67. Natarajan M, Faggiani R, Brown ID (1979) Dilithium tetraborate, Li 2 B 4 O 7 . Cryst Struct
Commun 8:367–370
68. Radaev SF, Muradyan LA, Malakhova LF, Burak YV, Simonov VI (1989) Atomic Structure
and electron density of lithium tetraborate Li 2 B 4 O 7 . Sov Phys Crystallogr 34:842–845
69. Jiang A, Lei S, Huang Q, Chen T, Ke D (1990) Structure of lithium heptaborate, Li 3 B 7 O 12 .
Acta Crystallogr C 46:1999–2001
70. Radaev SF, Genkina EA, Lomonov VA, Maksimov BA, Pisarevskii YV, Chelokov MN,
Simonov VI (1991) Distribution of deformation electron density in lithium triborate LiB 3 O 5 .
Sov Phys Crystallogr 36:803–807
71. Radaev SF, Maximov BA, Simonov VI, Andreev BV, D’Yakov VA (1992) Deformation
density in lithium triborate, LiB 3 O 5 . Acta Crystallogr B 48:154–160
72. Le Henaff C, Hansen NK, Protas J, Marnier G (1997) Electron density distribution in LiB 3 O 5
at 293 K. Acta Crystallogr B 53:870–879
73. Sennova N, Albert B, Bubnova R, Krzhizhanovskaya M, Filatov S (2014) Anhydrous
lithium borate, Li 3 B 11 O 18 , crystal structure, phase transition and thermal expansion.
Z Kristallogr 229(7):497–504
74. Cardenas A, Solans J, Byrappa K, Shekar KVK (1993) Structure of lithium catena-Poly
[3,4-dihydroxopentaborate-1:5-mu-oxo]. Acta Crystallogr C 49:645–647
75. Zviedre I, Ievins A (1974) Crystalline structure of rubidium monoborate RbBO 2 •4/3 H 2 O.
Latvijas PSR Zinatnu Akademijas Vestis Kimijas Seria 4:395–400 (in Russian)
76. Schmid S, Schnick W (2004) Rubidium metaborate, Rb 3 B 3 O 6 . Acta Crystallogr C 60:i69–i70
77. Touboul M, Penin N, Nowogrocki G (2000) Crystal structure and thermal behavior of
Rb 2 [B 4 O 5 (OH) 4 ]•3.6H 2 O. J Solid State Chem 149:197–202
78. Krzhizhanovskaya MG, Bubnova RS, Bannova II, Filatov SK (1997) Crystal structure of
Rb 2 B 4 O 7 . Crystallogr Rep 42:226–231
79. Bubnova RS, Krivovichev SV, Shakhverdova IP, Filatov SK, Burns PC,
Krzhizhanovskaya MG, Polyakova IG (2002) Synthesis, crystal structure and thermal
behavior of Rb 3 B 7 O 12 , a new compound. Solid State Sci 4:985–992
80. Krzhizhanovskaya MG, Kabalov YK, Bubnova RS, Sokolova EV, Filatov SK (2000)
Crystal structure of the low-temperature modification of α-RbB 3 O 5 . Crystallogr Rep 45:572–
577
81. Krzhizhanovskaya MG, Bubnova RS, Fundamentskii VS, Bannova II, Polyakova IG,
Filatov SK (1998) Crystal structure and thermal expansion of high-temperature β-RbB 3 O 5
modification. Crystallogr Rep 43:21–25
82. Liu Z-H, Li L-Q, Zhang W-J (2006) Two new borates containing the first examples of large
isolated polyborate anions: chain [B 7 O 9 (OH) 5 ]
2− and ring [B 14 O 20 (OH) 6 ]
4− . Inorg Chem
45:1430–1432
83. Behm H (1984) Rubidium pentaborate tetrahydrate, Rb[B 5 O 6 (OH) 4 ].2H 2 O. Acta Crystallogr C 40:217–220
84. Penin N, Seguin L, Touboul M, Nowogrocki G (2001) Crystal structures of three MB 5 O 8
(M = Cs, Rb) borates (α-CsB 5 O 8 , γ-CsB 5 O 8 , and β-RbB 5 O 8 ). J Solid State Chem 161:205–213
85. Schlager M, Hoppe R (1994) Darstellung und Kristallstruktur von CsBO 2 . Z Anorg Allg
Chem 620:1867–1871 (in German)
86. Touboul M, Penin N, Nowogrocki G (1999) Crystal structure and thermal behavior of
Cs 2 [B 4 O 5 (OH) 4 ] 3H 2 O. J Solid State Chem 143:260–265
87. Nowogrocki G, Penin N, Touboul M (2003) Crystal structure of Cs 3 B 7 O 12 containing a new
large polyanion with 63 boron atoms. Solid State Sci 5:795–803
88. Krogh-Moe J (1960) The crystal structure of cesium triborate, Cs 2 O.3B 2 O 3 . Acta Crystallogr
13:889–892
89. Krogh-Moe J (1974) Refinement of the crystal structure of caesium triborate, Cs 2 O.3B 2 O 3 .
Acta Crystallogr B 30:1178–1180
90. Penin N, Seguin L, Touboul M, Nowogrocki G (2002) A new cesium borate Cs 3 B 13 O 21 .
Solid State Sci 4:67–76
A Crystallographic Review of Alkali Borate Salts …
141
Commun 8:367–370
68. Radaev SF, Muradyan LA, Malakhova LF, Burak YV, Simonov VI (1989) Atomic Structure
and electron density of lithium tetraborate Li 2 B 4 O 7 . Sov Phys Crystallogr 34:842–845
69. Jiang A, Lei S, Huang Q, Chen T, Ke D (1990) Structure of lithium heptaborate, Li 3 B 7 O 12 .
Acta Crystallogr C 46:1999–2001
70. Radaev SF, Genkina EA, Lomonov VA, Maksimov BA, Pisarevskii YV, Chelokov MN,
Simonov VI (1991) Distribution of deformation electron density in lithium triborate LiB 3 O 5 .
