33. Aprem AS, Joseph K, Thomas S (2004) Studies on double networks in natural rubber
vulcanizates. J Appl Polym Sci 91(2):1068–1076
34. Wang J, Hamed GR, Umetsu K, Roland CM (2005) The Payne effect in double betwork
elastomers. Rubber Chem Technol 78(1):76–83
35. Flory PJ (1960) Elasticity of polymer networks cross-linked in state of strain. Trans Faraday
Soc 56:722–743
36. Baxandall LG, Edwards SF (1988) Deformation-dependent properties of polymer networks
constructed by addition of crosslinks under strain. Macromolecules 21(6):1763–1772
37. Termonia Y (1990) Molecular model for the mechanical properties of elastomers. 3. networks
cross-linked in a state of strain. Macromolecules 23(7):1976–1979
38. Dontsov A, Decandia F, Amelino L (1972) Elastic properties and structure of polybutadiene
vulcanized with magnesium methaceylate. J Appl Polym Sci 16(2):505–518
39. Saito Y, Nishimura K, Asada M, Toyoda A (1994) Polymerization behavior of zinc methacrylate study of zinc methacrylate/rubber/peroxide compounds; Part 2. J Jpn Rubber Soc 67
(12):867–872
40. Gao GX, Zhang ZC, Zheng YS, Jin ZH (2009) Effect of magnesium methacrylateand zinc
methacrylate on bond properties of thermal insulation material based on NBR/EPDM blends. J
Appl Polym Sci 113(6):3901–3909
41. Yin DH, Zhang Y, Zhang YX, Peng ZL, Fan Y, Sun K (2002) Reinforcement of peroxidecured styrene-butadiene rubber vulcanizates by mathacrylic acid and magnesium oxide. J Appl
Polym Sci 85(13):2667–2676
42. Yin DH, Zhang Y, Peng ZL, Zhang YX (2003) A comparison between the SBR vulcanizates
reinforced by magnesium methacrylate added directly or prepared in situ. Eur Polym J 39
(1):99–105
43. Lu YL, Liu L, Yang C, Tian M, Zhang LQ (2005) The morphology of zinc dimethacrylate
reinforced elastomers investigated by SEM and TEM. Eur Polym J 41(3):577–588
44. Peng ZL, Liang X, Zhang YX, Zhang Y (2002) Reinforcement of EPDM by in situ prepared
zinc dimethacrylate. J Appl Polym Sci 84(7):1339–1345
45. Yuan XH, Peng ZL, Zhang Y, Zhang YX (1999) The properties and structure of peroxidecured NBR containing magnesium methacrylate. Polym Polym Comp 7(6):431–436
46. Du AH, Peng ZL, Zhang Y, Zhang YX (2003) Properties of EVM vulcanizates reinforced by in
situ prepared sodium methacrylate. J Appl Polym Sci 89(8):2192–2200
47. Nie YJ, Huang GS, Qu LL, Zhang P, Weng GS, Wu JR (2010) Cure kinetics and morphology
of natural rubber reinforced by the in situ polymerization of zinc dimethacrylate. J Appl Polym
Sci 115(1):99–106
48. Du AH, Peng ZL, Zhang Y, Zhang YX (2002) Effect of magnesium methacrylate on the
mechanical properties of EVM vulcanizate. Polym Test 21(8):889–895
49. Lu YL, Liu L, Shen DY, Yang C, Zhang LQ (2004) Infrared study on in situ polymerization of
zinc dimethacrylate in poly(α-octylene-co-ethylene) elastomer. Polym Int 53(6):802–808
50. Klingender RC, Oyama M, Saito Y (1990) High-strength compound of highly saturated nitrile
and its applications. Rubber World 202(3):26–31
51. Lu YL, Liu L, Tian M, Geng HP, Zhang LQ (2005) Study on mechanical properties of
elastomers reinforced by zinc dimethacrylate. Eur Polym J 41(3):589–598
52. Du AH, Peng ZL, Zhang Y, Zhang YX (2004) Fracture morphology and mechanical properties
of ethylene/vinyl acetate rubber vulcanizates reinforced by in situ prepared sodium methacrylate. J Polym Sci B 42(9):1715–1724
53. Chen YK, Xu CH (2012) Stress-strain behaviors and crosslink networks studies of natural
rubber-zinc dimethacrylate composites. J Macro Sci B Phys 51(7):1384–1400
54. Xu CH, Chen YK, Cao LM, Wang YP, Zeng XR (2013) Study of the crosslinking evolution of
the styrene-butadiene rubber/zinc dimethacrylate based on dissolution/swelling experiments. J
