468
12 Localized or Spatially Selective Electrodeposition Methods
transient following the particle nucleation [182]. When Pt was deposited onto glassy
carbon from acidic femtomolar Pt(IV) solution, the particle nucleation at <0.1 Hz
frequency was accompanied by the onset of the hydrogen evolution, leading to significantly larger currents than the electrochemical nucleation of the nanoparticle itself.
After the activation of the electrode due to the appearance of a new particle with high
electrocatalytic activity, the current peak decayed due to the shielding effect of the
hydrogen bubble covering the active spot of the electrode. A very similar process
was observed upon anodic polarization and nucleation of Co-oxide nanoparticles
accompanied by oxygen evolution. In both cases, the nanoparticle growth became
limited by the side reaction originating from the locally modified electrochemical
activity.
References
1. Chazalviel JN, Rosso M, Chassaing E, Fleury V (1996) J Electroanal Chem 407:61–73
2. Huth J, Swinney H, McCormick W, Kuhn A, Argoul F (1995) Phys Rev E 51:3444–3458
3. Mocskos E, Marschall G (2009) Electron Trans Numer Anal 34:90–101
4. Marshall G, Mocskos E, González G, Dengra S, Molina FV, Iemmi C (2006) Electrochim
Acta 51:3058–3065
5. González G, Rosso M, Chassaing E, Chazalviel JN (2007) Electrochim Acta 53:141–144
6. Fleury V, Chazalviel JN, Rosso M (1993) Phys Rev E 48:1279–1299
7. Deng Y, Pritzker M (1992) J Electroanal Chem 336:25–34
8. Sun B, Zou XW, Jin ZZ (2004) Electrochim Acta 50:1031–1037
9. Zhong S, Wang M, Yin XB, Zhu JM, Peng RW, Wang Y, Ming NB (2001) J Phys Soc Japan
70:1452–1455
10. Wang M, Zhong S, Yin XB, Zhu JM, Peng RW, Wang Y, Zhang KQ, Ming NB (2001) Phys
Rev Lett 86:3827–3830
11. Zhong S, Wang Y, Wang M, Zhang MZ, Yin XB, Peng RW, Ming NB (2003) Phys Rev E
67:061601(1–9)
12. Zhang MZ, Wang M, Zhang Z, Zhu JM, Peng RW, Minga NB (2004) Electrochim Acta
49:2379–2383
13. Zhang M, Zuo G, Zong Z, Cheng H, He Z, Yang C, Zou G (2006) Small 2:727–731
14. Zhang B, Weng YY, Huang XP, WangM, Peng RW, Ming NB, Yang B, Lu N, Chi L (2009)
Adv Mater 21:3576–3580
15. Yu G, Hu X, Liu D, Sun D, Li J, Zhang H, Liu H, Wang (2010) J Electroanal Chem 638:225–230
16. Weng YY, Zhang B, Fu SJ, Wang M, Peng RW, Ma GB, Shu DJ, Ming NB (2010) Phys Rev
E 81:051607(1–6)
17. Wu Z, Bao YJ, Yu GW, Wang M, Peng RW, Fleury V, Hao XP, Ming NB (2006) J Phys
Condens Matter 18:5425–5434
18. Liu T, Wang S, Shi ZL, Ma GB, Wang M, Peng RW, Hao XP, Ming NB (2007) Phys Rev E
75:051606(1–6)
19. Liu C, Yao B, Wang S, Tian H, Zhang M (2009) J Phys Chem C 113:21303–21307
20. Chen F, Li J, Yu F, Zhao D, Wang F, Chen Y, Peng RW, Wang M (2016) Adv Mater 28:7193–
7199
21. Cui G, Gao L, Yao B, Wang S, Zhang P, Zhang M (2013) Electrochem Commun 30:42–45
22. Cui G, Xiao C, Zhang P, Zhang M (2016) Phys Chem Chem Phys 18:10918–10923
12 Localized or Spatially Selective Electrodeposition Methods
transient following the particle nucleation [182]. When Pt was deposited onto glassy
carbon from acidic femtomolar Pt(IV) solution, the particle nucleation at <0.1 Hz
frequency was accompanied by the onset of the hydrogen evolution, leading to significantly larger currents than the electrochemical nucleation of the nanoparticle itself.
