117. Tamimi A, Fayer MD (2016) Ionic liquid dynamics measured with 2D IR and IR pump-probe
experiments on a linear anion and the influence of potassium cations. J Phys Chem B
120:5842–5854. doi:10.1021/acs.jpcb.6b00409
118. Rosker MJ, Dantus M, Zewail AH (1988) Femtosecond real-time probing of reactions. I. The
technique. J Chem Phys 89:6113
119. Zewail AH (1988) Laser femtochemistry. Science (80-) 242:1645–1653
120. Motzkus M, Pedersen S, Zewail AH (1996) Femtosecond real-time probing of reactions. 19.
nonlinear (DFWM) techniques for probing transition states of uni- and bimolecular reactions. J Phys
Chem 100:5620–5633
121. Herbst J, Heyne K, Diller R (2002) Femtosecond infrared spectroscopy of bacteriorhodopsin
chromophore isomerization. Science (80-) 297:822–825
122. Kukura P, McCamant DW, Yoon S et al (2005) Structural observation of the primary isomerization
in vision with femtosecond-stimulated Raman. Science (80-) 310:1006–1009
123. Vos MH, Lambry JC, Robles SJ et al (1991) Direct observation of vibrational coherence in bacterial
reaction centers using femtosecond absorption-spectroscopy. Proc Natl Acad Sci USA
88:8885–8889
124. Rose TS, Rosker MJ, Zewail AH (1988) Femtosecond real-time observation of wave packet
oscillations (resonance) in dissociation reactions. J Chem Phys 88:6672–6673
125. Dantus M, Bowman RM, Gruebele M, Zewail AH (1989) Femtosecond real-time probing of
reactions. V. The reaction of IHgI. J Chem Phys 91:7437–7450
126. Kraack JP, Buckup T, Motzkus M (2013) Coherent high-frequency vibrational dynamics in the
excited electronic state of all-trans retinal derivatives. J Phys Chem Lett 383–387. doi:10.1021/
jz302001m
127. Kraack JP, Buckup T, Hampp N, Motzkus M (2011) Ground- and excited-state vibrational
coherence dynamics in bacteriorhodopsin probed with degenerate four-wave-mixing experiments.
ChemPhysChem 12:1851–1859. doi:10.1002/cphc.201100032
128. Kraack JP, Wand A, Buckup T et al (2013) Mapping multidimensional excited state dynamics using
pump-impulsive- vibrational-spectroscopy and pump-degenerate-four-wave-mixing. Phys Chem
Chem Phys 15:14487–14501. doi:10.1039/c3cp50871d
129. Gallagher Faeder SM, Jonas DM, Faeder SMG (1999) Two-dimensional electronic correlation and
relaxation spectra: theory and model calculations. J Phys Chem A 103:10489–10505. doi:10.1021/
jp9925738
130. Aue W, Bartholdi E, Ernst R (1976) Two-dimensional spectroscopy. Application to nuclear magnetic resonance. J Chem Phys 64:2229–2246. doi:10.1063/1.432450
131. Zheng J, Kwak K, Asbury J et al (2005) Ultrafast dynamics of solute- solvent complexation
observed at thermal equilibrium in real time. Science 309:1338–1343
132. Zheng J, Fayer MD (2007) Hydrogen bond lifetimes and energetics for solute/solvent complexes
studied with 2D-IR vibrational echo spectroscopy. J Am Chem Soc 94305:4328–4335
133. Kwak K, Zheng J, Cang H, Fayer MD (2006) Ultrafast two-dimensional infrared vibrational echo
chemical exchange experiments and theory. J Phys Chem B 110:19998–20013. doi:10.1021/
jp0624808
134. Kwak K, Park S, Fayer MD (2007) Dynamics around solutes and solute-solvent complexes in mixed
solvents. Proc Natl Acad Sci USA 104:14221–14226. doi:10.1073/pnas.0701710104
135. Rosenfeld DE, Kwak K, Gengeliczki Z, Fayer MD (2010) Hydrogen bond migration between
molecular sites observed with ultrafast 2D IR chemical exchange spectroscopy. J Phys Chem B
114:2383–2389. doi:10.1021/jp911452z
136. Kim YS, Hochstrasser RM (2005) Chemical exchange 2D IR of hydrogen-bond making and
breaking. Proc Natl Acad Sci USA 102:11185–11190. doi:10.1073/pnas.0504865102
137. Woutersen S, Mu Y, Stock G, Hamm P (2001) Hydrogen-bond lifetime measured by time-resolved
2D-IR spectroscopy: N-methylacetamide in methanol. Chem Phys 266:137–147. doi:10.1016/
S0301-0104(01)00224-5
138. Chuntonov L, Pazos IM, Ma J, Gai F (2015) Kinetics of exchange between zero-, one-, and twohydrogen-bonded states of methyl and ethyl acetate in methanol. J Phys Chem B 150313152915006.
