way for a more rational and efficient design of such species may consist in testing
first a series of mononuclear early and late complexes in dual catalysis and then
synthesizing the heterobimetallic complex with the hope that by bringing both
metals closer, a better reactivity would be observed for kinetic reasons. Finally,
cooperative effects or synergetic effects are not limited to catalysis, and the use of
early–late bimetallic complexes for other purposes such as therapy constitutes also
wonderful opportunity to widen the scope of this research.
References
1. Beller M, Bolm C (eds) (2004) Transition metals for organic synthesis, 2nd edn. Wiley-VCH,
Weinheim, p 1344
2. Steinhagen H, Helmchen G (1996) Angew Chem Int Ed 35:2339–2342
3. Drauz K, Waldmann K (eds) (2002) Enzyme catalysis in organic synthesis, vols 1–3, 2nd edn.
Wiley-VCH, Weinheim, p 1556
4. Wheatley N, Kalck P (1999) Chem Rev 99:3379–3419
5. Cooper BG, Napoline JW, Thomas CM (2012) Catalysis Reviews: Science and Engineering
54:1–40
6. Peters R (2015) Cooperative catalysis: designing efficient catalysts for synthesis. WileyVCH, Weinheim
7. Rowlands GJ (2001) Tetrahedron 57:1865–1882
8. Lee JM, Na Y, Han H, Chang S (2004) Chem Soc Rev 33:302–312
9. Shinde VS, Gajula B, Patil NT (2012) Org Biomol Chem 10:211–224
10. Allen AE, MacMillan DWC (2012) Chem Sci 3:633–658
11. Fogg D, Santos E (2004) Coord Chem Rev 248:2365–2379
12. Lohr TL, Marks TJ (2015) Nat Chem 7:477–482
13. Corey EJ, Bakshi RK, Shibata S, Chen C-P, Singh VK (1987) J Am Chem Soc
109:7925–7926
14. Corey EJ, Halal CJ (1998) Angew Chem Int Ed 37:1986–2012
15. Welch GC, Juan RRS, Masuda JD, Stephan DW (2006) Science 314:1124–1126
16. Stephan DW, Erker G (2010) Angew Chem Int Ed 49:46–76
17. Okino T, Hoashi Y, Takemoto Y (2003) J Am Chem Soc 125:12672–12673
18. Hamza A, Schubert G, So os T, Pa ´pai I, Am J (2006) Chem Soc 128:13151–13160
19. Siau W-Y, Wang J (2011) Catal Sci Technol 1:1298–1310
20. Ibrahem I, Cordova A (2006) Angew Chem Int Ed 45:1952–1956
21. Shao Z, Zhang H (2009) Chem Soc Rev 38:2745–2755
22. Du Z, Shao Z (2013) Chem Soc Rev 42:1337–1378
23. Ito Y, Sawamura M, Hayashi T (1986) J Am Chem Soc 108:6405–6406
24. Sasai H, Suzuki T, Arai S, Arai T, Shibasaki M (1992) J Am Chem Soc 114:4418–4420
25. Hashiguchi S, Fujii A, Takehara J, Ikariya T, Noyori R (1995) J Am Chem Soc
117:7562–7563
26. Yamakawa M, Ito H, Noyori R (2000) J Am Chem Soc 122:1466–1478
27. Shibasaki M, Sasai H, Arai T (1997) Angew Chem Int Ed Engl 36:1236–1256
28. Shibasaki M, Yoshikawa N (2002) Chem Rev 102:2187–2209
29. Shibasaki M, Kanai M, Matsunaga S, Kumagai N (2009) Acc Chem Res 42:1117–1127
30. Arai T, Sasai H, Aoe K-I, Okamura K, Date T, Shibasaki M (1996) Angew Chem Int Ed Engl
35:104–106
31. Hamashima Y, Kanai M, Shibasaki M (2000) J Am Chem Soc 122:7412–7413
32. Shibasaki M, Kanai M, Funabashi K (2002) Chem Comm 1989–1999
182
E. Bodio et al.
first a series of mononuclear early and late complexes in dual catalysis and then
synthesizing the heterobimetallic complex with the hope that by bringing both
metals closer, a better reactivity would be observed for kinetic reasons. Finally,
cooperative effects or synergetic effects are not limited to catalysis, and the use of
early–late bimetallic complexes for other purposes such as therapy constitutes also
wonderful opportunity to widen the scope of this research.
