1 3
Top Curr Chem (Z) (2018) 376:24
It can be obtained from MD simulations or in closed-form expressions derived
from different models. For example, the homogeneous (anti-diagonal) broadening
of the spectral signals arising due to coupling to a continuum of fast-decaying lowfrequency modes can be expressed by the line shape function of the semi-classical
Brownian oscillator (OBO) [124]:
where λ ij and Λ are the system–bath coupling strength and fluctuation timescale,
respectively.
References
1. Aue WP, Bartholdi E, Ernst RR (1976) 2-dimensional spectroscopy - application to nuclear magnetic-resonance. J Chem Phys 64(5):2229–2246
2. Mukamel S (1995) Principles of nonlinear optical spectroscopy. O.U.P, New York
3. Zanni MT, Hochstrasser RM (2001) Two-dimensional infrared spectroscopy: a promising new
method for the time resolution of structures. Curr Opin Struct Biol 11(5):516–522
4. Jonas DM (2003) Two-dimensional femtosecond spectroscopy. Annu Rev Phys Chem 54:425–463
5. Cowan ML, Ogilvie JP, Miller RJD (2004) Two-dimensional spectroscopy using diffractive optics
based phased-locked photon echoes. Chem Phys Lett 386(1–3):184–189
6. Brixner T, Mancal T, Stiopkin IV, Fleming GR (2004) Phase-stabilized two-dimensional electronic
spectroscopy. J Chem Phys 121(9):4221–4236
7. Brixner T, Stenger J, Vaswani HM, Cho M, Blankenship RE, Fleming GR (2005) Two-dimensional
spectroscopy of electronic couplings in photosynthesis. Nature 434(7033):625–628
8. Collini E, Wong CY, Wilk KE, Curmi PMG, Brumer P, Scholes GD (2010) Coherently wired lightharvesting in photosynthetic marine algae at ambient temperature. Nature 463(7281):644–U669
9. Mukamel S, Abramavicius D, Yang L, Zhuang W, Schweigert IV, Voronine DV (2009) Coherent multidimensional optical probes for electron correlations and exciton dynamics: from nmr to
x-rays. Acc Chem Res 42(4):553–562
10. Mukamel S, Bakker HJ (2015) Preface: special topic on multidimensional spectroscopy. J Chem
Phys 142(21):212101
11. Fuller FD, Ogilvie JP (2015) Experimental implementations of two-dimensional Fourier transform
electronic spectroscopy. Annu Rev Phys Chem 66(66):667–690
12. Selig U, Schleussner C-F, Foerster M, Langhojer F, Nuernberger P, Brixner T (2010) Coherent twodimensional ultraviolet spectroscopy in fully noncollinear geometry. Opt Lett 35(24):4178–4180
13. C-h Tseng, Matsika S, Weinacht TC (2009) Two-dimensional ultrafast Fourier transform spectroscopy in the deep ultraviolet. Opt Express 17(21):18788–18793
14. Varillas RB, Candeo A, Viola D, Garavelli M, De Silvestri S, Cerullo G, Manzoni C (2014)
Microjoule-level, tunable sub-10 fs UV pulses by broadband sum-frequency generation. Opt Lett
39(13):3849–3852
15. Borrego-Varillas R, Oriana A, Ganzer L, Trifonov A, Buchvarov I, Manzoni C, Cerullo G (2016)
Two-dimensional electronic spectroscopy in the ultraviolet by a birefringent delay line. Opt
Express 24(25):28491–28499
16. Krebs N, Pugliesi I, Hauer J, Riedle E (2013) Two-dimensional Fourier transform spectroscopy
in the ultraviolet with sub-20 fs pump pulses and 250–720 nm supercontinuum probe. N J Phys
15(8):085016
17. Baum P, Lochbrunner S, Riedle E (2004) Tunable sub-10-fs ultraviolet pulses generated by achromatic frequency doubling. Opt Lett 29(14):1686–1688
(A.7)
g
OBO
ij
(t) =
ij
2k B T
ℏℏ
− i
(e
−t + t − 1)
107
Reprinted from the journal
Top Curr Chem (Z) (2018) 376:24
It can be obtained from MD simulations or in closed-form expressions derived
from different models. For example, the homogeneous (anti-diagonal) broadening
of the spectral signals arising due to coupling to a continuum of fast-decaying lowfrequency modes can be expressed by the line shape function of the semi-classical
Brownian oscillator (OBO) [124]:
where λ ij and Λ are the system–bath coupling strength and fluctuation timescale,
respectively.