doi:10.1021/acs.jpcb.5b00745
139. Park S, Odelius M, Gaffney KJ (2009) Ultrafast dynamics of hydrogen bond exchange in aqueous
ionic solutions. J Phys Chem B 113:7825–7835. doi:10.1021/jp9016739
140. Olschewski M, Lindner J, Vo ¨hringer P (2013) A hydrogen-bond flip-flop through a bjerrum-type
defect. Angew Chemie Int Ed 52:2602–2605. doi:10.1002/anie.201208625
Top Curr Chem (Z) (2017) 375:86
123
194
Reprinted from the journal
experiments on a linear anion and the influence of potassium cations. J Phys Chem B
120:5842–5854. doi:10.1021/acs.jpcb.6b00409
118. Rosker MJ, Dantus M, Zewail AH (1988) Femtosecond real-time probing of reactions. I. The
technique. J Chem Phys 89:6113
119. Zewail AH (1988) Laser femtochemistry. Science (80-) 242:1645–1653
120. Motzkus M, Pedersen S, Zewail AH (1996) Femtosecond real-time probing of reactions. 19.
nonlinear (DFWM) techniques for probing transition states of uni- and bimolecular reactions. J Phys
Chem 100:5620–5633
121. Herbst J, Heyne K, Diller R (2002) Femtosecond infrared spectroscopy of bacteriorhodopsin
chromophore isomerization. Science (80-) 297:822–825
122. Kukura P, McCamant DW, Yoon S et al (2005) Structural observation of the primary isomerization
in vision with femtosecond-stimulated Raman. Science (80-) 310:1006–1009
123. Vos MH, Lambry JC, Robles SJ et al (1991) Direct observation of vibrational coherence in bacterial
reaction centers using femtosecond absorption-spectroscopy. Proc Natl Acad Sci USA
88:8885–8889
124. Rose TS, Rosker MJ, Zewail AH (1988) Femtosecond real-time observation of wave packet
oscillations (resonance) in dissociation reactions. J Chem Phys 88:6672–6673
125. Dantus M, Bowman RM, Gruebele M, Zewail AH (1989) Femtosecond real-time probing of
reactions. V. The reaction of IHgI. J Chem Phys 91:7437–7450
126. Kraack JP, Buckup T, Motzkus M (2013) Coherent high-frequency vibrational dynamics in the
excited electronic state of all-trans retinal derivatives. J Phys Chem Lett 383–387. doi:10.1021/
jz302001m
127. Kraack JP, Buckup T, Hampp N, Motzkus M (2011) Ground- and excited-state vibrational
coherence dynamics in bacteriorhodopsin probed with degenerate four-wave-mixing experiments.
ChemPhysChem 12:1851–1859. doi:10.1002/cphc.201100032
128. Kraack JP, Wand A, Buckup T et al (2013) Mapping multidimensional excited state dynamics using
pump-impulsive- vibrational-spectroscopy and pump-degenerate-four-wave-mixing. Phys Chem
Chem Phys 15:14487–14501. doi:10.1039/c3cp50871d
129. Gallagher Faeder SM, Jonas DM, Faeder SMG (1999) Two-dimensional electronic correlation and
relaxation spectra: theory and model calculations. J Phys Chem A 103:10489–10505. doi:10.1021/
jp9925738
130. Aue W, Bartholdi E, Ernst R (1976) Two-dimensional spectroscopy. Application to nuclear magnetic resonance. J Chem Phys 64:2229–2246. doi:10.1063/1.432450
131. Zheng J, Kwak K, Asbury J et al (2005) Ultrafast dynamics of solute- solvent complexation
observed at thermal equilibrium in real time. Science 309:1338–1343
132. Zheng J, Fayer MD (2007) Hydrogen bond lifetimes and energetics for solute/solvent complexes
studied with 2D-IR vibrational echo spectroscopy. J Am Chem Soc 94305:4328–4335
133. Kwak K, Zheng J, Cang H, Fayer MD (2006) Ultrafast two-dimensional infrared vibrational echo
chemical exchange experiments and theory. J Phys Chem B 110:19998–20013. doi:10.1021/
jp0624808
134. Kwak K, Park S, Fayer MD (2007) Dynamics around solutes and solute-solvent complexes in mixed
solvents. Proc Natl Acad Sci USA 104:14221–14226. doi:10.1073/pnas.0701710104
135. Rosenfeld DE, Kwak K, Gengeliczki Z, Fayer MD (2010) Hydrogen bond migration between
molecular sites observed with ultrafast 2D IR chemical exchange spectroscopy. J Phys Chem B
114:2383–2389. doi:10.1021/jp911452z
136. Kim YS, Hochstrasser RM (2005) Chemical exchange 2D IR of hydrogen-bond making and
breaking. Proc Natl Acad Sci USA 102:11185–11190. doi:10.1073/pnas.0504865102
137. Woutersen S, Mu Y, Stock G, Hamm P (2001) Hydrogen-bond lifetime measured by time-resolved
2D-IR spectroscopy: N-methylacetamide in methanol. Chem Phys 266:137–147. doi:10.1016/
S0301-0104(01)00224-5
138. Chuntonov L, Pazos IM, Ma J, Gai F (2015) Kinetics of exchange between zero-, one-, and twohydrogen-bonded states of methyl and ethyl acetate in methanol. J Phys Chem B 150313152915006.
doi:10.1021/acs.jpcb.5b00745
139. Park S, Odelius M, Gaffney KJ (2009) Ultrafast dynamics of hydrogen bond exchange in aqueous
ionic solutions. J Phys Chem B 113:7825–7835. doi:10.1021/jp9016739
140. Olschewski M, Lindner J, Vo ¨hringer P (2013) A hydrogen-bond flip-flop through a bjerrum-type
defect. Angew Chemie Int Ed 52:2602–2605. doi:10.1002/anie.201208625
Top Curr Chem (Z) (2017) 375:86
123
194
Reprinted from the journal