After the activation of the electrode due to the appearance of a new particle with high
electrocatalytic activity, the current peak decayed due to the shielding effect of the
hydrogen bubble covering the active spot of the electrode. A very similar process
was observed upon anodic polarization and nucleation of Co-oxide nanoparticles
accompanied by oxygen evolution. In both cases, the nanoparticle growth became
limited by the side reaction originating from the locally modified electrochemical
activity.
References
1. Chazalviel JN, Rosso M, Chassaing E, Fleury V (1996) J Electroanal Chem 407:61–73
2. Huth J, Swinney H, McCormick W, Kuhn A, Argoul F (1995) Phys Rev E 51:3444–3458
3. Mocskos E, Marschall G (2009) Electron Trans Numer Anal 34:90–101
4. Marshall G, Mocskos E, González G, Dengra S, Molina FV, Iemmi C (2006) Electrochim
Acta 51:3058–3065
5. González G, Rosso M, Chassaing E, Chazalviel JN (2007) Electrochim Acta 53:141–144
6. Fleury V, Chazalviel JN, Rosso M (1993) Phys Rev E 48:1279–1299
7. Deng Y, Pritzker M (1992) J Electroanal Chem 336:25–34
8. Sun B, Zou XW, Jin ZZ (2004) Electrochim Acta 50:1031–1037
9. Zhong S, Wang M, Yin XB, Zhu JM, Peng RW, Wang Y, Ming NB (2001) J Phys Soc Japan
70:1452–1455
10. Wang M, Zhong S, Yin XB, Zhu JM, Peng RW, Wang Y, Zhang KQ, Ming NB (2001) Phys
Rev Lett 86:3827–3830
11. Zhong S, Wang Y, Wang M, Zhang MZ, Yin XB, Peng RW, Ming NB (2003) Phys Rev E
67:061601(1–9)
12. Zhang MZ, Wang M, Zhang Z, Zhu JM, Peng RW, Minga NB (2004) Electrochim Acta
49:2379–2383
13. Zhang M, Zuo G, Zong Z, Cheng H, He Z, Yang C, Zou G (2006) Small 2:727–731
14. Zhang B, Weng YY, Huang XP, WangM, Peng RW, Ming NB, Yang B, Lu N, Chi L (2009)
Adv Mater 21:3576–3580
15. Yu G, Hu X, Liu D, Sun D, Li J, Zhang H, Liu H, Wang (2010) J Electroanal Chem 638:225–230
16. Weng YY, Zhang B, Fu SJ, Wang M, Peng RW, Ma GB, Shu DJ, Ming NB (2010) Phys Rev
E 81:051607(1–6)
17. Wu Z, Bao YJ, Yu GW, Wang M, Peng RW, Fleury V, Hao XP, Ming NB (2006) J Phys
Condens Matter 18:5425–5434
18. Liu T, Wang S, Shi ZL, Ma GB, Wang M, Peng RW, Hao XP, Ming NB (2007) Phys Rev E
75:051606(1–6)
19. Liu C, Yao B, Wang S, Tian H, Zhang M (2009) J Phys Chem C 113:21303–21307
20. Chen F, Li J, Yu F, Zhao D, Wang F, Chen Y, Peng RW, Wang M (2016) Adv Mater 28:7193–
7199
21. Cui G, Gao L, Yao B, Wang S, Zhang P, Zhang M (2013) Electrochem Commun 30:42–45
22. Cui G, Xiao C, Zhang P, Zhang M (2016) Phys Chem Chem Phys 18:10918–10923