References
1. Aue WP, Bartholdi E, Ernst RR (1976) 2-dimensional spectroscopy - application to nuclear magnetic-resonance. J Chem Phys 64(5):2229–2246
2. Mukamel S (1995) Principles of nonlinear optical spectroscopy. O.U.P, New York
3. Zanni MT, Hochstrasser RM (2001) Two-dimensional infrared spectroscopy: a promising new
method for the time resolution of structures. Curr Opin Struct Biol 11(5):516–522
4. Jonas DM (2003) Two-dimensional femtosecond spectroscopy. Annu Rev Phys Chem 54:425–463
5. Cowan ML, Ogilvie JP, Miller RJD (2004) Two-dimensional spectroscopy using diffractive optics
based phased-locked photon echoes. Chem Phys Lett 386(1–3):184–189
6. Brixner T, Mancal T, Stiopkin IV, Fleming GR (2004) Phase-stabilized two-dimensional electronic
spectroscopy. J Chem Phys 121(9):4221–4236
7. Brixner T, Stenger J, Vaswani HM, Cho M, Blankenship RE, Fleming GR (2005) Two-dimensional
spectroscopy of electronic couplings in photosynthesis. Nature 434(7033):625–628
8. Collini E, Wong CY, Wilk KE, Curmi PMG, Brumer P, Scholes GD (2010) Coherently wired lightharvesting in photosynthetic marine algae at ambient temperature. Nature 463(7281):644–U669
9. Mukamel S, Abramavicius D, Yang L, Zhuang W, Schweigert IV, Voronine DV (2009) Coherent multidimensional optical probes for electron correlations and exciton dynamics: from nmr to
x-rays. Acc Chem Res 42(4):553–562
10. Mukamel S, Bakker HJ (2015) Preface: special topic on multidimensional spectroscopy. J Chem
Phys 142(21):212101
11. Fuller FD, Ogilvie JP (2015) Experimental implementations of two-dimensional Fourier transform
electronic spectroscopy. Annu Rev Phys Chem 66(66):667–690
12. Selig U, Schleussner C-F, Foerster M, Langhojer F, Nuernberger P, Brixner T (2010) Coherent twodimensional ultraviolet spectroscopy in fully noncollinear geometry. Opt Lett 35(24):4178–4180
13. C-h Tseng, Matsika S, Weinacht TC (2009) Two-dimensional ultrafast Fourier transform spectroscopy in the deep ultraviolet. Opt Express 17(21):18788–18793
14. Varillas RB, Candeo A, Viola D, Garavelli M, De Silvestri S, Cerullo G, Manzoni C (2014)
Microjoule-level, tunable sub-10 fs UV pulses by broadband sum-frequency generation. Opt Lett
39(13):3849–3852
15. Borrego-Varillas R, Oriana A, Ganzer L, Trifonov A, Buchvarov I, Manzoni C, Cerullo G (2016)
Two-dimensional electronic spectroscopy in the ultraviolet by a birefringent delay line. Opt
Express 24(25):28491–28499
16. Krebs N, Pugliesi I, Hauer J, Riedle E (2013) Two-dimensional Fourier transform spectroscopy
in the ultraviolet with sub-20 fs pump pulses and 250–720 nm supercontinuum probe. N J Phys
15(8):085016
17. Baum P, Lochbrunner S, Riedle E (2004) Tunable sub-10-fs ultraviolet pulses generated by achromatic frequency doubling. Opt Lett 29(14):1686–1688
(A.7)
g
OBO
ij
(t) =
ij
2k B T
ℏℏ
− i
(e
−t + t − 1)
107
Reprinted from the journal