CNT filled S-SBR-BR blends, 112–114
dynamic mechanical analysis curves,
118, 119
elastic modulus and tan δ, 116, 118
elastomeric applications, 112
filler–filler network, 113
loss tangent, MD and TD, 116, 117
MWCNT, 112, 116
80NR/20BR/22CB/3t-CNTs, 118
NR/XSBR based nanocomposites, 115,
116
Payne effect, 112
storage modulus, MD and TD, 116, 117
SWNTs, 111–112
Tubular nanofillers
carbon nanofiber, 94–95
carbon nanotubes, 93–94
halloysite nanotubes, 95–96
Two-dimensional fillers
dynamic storage and loss moduli, 44
elastomers, 43, 44
Maier Goritz mechanism, 45
mechanical properties, 44
micro and nano composites, 44
nanocomposites, 2D fillers, 46–48
nanoparticles, 2D fillers, 45–46
nonlinear behavior, 44
non-linear viscoelasticity (see Non-linear
viscoelasticity)
Payne effect, 44, 45
reinforcement and nonlinear
viscoelasticity, 55
rubber nanocomposites (see Rubber
nanocomposites)
soft biological tissues, 43
viscoelasticity, 43
V
Van der Waal’s interaction, 8, 261–262
Viscoelasticity
acid modified MWCNTs (A-MWCNTs), 33
Bonet’s model, 243
carbon black-filled rubber, 239
carbon black particles and rubber matrices:,
241
complex shear viscosity, 30
constitutive laws, 240
decomposition, 242
determinism, 239
differential
analytic functions, 259
constitutive relation, 256
dynamic moduli, 258
and integral viscoelastic models, 260
linear viscoelastic model, 257
polymer–filler network, 261
stationary stress, 258
Van der Waal’s interaction, 261
dynamic frequency sweep tests, 33
dynamic moduli, 33
elastomers, 30
frequency dependence, 34–35
integral formulation, 244–245
linear, 29–30
logarithmical plots, 32–33
Maxwell-model, 243
non-linear (see Non-linear viscoelasticity)
nonlinear theory, 240
polymeric materials, 240
quasi-linear viscoelasticity, 247–249
scaling law/power law, 33
single integral formulation, 245–247
state-variable formulations, 242
storage modulus, 30, 31
TPO/SWCNT nanocomposites, 32
viscous and elastic characteristics, 101
Z
Zinc dimethacrylate (ZDMA)
compounds, 175–176
concentration, 177
filler–filler network, 176
ionic crosslink network, 178–179
LVE, 177–178
non-linear viscoelasticity, 177
stress-softening, 179–180
Index
309
dynamic mechanical analysis curves,
118, 119
elastic modulus and tan δ, 116, 118
elastomeric applications, 112
filler–filler network, 113
loss tangent, MD and TD, 116, 117
MWCNT, 112, 116
80NR/20BR/22CB/3t-CNTs, 118
NR/XSBR based nanocomposites, 115,
116
Payne effect, 112
storage modulus, MD and TD, 116, 117
SWNTs, 111–112
Tubular nanofillers
carbon nanofiber, 94–95
carbon nanotubes, 93–94
halloysite nanotubes, 95–96
Two-dimensional fillers
dynamic storage and loss moduli, 44
elastomers, 43, 44
Maier Goritz mechanism, 45
mechanical properties, 44
micro and nano composites, 44
nanocomposites, 2D fillers, 46–48
nanoparticles, 2D fillers, 45–46
nonlinear behavior, 44
non-linear viscoelasticity (see Non-linear
viscoelasticity)
Payne effect, 44, 45
reinforcement and nonlinear
viscoelasticity, 55
rubber nanocomposites (see Rubber
nanocomposites)
soft biological tissues, 43
viscoelasticity, 43
V
Van der Waal’s interaction, 8, 261–262
Viscoelasticity
acid modified MWCNTs (A-MWCNTs), 33
Bonet’s model, 243
carbon black-filled rubber, 239
carbon black particles and rubber matrices:,
241
complex shear viscosity, 30
constitutive laws, 240
decomposition, 242
determinism, 239
differential
analytic functions, 259
constitutive relation, 256
dynamic moduli, 258
and integral viscoelastic models, 260
linear viscoelastic model, 257
polymer–filler network, 261
stationary stress, 258
Van der Waal’s interaction, 261
dynamic frequency sweep tests, 33
dynamic moduli, 33
elastomers, 30
frequency dependence, 34–35
integral formulation, 244–245
linear, 29–30
logarithmical plots, 32–33
Maxwell-model, 243
non-linear (see Non-linear viscoelasticity)
nonlinear theory, 240
polymeric materials, 240
quasi-linear viscoelasticity, 247–249
scaling law/power law, 33
single integral formulation, 245–247
state-variable formulations, 242
storage modulus, 30, 31
TPO/SWCNT nanocomposites, 32
viscous and elastic characteristics, 101
Z
Zinc dimethacrylate (ZDMA)
compounds, 175–176
concentration, 177
filler–filler network, 176
ionic crosslink network, 178–179
LVE, 177–178
non-linear viscoelasticity, 177
stress-softening, 179–180
Index
309
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