References
1. Beller M, Bolm C (eds) (2004) Transition metals for organic synthesis, 2nd edn. Wiley-VCH,
Weinheim, p 1344
2. Steinhagen H, Helmchen G (1996) Angew Chem Int Ed 35:2339–2342
3. Drauz K, Waldmann K (eds) (2002) Enzyme catalysis in organic synthesis, vols 1–3, 2nd edn.
Wiley-VCH, Weinheim, p 1556
4. Wheatley N, Kalck P (1999) Chem Rev 99:3379–3419
5. Cooper BG, Napoline JW, Thomas CM (2012) Catalysis Reviews: Science and Engineering
54:1–40
6. Peters R (2015) Cooperative catalysis: designing efficient catalysts for synthesis. WileyVCH, Weinheim
7. Rowlands GJ (2001) Tetrahedron 57:1865–1882
8. Lee JM, Na Y, Han H, Chang S (2004) Chem Soc Rev 33:302–312
9. Shinde VS, Gajula B, Patil NT (2012) Org Biomol Chem 10:211–224
10. Allen AE, MacMillan DWC (2012) Chem Sci 3:633–658
11. Fogg D, Santos E (2004) Coord Chem Rev 248:2365–2379
12. Lohr TL, Marks TJ (2015) Nat Chem 7:477–482
13. Corey EJ, Bakshi RK, Shibata S, Chen C-P, Singh VK (1987) J Am Chem Soc
109:7925–7926
14. Corey EJ, Halal CJ (1998) Angew Chem Int Ed 37:1986–2012
15. Welch GC, Juan RRS, Masuda JD, Stephan DW (2006) Science 314:1124–1126
16. Stephan DW, Erker G (2010) Angew Chem Int Ed 49:46–76
17. Okino T, Hoashi Y, Takemoto Y (2003) J Am Chem Soc 125:12672–12673
18. Hamza A, Schubert G, So os T, Pa ´pai I, Am J (2006) Chem Soc 128:13151–13160
19. Siau W-Y, Wang J (2011) Catal Sci Technol 1:1298–1310
20. Ibrahem I, Cordova A (2006) Angew Chem Int Ed 45:1952–1956
21. Shao Z, Zhang H (2009) Chem Soc Rev 38:2745–2755
22. Du Z, Shao Z (2013) Chem Soc Rev 42:1337–1378
23. Ito Y, Sawamura M, Hayashi T (1986) J Am Chem Soc 108:6405–6406
24. Sasai H, Suzuki T, Arai S, Arai T, Shibasaki M (1992) J Am Chem Soc 114:4418–4420
25. Hashiguchi S, Fujii A, Takehara J, Ikariya T, Noyori R (1995) J Am Chem Soc
117:7562–7563
26. Yamakawa M, Ito H, Noyori R (2000) J Am Chem Soc 122:1466–1478
27. Shibasaki M, Sasai H, Arai T (1997) Angew Chem Int Ed Engl 36:1236–1256
28. Shibasaki M, Yoshikawa N (2002) Chem Rev 102:2187–2209
29. Shibasaki M, Kanai M, Matsunaga S, Kumagai N (2009) Acc Chem Res 42:1117–1127
30. Arai T, Sasai H, Aoe K-I, Okamura K, Date T, Shibasaki M (1996) Angew Chem Int Ed Engl
35:104–106
31. Hamashima Y, Kanai M, Shibasaki M (2000) J Am Chem Soc 122:7412–7413
32. Shibasaki M, Kanai M, Funabashi K (2002) Chem Comm 1989–1999
182
E. Bodio et al.