107. Nagaki A, Takabayashi N, Tomida Y et al (2008) Synthesis of unsymmetrical biaryls by
means of mono-selective reaction of polyhaloarenes using integrated microflow system.
Org Lett 18:3937–3940
108. Nagaki A, Takabayashi N, Tomida Y et al (2009) Synthesis of unsymmetrically substituted
biaryls via sequential lithiation of dibromobiaryls using integrated microflow systems.
Beilstein J Org Chem 5:16
109. Ishigaki Y, Suzuki T, Nishida J et al (2011) Hysteretic tricolor electrochromic systems based
on the dynamic redox properties of unsymmetrically substituted dihydrophenanthrenes and
biphenyl-2,2
0 -diyl dications: efficient precursor synthesis by a flow microreactor method.
Materials 4:1906–1926
110. Suzuki T, Uchimura Y, Ishigaki Y et al (2012) Non-additive substituent effects on expanding
prestrained C–C bond in crystal: X-ray analyses on unsymmetrically substituted tetraarylpyracenes prepared by a flow microreactor method. Chem Lett 41:541–543
111. Midorikawa K, Suga S, Yoshida J (2006) Selective monoiodination of aromatic compounds
with electrochemically generated I
+ using micromixing. Chem Commun 3794–3796
112. Kataoka K, Hagiwara Y, Midorikawa K et al (2008) Practical electrochemical iodination of
aromatic compounds. Org Process Res Dev 12:1130–1136
113. Hessel V, Hofmann C, L€ owe H et al (2004) Selectivity gains and energy savings for the
industrial phenyl boronic acid process using micromixer/tubular reactors. Org Process Res
Dev 8:511–523
114. Yoshida J, Suga S, Suzuki S et al (1999) Direct oxidative carbon-carbon bond formation
using the “cation pool” method. Generation of iminium cation pools and their reaction with
carbon nucleophiles. J Am Chem Soc 121:9546–9549
115. Yoshida J, Suga S (2002) Basic concepts of “cation pool” and “cation flow” methods and their
applications in conventional and combinatorial organic synthesis. Chem Eur J 8:2650–2658
116. Suga S, Nishida T, Yamada D et al (2004) Three-component coupling based on the “cation
pool” method. J Am Chem Soc 126:14338–14339
117. Suga S, Suzuki S, Yamamoto A et al (2000) Electrooxidative generation and accumulation of
alkoxycarbenium ions and their reactions with carbon nucleophiles. J Am Chem Soc
122:10244–10245
118. Suga S, Matsumoto K, Ueoka K et al (2006) Indirect cation pool method. Rapid generation of
alkoxycarbenium ion pools from thioacetals. J Am Chem Soc 128:7710–7711
119. Suzuki S, Matsumoto K, Kawamura K et al (2004) Generation of alkoxycarbenium ion pools
from thioacetals and applications to glycosylation chemistry. Org Lett 6:3755–3758
120. Okajima M, Suga S, Itami K et al (2005) “Cation pool” method based on C–C bond
dissociation. Effective generation of monocations and dications. J Am Chem Soc
127:6930–6931
121. Saito K, Ueoka K, Matsumoto K et al (2011) Indirect cation flow method. Flash generation of
alkoxycarbenium ions and studies on stability of glycosyl cations. Angew Chem Int Ed
50:5153–5156
122. Okajima M, Soga K, Nokami T et al (2006) Oxidative generation of diarylcarbenium ion
pools. Org Lett 8:5005–5007
123. Okajima M, Soga K, Watanabe T et al (2009) Generation of diarylcarbenium ion pools via
electrochemical C–H bond dissociation. Bull Chem Soc Jpn 82:594–599
124. Nokami T, Shibuya A, Tsuyama H et al (2007) Electrochemical generarion of glycosyl
triflate pools. J Am Chem Soc 129:10922–10928
125. Nagaki A, Kawamura K, Suga S et al (2004) “Cation pool” initiated controlled/living
polymerization using microsystems. J Am Chem Soc 126:14702–14703
126. Cho CG, Feit BA, Webster OW (1990) Cationic polymerization of isobutyl vinyl ether:
livingness enhancement by dialkyl sulfide. Macromolecules 23:1918–1923
127. Iwasaki T, Nagaki A, Yoshida J (2007) Microsystem controlled cationic polymerization of
vinyl ethers initiated by CF 3 SO 3 H. Chem Commun 1263–1265
44
A. Nagaki and J.-i. Yoshida
means of mono-selective reaction of polyhaloarenes using integrated microflow system.
