64. Pingkarawat K, Wang CH, Varley RJ, Mouritz AP (2012) Self-healing of delamination
fatigue cracks in carbon fibre-epoxy laminate using mendable thermoplastics. J Mater Sci
47:4449–4456
65. Hughes AE, Cole IS, Muster TH, Varley RJ (2010) Designing green, self-healing coatings for
metal protection. Npg Asia Mater 2:143–151
66. Varley RJ, van der Zwaag S (2008) Development of a quasi-static test method to investigate
the origin of self-healing in ionomers under ballistic conditions. Polym Test 27:11–19
67. Tadano K, Hirasawa E, Yamamoto H, Yano S (1989) Order-disorder transition of ionic
clusters in ionomers. Macromolecules 22:226–233
68. Neppel A, Butler IS, Eisenberg A (1979) Vibrational spectra of polymers. 2. Variabletemperature raman spectroscopy as a probe for ion clustering in ionomers. Macromolecules
12:948–952
69. Stuart MAC, Huck WTS, Genzer J, Muller M, Ober C, Stamm M, Sukhorukov GB, Szleifer I,
Tsukruk VV, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S (2010) Emerging
applications of stimuli-responsive polymer materials. Nat Mater 9:101–113
70. Peng F, Li GZ, Liu XX, Wu SZ, Tong Z (2008) Redox-responsive gel–sol/sol–gel transition
in poly(acrylic acid) aqueous solution containing Fe(III) ions switched by light. J Am Chem
Soc 130:16166–16167
71. Zhou GC, Harruna II, Ingram CW (2005) Ruthenium-centered thermosensitive polymers.
Polymer 46:10672–10677
72. Wool RP (2008) Self-healing materials: a review. Soft Matter 4:400–418
73. Beck JB, Rowan SJ (2003) Multistimuli, multiresponsive metallo-supramolecular polymers.
J Am Chem Soc 125:13922–13923
74. Weng WG, Li Z, Jamieson AM, Rowan SJ (2009) Effect of monomer structure on the
gelation of a class of metallo-supramolecular polymers. Soft Matter 5:4647–4657
75. Rowan SJ, Beck JB (2005) Metal–ligand induced supramolecular polymerization: a route to
responsive materials. Faraday Discuss 128:43–53
76. Murphy EB, Wudl F (2010) The world of smart healable materials. Prog Polym Sci
35:223–251
77. Wang F, Zhang JQ, Ding X, Dong SY, Liu M, Zheng B, Li SJ, Wu L, Yu YH, Gibson HW,
Huang FH (2010) Metal coordination mediated reversible conversion between linear and
cross-linked supramolecular polymers. Angew Chem Int Ed 49:1090–1094
78. Hager MD, Greil P, Leyens C, van der Zwaag S, Schubert US (2010) Self-healing materials.
Adv Mater 22:5424–5430
79. Herbst F, Do ¨hler D, Michael P, Binder WH (2013) Self-healing polymers via supramolecular
forces. Macromol Rapid Commun 34:203–220
80. Billiet S, Hillewaere XKD, Teixeira RFA, Du Prez FE (2013) Chemistry of crosslinking
processes for self-healing polymers. Macromol Rapid Commun 34:290–309
81. Brassinne J, Fustin C-A, Gohy JF (2013) Polymer gels constructed through metal–ligand
coordination. J Inorg Organomet Polym 23:23–40
82. Vaccaro E, Waite JH (2001) Yield and post-yield behavior of mussel byssal thread: a selfhealing biomolecular material. Biomacromolecules 2:906–911
83. Harrington MJ, Masic A, Holten-Andersen N, Waite JH, Fratzl P (2010) Iron-clad fibers: a
metal-based biological strategy for hard flexible coatings. Science 328:216–220
84. Holten-Andersen N, Harrington MJ, Birkedal H, Lee BP, Messersmith PB, Lee KYC, Waite
JH (2011) pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer
networks with near-covalent elastic moduli. Proc Natl Acad Sci USA 108:2651–2655
85. Barrett DG, Fullenkamp DE, He L, Holten-Andersen N, Lee KYC, Messersmith PB (2013)
pH-Based regulation of hydrogel mechanical properties through mussel-inspired chemistry
and processing. Adv Funct Mater 23:1111–1119
86. Harrington MJ, Waite JH (2008) pH-Dependent locking of giant mesogens in fibers
drawnfrom mussel byssal collagens. Biomacromolecules 9:1480–1486
