91. Behm H (1984) Structure determination on a twinned crystal of cesium pentaborate
tetrahydrate, Cs[B 5 O 6 (OH) 4 ].2H 2 O. Acta Crystallogr C 40:1114–1116
92. Bubnova RS, Fundamentsky VS, Anderson JE, Filatov SK (2002) New layered polyanion in
α-CsB 5 O 8 high-temperature modification. Solid State Sci 4:87–91
93. Krogh-Moe J, Ihara M (1967) The crystal structure of caesium enneaborate, Cs 2 O.9B 2 O 3 .
Acta Crystallogr 23:427–430
94. Gupta A, Tossell JA (1983) Quantum mechanical studies of distortions and polymerization
of borate polyhedra. Am Mineral 68:989–995
95. Zhang ZG, Boisen MB Jr, Finger LW, Gibbs GV (1985) Molecular mimicry of the geometry
and charge density distribution of polyanions in borate minerals. Am Mineral 70:1238–1247
96. Oi T (2000) Calculations of reducted partition function ratios of monomeric and dimeric
boric acids and borates by the ab initio molecular orbital theory. J Nucl Sci Tech 37(2):
166–172
97. Oi T (2000) Ab initio molecular orbital calculations of reduced partition function ratios of
polyboric acids and polyborate anions. Z Naturforsch A 55:623–628
98. Zhou Y, Fang C, Fang Y, Zhu F (2011) Polyborates in aqueous borate solution: a Raman
and DFT theory investigation. Spectrochim Acta A 83:82–87
99. Beckett MA, Davies RA, Thomas CD (2014) Computational studies on gas phase polyborate
anions. Comput Theor Chem 1044:74–79
100. Frisch MJ et al (2004) Gaussian 03, revision D.02. Gaussian Inc, Wallingford, CT
101. Ishihara K, Nagasawa A, Umemoto K, Ito H, Saito K (1994) Kinetic study of boric
acid-borate interchange in aqueous solution by
11 B NMR spectroscopy. Inorg Chem
33:3811–3816
102. Stadler HP (1947) The cell dimensions and space-group of pinnoite. Mineral Mag 28:26–28
103. Paton F, MacDonald SGG (1957) The crystal structure of pinnoite. Acta Crystallogr
10:653–656
104. Krogh-Moe J (1967) A note on the structure of pinnoite. Acta Crystallogr 23:500–501
142
C. C. Pye
tetrahydrate, Cs[B 5 O 6 (OH) 4 ].2H 2 O. Acta Crystallogr C 40:1114–1116
92. Bubnova RS, Fundamentsky VS, Anderson JE, Filatov SK (2002) New layered polyanion in
α-CsB 5 O 8 high-temperature modification. Solid State Sci 4:87–91
93. Krogh-Moe J, Ihara M (1967) The crystal structure of caesium enneaborate, Cs 2 O.9B 2 O 3 .
Acta Crystallogr 23:427–430
94. Gupta A, Tossell JA (1983) Quantum mechanical studies of distortions and polymerization
of borate polyhedra. Am Mineral 68:989–995
95. Zhang ZG, Boisen MB Jr, Finger LW, Gibbs GV (1985) Molecular mimicry of the geometry
and charge density distribution of polyanions in borate minerals. Am Mineral 70:1238–1247
96. Oi T (2000) Calculations of reducted partition function ratios of monomeric and dimeric
boric acids and borates by the ab initio molecular orbital theory. J Nucl Sci Tech 37(2):
166–172
97. Oi T (2000) Ab initio molecular orbital calculations of reduced partition function ratios of
polyboric acids and polyborate anions. Z Naturforsch A 55:623–628
98. Zhou Y, Fang C, Fang Y, Zhu F (2011) Polyborates in aqueous borate solution: a Raman
and DFT theory investigation. Spectrochim Acta A 83:82–87
99. Beckett MA, Davies RA, Thomas CD (2014) Computational studies on gas phase polyborate
anions. Comput Theor Chem 1044:74–79
100. Frisch MJ et al (2004) Gaussian 03, revision D.02. Gaussian Inc, Wallingford, CT
101. Ishihara K, Nagasawa A, Umemoto K, Ito H, Saito K (1994) Kinetic study of boric
acid-borate interchange in aqueous solution by
11 B NMR spectroscopy. Inorg Chem
33:3811–3816
102. Stadler HP (1947) The cell dimensions and space-group of pinnoite. Mineral Mag 28:26–28
103. Paton F, MacDonald SGG (1957) The crystal structure of pinnoite. Acta Crystallogr
10:653–656
104. Krogh-Moe J (1967) A note on the structure of pinnoite. Acta Crystallogr 23:500–501
142
C. C. Pye