81. Guzmán J, García-Orduña P, Polo V, Lahoz FJ, Oro LA, Fernández-Alvarez FJ (2019)
Ir-catalyzed selective reduction of CO 2 to the methoxy or formate level with HSiMe
(OSiMe 3 ) 2 . Cat Sci Technol 9:2858–2867
82. Ojeda-Amador AI, Munarriz J, Alamán-Valtierra P, Polo V, Puerta-Oteo R, Jiménez MV,
Fernández-Alvarez FJ, Pérez-Torrente JJ (2019) Mechanistic insights on the functionalization
of CO 2 with amines and hydrosilanes catalyzed by a zwitterionic iridium carboxylatefunctionalized Bis-NHC catalyst. ChemCatChem 11:5524–5535
83. Jansen A, Görls H, Pitter S (2000) trans-[Ru
II
Cl(MeCN) 5 ][Ru
III Cl 4 (MeCN) 2 ]: a reactive
intermediate in the homogeneous catalyzed hydrosilylation of carbon dioxide. Organometallics 19:135–138
84. Deglmann P, Ember E, Hofmann P, Pitter S, Walter O (2007) Experimental and theoretical
investigations on the catalytic hydrosilylation of carbon dioxide with ruthenium nitrile complexes. Chem A Eur J 13:2864–2879
85. Scheuermann ML, Semproni SP, Pappas I, Chirik PJ (2014) Carbon dioxide hydrosilylation
promoted by cobalt pincer complexes. Inorg Chem 53:9463–9465
86. Itagaki S, Yamaguchi K, Mizuno N (2013) Catalytic synthesis of silyl formates with 1 atm of
CO 2 and their utilization for synthesis of formyl compounds and formic acid. J Mol Catal A
Chem 366:347–352
87. Takaya J, Iwasawa N (2017) Synthesis, structure, and catalysis of palladium complexes
bearing a group 13 metalloligand: remarkable effect of an aluminum-metalloligand in
hydrosilylation of CO 2 . J Am Chem Soc 139:6074–6077
88. Rios P, Díez J, López-Serrano J, Rodríguez A, Conejero S (2016) Cationic platinum(II) σ-SiH
complexes in carbon dioxide hydrosilation. Chem A Eur J 22:16791–16795
89. Motokura K, Kashiwame D, Takahashi N, Miyaji A, Baba T (2013) Highly active and
selective catalysis of copper diphosphine complexes for the transformation of carbon dioxide
into silyl formate. Chem A Eur J 19:10030–10037
90. Zhang L, Cheng J, Hou Z (2013) Highly efficient catalytic hydrosilylation of carbon dioxide
by an N-heterocyclic carbene copper catalyst. ChemCommun 49:4782–4784
91. Sattler W, Parkin G (2012) Zinc catalysts for on-demand hydrogen generation and carbon
dioxide functionalization. J Am Chem Soc 134:17462–17465
92. Specklin D, Fliedel C, Gourlaouen C, Bruyere J-C, Avilés T, Boudon C, Ruhlmann L,
Dagorne S (2017) N-heterocyclic carbene based tri-organyl-Zn–alkyl cations: synthesis,
structures, and use in CO 2 functionalization. Chem A Eur J 23:5509–5519
93. Morris DS, Weetman C, Wennmacher JTC, Cokoja M, Drees M, Kühn FE, Love JB (2017)
Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the
perrhenate anion. Cat Sci Technol 7:2838–2845
94. Specklin D, Hild F, Fliedel C, Gourlaouen C, Veiros LF, Dagorne S (2017) Accessing
two-coordinate Zn
II Organocations by NHC coordination: synthesis, structure, and use as
π-Lewis acids in alkene, alkyne, and CO 2 hydrosilylation. Chem A Eur J 23:15908–15912
95. Riduan SN, Zhang Y, Ying JY (2009) Conversion of carbon dioxide into methanol with
silanes over N-heterocyclic carbene catalysts. Angew Chem Int Ed 48:3322–3325
96. Matsuo T, Kawaguchi H (2006) From carbon dioxide to methane: homogeneous reduction of
carbon dioxide with hydrosilanes catalyzed by zirconiumÀborane complexes. J Am Chem Soc
128:12362–12363
97. Luconi L, Rossin A, Tuci G, Gafurov Z, Lyubov DM, Trifonov AA, Cicchi S, Ba H, PhamHuu C, Yakhvarov D, Giambastiani G (2019) Benzoimidazole-pyridylamido zirconium and
hafnium alkyl complexes as homogeneous catalysts for tandem carbon dioxide hydrosilylation
to methane. ChemCatChem 11:495–510
98. Park S, Bézier D, Brookhart M (2012) An efficient iridium catalyst for reduction of carbon
dioxide to methane with trialkylsilanes. J Am Chem Soc 134:11404–11407
99. Mitton SJ, Turculet L (2012) Mild reduction of carbon dioxide to methane with tertiary silanes
catalyzed by platinum and palladium silyl pincer complexes. Chem A Eur J 18:15258–15262
Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon. . .
323
Ir-catalyzed selective reduction of CO 2 to the methoxy or formate level with HSiMe
(OSiMe 3 ) 2 . Cat Sci Technol 9:2858–2867
82. Ojeda-Amador AI, Munarriz J, Alamán-Valtierra P, Polo V, Puerta-Oteo R, Jiménez MV,
Fernández-Alvarez FJ, Pérez-Torrente JJ (2019) Mechanistic insights on the functionalization
of CO 2 with amines and hydrosilanes catalyzed by a zwitterionic iridium carboxylatefunctionalized Bis-NHC catalyst. ChemCatChem 11:5524–5535
83. