151. Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH (1992) Synthetic nickel-containing
heterometal cubane-type clusters with NiFe 3 Q 4 cores (Q¼sulfur, selenium). J Am Chem
Soc 114(13):5415–5423. doi:10.1021/ja00039a063
152. Zhou J, Raebiger JW, Crawford CA, Holm RH (1997) Metal ion incorporation reactions of
the cluster [Fe 3 S 4 (LS 3 )]
3À
, containing the cuboidal [Fe 3 S 4 ]
0 core. J Am Chem Soc 119
(27):6242–6250. doi:10.1021/ja9704186
153. Panda R, Zhang Y, McLauchlan CC, Venkateswara Rao P, Tiago de Oliveira FA, Mu ¨nck E,
Holm RH (2004) Initial structure modification of tetrahedral to planar nickel(II) in a
nickel À iron À sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase.
J Am Chem Soc 126(20):6448–6459. doi:10.1021/ja030627s
154. Panda R, Berlinguette CP, Zhang Y, Holm RH (2005) Synthesis of [MFe 3 S 4 ] clusters
containing a planar MII site (M¼Ni, Pd, Pt), a structural element in the C-cluster of carbon
monoxide dehydrogenase. J Am Chem Soc 127(31):11092–11101. doi:10.1021/ja052381s
155. Sun J, Tessier C, Holm RH (2007) Sulfur ligand substitution at the nickel(II) sites of cubanetype and cubanoid [NiFe 3 S 4 ] clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorg Chem 46(7):2691–2699. doi:10.1021/ic062362z
156. Slater S, Wagenknecht JH (1984) Electrochemical reduction of carbon dioxide catalyzed by
Rh(diphos) 2 Cl. J Am Chem Soc 106(18):5367–5368. doi:10.1021/ja00330a064
157. Darensbourg DJ, Darensbourg MY, Goh LY, Ludvig M, Wiegreffe P (1987) Reaction of
(Cy 3 P) 2 Ni(H)(CH 3 ) with carbon dioxide. Formation of an hydridonickel formate complex,
HNi(O 2 CH)(Cy 3 P) 2 . J Am Chem Soc 109(24):7539–7540. doi:10.1021/ja00258a053
158. DuBois DL, Miedaner A (1987) Mediated electrochemical reduction of CO 2 . Preparation and
comparison of an isoelectronic series of complexes. J Am Chem Soc 109(1):113–117.
doi:10.1021/ja00235a019
159. DuBois DL, Miedaner A, Haltiwanger RC (1991) Electrochemical reduction of carbon
dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4) 2 complexes: synthetic and mechanistic studies. J Am Chem Soc 113(23):8753–8764. doi:10.1021/ja00023a023
160. Steffey BD, Curtis CJ, DuBois DL (1995) Electrochemical reduction of CO 2 catalyzed by a
dinuclear palladium complex containing a bridging hexaphosphine ligand: evidence for
cooperativity. Organometallics 14(10):4937–4943. doi:10.1021/om00010a066
161. Hawecker J, Lehn J-M, Ziessel R (1983) Efficient photochemical reduction of CO 2 to CO by
visible light irradiation of systems containing Re(bipy)(CO) 3 X or Ru(bipy) 3
2+ -Co
2+ combinations as homogeneous catalysts. Chem Commun 9:536–538. doi:10.1039/c39830000536
162. Hawecker J, Lehn J-M, Ziessel R (1984) Electrocatalytic reduction of carbon dioxide
mediated by Re(bipy)(CO) 3 Cl (bipy¼2,2
0 -bipyridine). Chem Commun 6:328–330.
doi:10.1039/c39840000328
163. Hawecker J, Lehn J-M, Ziessel R (1986) Photochemical and electrochemical reduction of
carbon dioxide to carbon monoxide mediated by (2,2
0 -bipyridine)tricarbonylchlororhenium
(I) and related complexes as homogeneous catalysts. Helv Chim Acta 69(8):1990–2012.
doi:10.1002/hlca.19860690824
164. O’Toole TR, Margerum LD, Westmoreland TD, Vining WJ, Murray RW, Meyer TJ (1985)
Electrocatalytic reduction of CO 2 at a chemically modified electrode. Chem Commun
20:1416–1417. doi:10.1039/c39850001416
165. Cabrera CR, Abru~ na HD (1986) Electrocatalysis of CO 2 reduction at surface modified
metallic and semiconducting electrodes. J Electroanal Chem Interfacial Electrochem 209
(1):101–107. doi:10.1016/0022-0728(86)80189-9
166. Cosnier S, Deronzier A, Moutet J-C (1986) Electrochemical coating of a platinum electrode
by a poly(pyrrole) film containing the Fac-Re(2,2
0 -bipyridine)(CO) 3 Cl system application to
electrocatalytic reduction of CO 2 . J Electroanal Chem Interfacial Electrochem 207
(1–2):315–321. doi:10.1016/0022-0728(86)87080-2
167. Cosnier S, Deronzier A, Moutet J-C (1988) Electrocatalytic reduction of CO 2 on electrodes
modified by Fac-Re(2,2
0 -bipyridine)(CO) 3 Cl complexes bonded to polypyrrole films. J Mol
Catal 45(3):381–391. doi:10.1016/0304-5102(88)80070-1
Biomimetic Complexes for Production of Dihydrogen and Reduction of CO 2
271
heterometal cubane-type clusters with NiFe 3 Q 4 cores (Q¼sulfur, selenium). J Am Chem
Soc 114(13):5415–5423. doi:10.1021/ja00039a063
152. Zhou J, Raebiger JW, Crawford CA, Holm RH (1997) Metal ion incorporation reactions of
the cluster [Fe 3 S 4 (LS 3 )]
3À
, containing the cuboidal [Fe 3 S 4 ]
0 core. J Am Chem Soc 119
(27):6242–6250. doi:10.1021/ja9704186
153. Panda R, Zhang Y, McLauchlan CC, Venkateswara Rao P, Tiago de Oliveira FA, Mu ¨nck E,
Holm RH (2004) Initial structure modification of tetrahedral to planar nickel(II) in a
nickel À iron À sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase.
J Am Chem Soc 126(20):6448–6459. doi:10.1021/ja030627s
154. Panda R, Berlinguette CP, Zhang Y, Holm RH (2005) Synthesis of [MFe 3 S 4 ] clusters
containing a planar MII site (M¼Ni, Pd, Pt), a structural element in the C-cluster of carbon
monoxide dehydrogenase. J Am Chem Soc 127(31):11092–11101. doi:10.1021/ja052381s
155. Sun J, Tessier C, Holm RH (2007) Sulfur ligand substitution at the nickel(II) sites of cubanetype and cubanoid [NiFe 3 S 4 ] clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorg Chem 46(7):2691–2699. doi:10.1021/ic062362z
156. Slater S, Wagenknecht JH (1984) Electrochemical reduction of carbon dioxide catalyzed by
Rh(diphos) 2 Cl. J Am Chem Soc 106(18):5367–5368. doi:10.1021/ja00330a064
157. Darensbourg DJ, Darensbourg MY, Goh LY, Ludvig M, Wiegreffe P (1987) Reaction of
(Cy 3 P) 2 Ni(H)(CH 3 ) with carbon dioxide. Formation of an hydridonickel formate complex,
HNi(O 2 CH)(Cy 3 P) 2 . J Am Chem Soc 109(24):7539–7540. doi:10.1021/ja00258a053
158. DuBois DL, Miedaner A (1987) Mediated electrochemical reduction of CO 2 . Preparation and
comparison of an isoelectronic series of complexes. J Am Chem Soc 109(1):113–117.
doi:10.1021/ja00235a019
159. DuBois DL, Miedaner A, Haltiwanger RC (1991) Electrochemical reduction of carbon
dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4) 2 complexes: synthetic and mechanistic studies. J Am Chem Soc 113(23):8753–8764. doi:10.1021/ja00023a023
160. Steffey BD, Curtis CJ, DuBois DL (1995) Electrochemical reduction of CO 2 catalyzed by a
dinuclear palladium complex containing a bridging hexaphosphine ligand: evidence for
cooperativity. Organometallics 14(10):4937–4943. doi:10.1021/om00010a066
161. Hawecker J, Lehn J-M, Ziessel R (1983) Efficient photochemical reduction of CO 2 to CO by
visible light irradiation of systems containing Re(bipy)(CO) 3 X or Ru(bipy) 3
2+ -Co
2+ combinations as homogeneous catalysts. Chem Commun 9:536–538. doi:10.1039/c39830000536
162. Hawecker J, Lehn J-M, Ziessel R (1984) Electrocatalytic reduction of carbon dioxide
mediated by Re(bipy)(CO) 3 Cl (bipy¼2,2
0 -bipyridine). Chem Commun 6:328–330.
doi:10.1039/c39840000328
163. Hawecker J, Lehn J-M, Ziessel R (1986) Photochemical and electrochemical reduction of
carbon dioxide to carbon monoxide mediated by (2,2
0 -bipyridine)tricarbonylchlororhenium
(I) and related complexes as homogeneous catalysts. Helv Chim Acta 69(8):1990–2012.
doi:10.1002/hlca.19860690824
164. O’Toole TR, Margerum LD, Westmoreland TD, Vining WJ, Murray RW, Meyer TJ (1985)
Electrocatalytic reduction of CO 2 at a chemically modified electrode. Chem Commun
20:1416–1417. doi:10.1039/c39850001416
165. Cabrera CR, Abru~ na HD (1986) Electrocatalysis of CO 2 reduction at surface modified
metallic and semiconducting electrodes. J Electroanal Chem Interfacial Electrochem 209
(1):101–107. doi:10.1016/0022-0728(86)80189-9
166. Cosnier S, Deronzier A, Moutet J-C (1986) Electrochemical coating of a platinum electrode
by a poly(pyrrole) film containing the Fac-Re(2,2
0 -bipyridine)(CO) 3 Cl system application to
electrocatalytic reduction of CO 2 . J Electroanal Chem Interfacial Electrochem 207
(1–2):315–321. doi:10.1016/0022-0728(86)87080-2
167. Cosnier S, Deronzier A, Moutet J-C (1988) Electrocatalytic reduction of CO 2 on electrodes
modified by Fac-Re(2,2
0 -bipyridine)(CO) 3 Cl complexes bonded to polypyrrole films. J Mol
Catal 45(3):381–391. doi:10.1016/0304-5102(88)80070-1
Biomimetic Complexes for Production of Dihydrogen and Reduction of CO 2
271