87. Harrington MJ, Gupta HS, Fratzl P, Waite JH (2009) Collagen insulated from tensile damage
by domains that unfold reversibly: in situ X-ray investigation of mechanical yield and
damage repair in the mussel byssus. J Struct Biol 167:47–54
88. Harrington MJ, Waite JH (2009) How nature modulates a fiber’s mechanical properties:
mechanically distinct fibers drawn from natural mesogenic block copolymer variants. Adv
Mater 21:440–444
89. Ceylan H, Urel M, Erkal TS, Tekinay AB, Dana A, Guler MO (2013) Mussel inspired dynamic
cross-linking of self-healing peptide nanofiber network. Adv Funct Mater 23:2081–2090
90. Krogsgaard M, Behrens MA, Pedersen JS, Birkedal H (2013) Self-healing mussel-inspired
multi-pH-responsive hydrogels. Biomacromolecules 14:297–301
91. Waite JH, Qin XX, Coyne KJ (1998) The peculiar collagens of mussel byssus. Matrix Biol
17:93–106
92. Carrington E, Gosline JM (2004) Mechanical design of mussel byssus: load cycle and strain
rate dependence. Am Malacol Bull 18:135–142
93. Waite JH, Lichtenegger HC, Stucky GD, Hansma P (2004) Exploring molecular and
mechanical gradients in structural bioscaffolds. Biochemistry 43:7653–7662
94. Waite JH, Broomell CC (2012) Changing environments and structure–property relationships
in marine biomaterials. J Exp Biol 215:873–883
95. Krauss S, Metzger TH, Fratzl P, Harrington MJ (2013) Self-repair of a biological fiber guided
by an ordered elastic framework. Biomacromolecules 14:1520–1528
96. Fullenkamp DE, He L, Barrett DG, Burghardt WR, Messersmith PB (2013) Mussel-inspired
histidine-based transient network metal coordination hydrogels. Macromolecules
46:1167–1174
97. Varghese S, Lele A, Mashelkar R (2006) Metal-ion-mediated healing of gels. J Polym Sci A
Polym Chem 44:666–670
98. Yuan JC, Fang XL, Zhang LX, Hong GN, Lin YJ, Zheng QF, Xu YZ, Ruan YH, Weng WG,
Xia HP, Chen GH (2012) Multi-responsive self-healing metallo-supramolecular gels based
on “click” ligand. J Mater Chem 22:11515–11522
99. Terech P, Yan M, Mare ´chal M, Royal G, Galvez J, Velu SKP (2013) Characterization of
strain recovery and “self-healing” in a self-assembled metallo-gel. Phys Chem Chem Phys
15:7338–7344
100. Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, Hager MD, Schubert US
(2013) Self-healing polymer coatings based on crosslinked metallosupramolecular copolymers. Adv Mater 25:1634–1638
101. Bode S, Bose RK, Matthes S, Ehrhardt M, Seifert A, Schacher FH, Paulus RM, Stumpf S,
Sandmann B, Vitz J, Winter A, Hoeppener S, Garcia SJ, Spange S, van der Zwaag S, Hager
MD, Schubert US (2013) Self-healing metallopolymers based on cadmium bis(terpyridine)
complex containing polymer networks. Polym Chem 4:4966–4973
102. Lohmeijer BGG, Schubert US (2003) Water-soluble building blocks for terpyridinecontaining supramolecular polymers: synthesis, complexation, and pH stability studies of
poly(ethylene oxide) moieties. Macromol Chem Phys 204:1072–1078
103. Gohy JF, Lohmeijer BGG, Schubert US (2002) Metallo-supramolecular block copolymer
micelles. Macromolecules 35:4560–4563
104. Gohy JF, Lohmeijer BGG, Schubert US (2002) Reversible metallo-supramolecular block
copolymer micelles containing a soft core. Macromol Rapid Commun 23:555–560
105. Gohy JF, Lohmeijer BGG, Varshney SK, Decamps B, Leroy E, Boileau S, Schubert US
(2002) Stimuli-responsive aqueous micelles from an ABC metallo-supramolecular triblock
copolymer. Macromolecules 35:9748–9755
106. Wild A, Winter A, Schlu ¨tter F, Schubert US (2011) Advances in the field of π-conjugated
2,2
0 :6
0 ,2
00 -Terpyridines. Chem Soc Rev 40:1459–1511
107. Ulbricht C, Beyer B, Friebe C, Winter A, Schubert US (2009) Recent developments in the
application of phosphorescent iridium(III) complex systems. Adv Mater 21:4418–4441