Macro Sci B Phys 52(2):319–333
190
Y. Chen and C. Xu
vulcanizates. J Appl Polym Sci 91(2):1068–1076
34. Wang J, Hamed GR, Umetsu K, Roland CM (2005) The Payne effect in double betwork
elastomers. Rubber Chem Technol 78(1):76–83
35. Flory PJ (1960) Elasticity of polymer networks cross-linked in state of strain. Trans Faraday
Soc 56:722–743
36. Baxandall LG, Edwards SF (1988) Deformation-dependent properties of polymer networks
constructed by addition of crosslinks under strain. Macromolecules 21(6):1763–1772
37. Termonia Y (1990) Molecular model for the mechanical properties of elastomers. 3. networks
cross-linked in a state of strain. Macromolecules 23(7):1976–1979
38. Dontsov A, Decandia F, Amelino L (1972) Elastic properties and structure of polybutadiene
vulcanized with magnesium methaceylate. J Appl Polym Sci 16(2):505–518
39. Saito Y, Nishimura K, Asada M, Toyoda A (1994) Polymerization behavior of zinc methacrylate study of zinc methacrylate/rubber/peroxide compounds; Part 2. J Jpn Rubber Soc 67
(12):867–872
40. Gao GX, Zhang ZC, Zheng YS, Jin ZH (2009) Effect of magnesium methacrylateand zinc
methacrylate on bond properties of thermal insulation material based on NBR/EPDM blends. J
Appl Polym Sci 113(6):3901–3909
41. Yin DH, Zhang Y, Zhang YX, Peng ZL, Fan Y, Sun K (2002) Reinforcement of peroxidecured styrene-butadiene rubber vulcanizates by mathacrylic acid and magnesium oxide. J Appl
Polym Sci 85(13):2667–2676
42. Yin DH, Zhang Y, Peng ZL, Zhang YX (2003) A comparison between the SBR vulcanizates
reinforced by magnesium methacrylate added directly or prepared in situ. Eur Polym J 39
(1):99–105
43. Lu YL, Liu L, Yang C, Tian M, Zhang LQ (2005) The morphology of zinc dimethacrylate
reinforced elastomers investigated by SEM and TEM. Eur Polym J 41(3):577–588
44. Peng ZL, Liang X, Zhang YX, Zhang Y (2002) Reinforcement of EPDM by in situ prepared
zinc dimethacrylate. J Appl Polym Sci 84(7):1339–1345
45. Yuan XH, Peng ZL, Zhang Y, Zhang YX (1999) The properties and structure of peroxidecured NBR containing magnesium methacrylate. Polym Polym Comp 7(6):431–436
46. Du AH, Peng ZL, Zhang Y, Zhang YX (2003) Properties of EVM vulcanizates reinforced by in
situ prepared sodium methacrylate. J Appl Polym Sci 89(8):2192–2200
47. Nie YJ, Huang GS, Qu LL, Zhang P, Weng GS, Wu JR (2010) Cure kinetics and morphology
of natural rubber reinforced by the in situ polymerization of zinc dimethacrylate. J Appl Polym
Sci 115(1):99–106
48. Du AH, Peng ZL, Zhang Y, Zhang YX (2002) Effect of magnesium methacrylate on the
mechanical properties of EVM vulcanizate. Polym Test 21(8):889–895
49. Lu YL, Liu L, Shen DY, Yang C, Zhang LQ (2004) Infrared study on in situ polymerization of
zinc dimethacrylate in poly(α-octylene-co-ethylene) elastomer. Polym Int 53(6):802–808
50. Klingender RC, Oyama M, Saito Y (1990) High-strength compound of highly saturated nitrile
and its applications. Rubber World 202(3):26–31
51. Lu YL, Liu L, Tian M, Geng HP, Zhang LQ (2005) Study on mechanical properties of
elastomers reinforced by zinc dimethacrylate. Eur Polym J 41(3):589–598
52. Du AH, Peng ZL, Zhang Y, Zhang YX (2004) Fracture morphology and mechanical properties
of ethylene/vinyl acetate rubber vulcanizates reinforced by in situ prepared sodium methacrylate. J Polym Sci B 42(9):1715–1724
53. Chen YK, Xu CH (2012) Stress-strain behaviors and crosslink networks studies of natural
rubber-zinc dimethacrylate composites. J Macro Sci B Phys 51(7):1384–1400
54. Xu CH, Chen YK, Cao LM, Wang YP, Zeng XR (2013) Study of the crosslinking evolution of
the styrene-butadiene rubber/zinc dimethacrylate based on dissolution/swelling experiments. J
Macro Sci B Phys 52(2):319–333
190
Y. Chen and C. Xu