Org Lett 18:3937–3940
108. Nagaki A, Takabayashi N, Tomida Y et al (2009) Synthesis of unsymmetrically substituted
biaryls via sequential lithiation of dibromobiaryls using integrated microflow systems.
Beilstein J Org Chem 5:16
109. Ishigaki Y, Suzuki T, Nishida J et al (2011) Hysteretic tricolor electrochromic systems based
on the dynamic redox properties of unsymmetrically substituted dihydrophenanthrenes and
biphenyl-2,2
0 -diyl dications: efficient precursor synthesis by a flow microreactor method.
Materials 4:1906–1926
110. Suzuki T, Uchimura Y, Ishigaki Y et al (2012) Non-additive substituent effects on expanding
prestrained C–C bond in crystal: X-ray analyses on unsymmetrically substituted tetraarylpyracenes prepared by a flow microreactor method. Chem Lett 41:541–543
111. Midorikawa K, Suga S, Yoshida J (2006) Selective monoiodination of aromatic compounds
with electrochemically generated I
+ using micromixing. Chem Commun 3794–3796
112. Kataoka K, Hagiwara Y, Midorikawa K et al (2008) Practical electrochemical iodination of
aromatic compounds. Org Process Res Dev 12:1130–1136
113. Hessel V, Hofmann C, L€ owe H et al (2004) Selectivity gains and energy savings for the
industrial phenyl boronic acid process using micromixer/tubular reactors. Org Process Res
Dev 8:511–523
114. Yoshida J, Suga S, Suzuki S et al (1999) Direct oxidative carbon-carbon bond formation
using the “cation pool” method. Generation of iminium cation pools and their reaction with
carbon nucleophiles. J Am Chem Soc 121:9546–9549
115. Yoshida J, Suga S (2002) Basic concepts of “cation pool” and “cation flow” methods and their
applications in conventional and combinatorial organic synthesis. Chem Eur J 8:2650–2658
116. Suga S, Nishida T, Yamada D et al (2004) Three-component coupling based on the “cation
pool” method. J Am Chem Soc 126:14338–14339
117. Suga S, Suzuki S, Yamamoto A et al (2000) Electrooxidative generation and accumulation of
alkoxycarbenium ions and their reactions with carbon nucleophiles. J Am Chem Soc
122:10244–10245
118. Suga S, Matsumoto K, Ueoka K et al (2006) Indirect cation pool method. Rapid generation of
alkoxycarbenium ion pools from thioacetals. J Am Chem Soc 128:7710–7711
119. Suzuki S, Matsumoto K, Kawamura K et al (2004) Generation of alkoxycarbenium ion pools
from thioacetals and applications to glycosylation chemistry. Org Lett 6:3755–3758
120. Okajima M, Suga S, Itami K et al (2005) “Cation pool” method based on C–C bond
dissociation. Effective generation of monocations and dications. J Am Chem Soc
127:6930–6931
121. Saito K, Ueoka K, Matsumoto K et al (2011) Indirect cation flow method. Flash generation of
alkoxycarbenium ions and studies on stability of glycosyl cations. Angew Chem Int Ed
50:5153–5156
122. Okajima M, Soga K, Nokami T et al (2006) Oxidative generation of diarylcarbenium ion
pools. Org Lett 8:5005–5007
123. Okajima M, Soga K, Watanabe T et al (2009) Generation of diarylcarbenium ion pools via
electrochemical C–H bond dissociation. Bull Chem Soc Jpn 82:594–599
124. Nokami T, Shibuya A, Tsuyama H et al (2007) Electrochemical generarion of glycosyl
triflate pools. J Am Chem Soc 129:10922–10928
125. Nagaki A, Kawamura K, Suga S et al (2004) “Cation pool” initiated controlled/living
polymerization using microsystems. J Am Chem Soc 126:14702–14703
126. Cho CG, Feit BA, Webster OW (1990) Cationic polymerization of isobutyl vinyl ether:
livingness enhancement by dialkyl sulfide. Macromolecules 23:1918–1923
127. Iwasaki T, Nagaki A, Yoshida J (2007) Microsystem controlled cationic polymerization of
vinyl ethers initiated by CF 3 SO 3 H. Chem Commun 1263–1265
44
A. Nagaki and J.-i. Yoshida