256
B. Sandmann et al.
by domains that unfold reversibly: in situ X-ray investigation of mechanical yield and
damage repair in the mussel byssus. J Struct Biol 167:47–54
88. Harrington MJ, Waite JH (2009) How nature modulates a fiber’s mechanical properties:
mechanically distinct fibers drawn from natural mesogenic block copolymer variants. Adv
Mater 21:440–444
89. Ceylan H, Urel M, Erkal TS, Tekinay AB, Dana A, Guler MO (2013) Mussel inspired dynamic
cross-linking of self-healing peptide nanofiber network. Adv Funct Mater 23:2081–2090
90. Krogsgaard M, Behrens MA, Pedersen JS, Birkedal H (2013) Self-healing mussel-inspired
multi-pH-responsive hydrogels. Biomacromolecules 14:297–301
91. Waite JH, Qin XX, Coyne KJ (1998) The peculiar collagens of mussel byssus. Matrix Biol
17:93–106
92. Carrington E, Gosline JM (2004) Mechanical design of mussel byssus: load cycle and strain
rate dependence. Am Malacol Bull 18:135–142
93. Waite JH, Lichtenegger HC, Stucky GD, Hansma P (2004) Exploring molecular and
mechanical gradients in structural bioscaffolds. Biochemistry 43:7653–7662
94. Waite JH, Broomell CC (2012) Changing environments and structure–property relationships
in marine biomaterials. J Exp Biol 215:873–883
95. Krauss S, Metzger TH, Fratzl P, Harrington MJ (2013) Self-repair of a biological fiber guided
by an ordered elastic framework. Biomacromolecules 14:1520–1528
96. Fullenkamp DE, He L, Barrett DG, Burghardt WR, Messersmith PB (2013) Mussel-inspired
histidine-based transient network metal coordination hydrogels. Macromolecules
46:1167–1174
97. Varghese S, Lele A, Mashelkar R (2006) Metal-ion-mediated healing of gels. J Polym Sci A
Polym Chem 44:666–670
98. Yuan JC, Fang XL, Zhang LX, Hong GN, Lin YJ, Zheng QF, Xu YZ, Ruan YH, Weng WG,
Xia HP, Chen GH (2012) Multi-responsive self-healing metallo-supramolecular gels based
on “click” ligand. J Mater Chem 22:11515–11522
99. Terech P, Yan M, Mare ´chal M, Royal G, Galvez J, Velu SKP (2013) Characterization of
strain recovery and “self-healing” in a self-assembled metallo-gel. Phys Chem Chem Phys
15:7338–7344
100. Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, Hager MD, Schubert US
(2013) Self-healing polymer coatings based on crosslinked metallosupramolecular copolymers. Adv Mater 25:1634–1638
101. Bode S, Bose RK, Matthes S, Ehrhardt M, Seifert A, Schacher FH, Paulus RM, Stumpf S,
Sandmann B, Vitz J, Winter A, Hoeppener S, Garcia SJ, Spange S, van der Zwaag S, Hager
MD, Schubert US (2013) Self-healing metallopolymers based on cadmium bis(terpyridine)
complex containing polymer networks. Polym Chem 4:4966–4973
102. Lohmeijer BGG, Schubert US (2003) Water-soluble building blocks for terpyridinecontaining supramolecular polymers: synthesis, complexation, and pH stability studies of
poly(ethylene oxide) moieties. Macromol Chem Phys 204:1072–1078
103. Gohy JF, Lohmeijer BGG, Schubert US (2002) Metallo-supramolecular block copolymer
micelles. Macromolecules 35:4560–4563
104. Gohy JF, Lohmeijer BGG, Schubert US (2002) Reversible metallo-supramolecular block
copolymer micelles containing a soft core. Macromol Rapid Commun 23:555–560
105. Gohy JF, Lohmeijer BGG, Varshney SK, Decamps B, Leroy E, Boileau S, Schubert US
(2002) Stimuli-responsive aqueous micelles from an ABC metallo-supramolecular triblock
copolymer. Macromolecules 35:9748–9755
106. Wild A, Winter A, Schlu ¨tter F, Schubert US (2011) Advances in the field of π-conjugated
2,2
0 :6
0 ,2
00 -Terpyridines. Chem Soc Rev 40:1459–1511
107. Ulbricht C, Beyer B, Friebe C, Winter A, Schubert US (2009) Recent developments in the
application of phosphorescent iridium(III) complex systems. Adv Mater 21:4418–4441
256
B. Sandmann et al.