Metallopolymers as an Emerging Class of Self-Healing Materials
255
fatigue cracks in carbon fibre-epoxy laminate using mendable thermoplastics. J Mater Sci
47:4449–4456
65. Hughes AE, Cole IS, Muster TH, Varley RJ (2010) Designing green, self-healing coatings for
metal protection. Npg Asia Mater 2:143–151
66. Varley RJ, van der Zwaag S (2008) Development of a quasi-static test method to investigate
the origin of self-healing in ionomers under ballistic conditions. Polym Test 27:11–19
67. Tadano K, Hirasawa E, Yamamoto H, Yano S (1989) Order-disorder transition of ionic
clusters in ionomers. Macromolecules 22:226–233
68. Neppel A, Butler IS, Eisenberg A (1979) Vibrational spectra of polymers. 2. Variabletemperature raman spectroscopy as a probe for ion clustering in ionomers. Macromolecules
12:948–952
69. Stuart MAC, Huck WTS, Genzer J, Muller M, Ober C, Stamm M, Sukhorukov GB, Szleifer I,
Tsukruk VV, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S (2010) Emerging
applications of stimuli-responsive polymer materials. Nat Mater 9:101–113
70. Peng F, Li GZ, Liu XX, Wu SZ, Tong Z (2008) Redox-responsive gel–sol/sol–gel transition
in poly(acrylic acid) aqueous solution containing Fe(III) ions switched by light. J Am Chem
Soc 130:16166–16167
71. Zhou GC, Harruna II, Ingram CW (2005) Ruthenium-centered thermosensitive polymers.
Polymer 46:10672–10677
72. Wool RP (2008) Self-healing materials: a review. Soft Matter 4:400–418
73. Beck JB, Rowan SJ (2003) Multistimuli, multiresponsive metallo-supramolecular polymers.
J Am Chem Soc 125:13922–13923
74. Weng WG, Li Z, Jamieson AM, Rowan SJ (2009) Effect of monomer structure on the
gelation of a class of metallo-supramolecular polymers. Soft Matter 5:4647–4657
75. Rowan SJ, Beck JB (2005) Metal–ligand induced supramolecular polymerization: a route to
responsive materials. Faraday Discuss 128:43–53
76. Murphy EB, Wudl F (2010) The world of smart healable materials. Prog Polym Sci
35:223–251
77. Wang F, Zhang JQ, Ding X, Dong SY, Liu M, Zheng B, Li SJ, Wu L, Yu YH, Gibson HW,
Huang FH (2010) Metal coordination mediated reversible conversion between linear and
cross-linked supramolecular polymers. Angew Chem Int Ed 49:1090–1094
78. Hager MD, Greil P, Leyens C, van der Zwaag S, Schubert US (2010) Self-healing materials.
Adv Mater 22:5424–5430
79. Herbst F, Do ¨hler D, Michael P, Binder WH (2013) Self-healing polymers via supramolecular
forces. Macromol Rapid Commun 34:203–220
80. Billiet S, Hillewaere XKD, Teixeira RFA, Du Prez FE (2013) Chemistry of crosslinking
processes for self-healing polymers. Macromol Rapid Commun 34:290–309
81. Brassinne J, Fustin C-A, Gohy JF (2013) Polymer gels constructed through metal–ligand
coordination. J Inorg Organomet Polym 23:23–40
82. Vaccaro E, Waite JH (2001) Yield and post-yield behavior of mussel byssal thread: a selfhealing biomolecular material. Biomacromolecules 2:906–911
83. Harrington MJ, Masic A, Holten-Andersen N, Waite JH, Fratzl P (2010) Iron-clad fibers: a
metal-based biological strategy for hard flexible coatings. Science 328:216–220
84. Holten-Andersen N, Harrington MJ, Birkedal H, Lee BP, Messersmith PB, Lee KYC, Waite
JH (2011) pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer
networks with near-covalent elastic moduli. Proc Natl Acad Sci USA 108:2651–2655
85. Barrett DG, Fullenkamp DE, He L, Holten-Andersen N, Lee KYC, Messersmith PB (2013)
pH-Based regulation of hydrogel mechanical properties through mussel-inspired chemistry
and processing. Adv Funct Mater 23:1111–1119
86. Harrington MJ, Waite JH (2008) pH-Dependent locking of giant mesogens in fibers
drawnfrom mussel byssal collagens. Biomacromolecules 9:1480–1486
Metallopolymers as an Emerging Class of Self-Healing Materials
255