Sov Phys Crystallogr 36:803–807
71. Radaev SF, Maximov BA, Simonov VI, Andreev BV, D’Yakov VA (1992) Deformation
density in lithium triborate, LiB 3 O 5 . Acta Crystallogr B 48:154–160
72. Le Henaff C, Hansen NK, Protas J, Marnier G (1997) Electron density distribution in LiB 3 O 5
at 293 K. Acta Crystallogr B 53:870–879
73. Sennova N, Albert B, Bubnova R, Krzhizhanovskaya M, Filatov S (2014) Anhydrous
lithium borate, Li 3 B 11 O 18 , crystal structure, phase transition and thermal expansion.
Z Kristallogr 229(7):497–504
74. Cardenas A, Solans J, Byrappa K, Shekar KVK (1993) Structure of lithium catena-Poly
[3,4-dihydroxopentaborate-1:5-mu-oxo]. Acta Crystallogr C 49:645–647
75. Zviedre I, Ievins A (1974) Crystalline structure of rubidium monoborate RbBO 2 •4/3 H 2 O.
Latvijas PSR Zinatnu Akademijas Vestis Kimijas Seria 4:395–400 (in Russian)
76. Schmid S, Schnick W (2004) Rubidium metaborate, Rb 3 B 3 O 6 . Acta Crystallogr C 60:i69–i70
77. Touboul M, Penin N, Nowogrocki G (2000) Crystal structure and thermal behavior of
Rb 2 [B 4 O 5 (OH) 4 ]•3.6H 2 O. J Solid State Chem 149:197–202
78. Krzhizhanovskaya MG, Bubnova RS, Bannova II, Filatov SK (1997) Crystal structure of
Rb 2 B 4 O 7 . Crystallogr Rep 42:226–231
79. Bubnova RS, Krivovichev SV, Shakhverdova IP, Filatov SK, Burns PC,
Krzhizhanovskaya MG, Polyakova IG (2002) Synthesis, crystal structure and thermal
behavior of Rb 3 B 7 O 12 , a new compound. Solid State Sci 4:985–992
80. Krzhizhanovskaya MG, Kabalov YK, Bubnova RS, Sokolova EV, Filatov SK (2000)
Crystal structure of the low-temperature modification of α-RbB 3 O 5 . Crystallogr Rep 45:572–
577
81. Krzhizhanovskaya MG, Bubnova RS, Fundamentskii VS, Bannova II, Polyakova IG,
Filatov SK (1998) Crystal structure and thermal expansion of high-temperature β-RbB 3 O 5
modification. Crystallogr Rep 43:21–25
82. Liu Z-H, Li L-Q, Zhang W-J (2006) Two new borates containing the first examples of large
isolated polyborate anions: chain [B 7 O 9 (OH) 5 ]
2− and ring [B 14 O 20 (OH) 6 ]
4− . Inorg Chem
45:1430–1432
83. Behm H (1984) Rubidium pentaborate tetrahydrate, Rb[B 5 O 6 (OH) 4 ].2H 2 O. Acta Crystallogr C 40:217–220
84. Penin N, Seguin L, Touboul M, Nowogrocki G (2001) Crystal structures of three MB 5 O 8
(M = Cs, Rb) borates (α-CsB 5 O 8 , γ-CsB 5 O 8 , and β-RbB 5 O 8 ). J Solid State Chem 161:205–213
85. Schlager M, Hoppe R (1994) Darstellung und Kristallstruktur von CsBO 2 . Z Anorg Allg
Chem 620:1867–1871 (in German)
86. Touboul M, Penin N, Nowogrocki G (1999) Crystal structure and thermal behavior of
Cs 2 [B 4 O 5 (OH) 4 ] 3H 2 O. J Solid State Chem 143:260–265
87. Nowogrocki G, Penin N, Touboul M (2003) Crystal structure of Cs 3 B 7 O 12 containing a new
large polyanion with 63 boron atoms. Solid State Sci 5:795–803
88. Krogh-Moe J (1960) The crystal structure of cesium triborate, Cs 2 O.3B 2 O 3 . Acta Crystallogr
13:889–892
89. Krogh-Moe J (1974) Refinement of the crystal structure of caesium triborate, Cs 2 O.3B 2 O 3 .
Acta Crystallogr B 30:1178–1180
90. Penin N, Seguin L, Touboul M, Nowogrocki G (2002) A new cesium borate Cs 3 B 13 O 21 .
Solid State Sci 4:67–76
A Crystallographic Review of Alkali Borate Salts …
141