosmetics (Buschmann and Schollmeyer 2002, 2004; Bilensoy 2011) and for environmental purposes (Gruiz et al. 2011; Morin-Crini et al. 2018; Crini et al. 2018).
1.4.10 The First Applications of Cyclodextrins
Table 1.4 shows selected historical landmarks in cyclodextrin fundamental science
and applications during the period of their development, from 1970 to 1990. Since the
1990s, a large number of generalist reviews and book chapters have been published on
Fig. 1.24 Examples of modified cyclodextrins
N. Morin-Crini et al.
In the last four decades, numerous cyclodextrin-based materials have also been
synthetized. The list includes modified polymers obtained using grafting reactions
(Crini and Morcellet 2002; Kozlowski and Sliwa 2010); cross-linked materials
using reticulation or polymerization reaction, e.g., soluble or insoluble polymers
(gels/hydrogels, beads, sponges) and fibers (Fenyvesi 1988; Armspach et al. 1999;
Mocanu et al. 2001; Crini and Morcellet 2002; Crini 2005; Li 2009; Yang and Yang
2013; Aytac and Uyar 2017); functionalized materials prepared through coating or
grafting such as silica beads, e.g., Cyclobond
®
columns, or resins (Crini and
Morcellet 2002; Landy et al. 2012); and nanoporous frameworks containing cyclodextrins (Mahmud and Wilson 2016; Morin-Crini et al. 2018). These materials have
been proposed for potential applications in pharmacy (Fenyvesi 1988; Van de
Manakker et al. 2009; Muankaew and Loftsson 2018), chromatography (Ward and
Armstrong 1988; Schneiderman and Stalcup 2000; Szejtli 2002; Vetter and Bester
2006; Xiao et al. 2012), electrophoresis (Fanali 1993; Chankvetadze 2004; EscuderGilabert et al. 2014), textile (Buschmann et al. 1998; Szejtli 2003; Buschmann and
Schollmeyer 2004; Ammayappan and Moses 2009; Andreaus et al. 2010; Voncina
2011), supramolecular chemistry (Wenz 1994; Nepogodiev and Stoddart 1998;
Schneider and Yatsimirsky 2000; Wenz et al. 2006; Schneider 2012; Zhang and Ma
2013), enzymology (Komiyama 1996; Villalonga et al. 2007; Sonnendecker and
Zimmermann 2019a), food industry (Han 2005; Fenyvesi et al. 2016), and cosmetics (Buschmann and Schollmeyer 2002, 2004; Bilensoy 2011) and for environmental purposes (Gruiz et al. 2011; Morin-Crini et al. 2018; Crini et al. 2018).
1.4.10 The First Applications of Cyclodextrins
Table 1.4 shows selected historical landmarks in cyclodextrin fundamental science
and applications during the period of their development, from 1970 to 1990. Since the
1990s, a large number of generalist reviews and book chapters have been published on
Fig. 1.24 Examples of modified cyclodextrins
N. Morin-Crini et al.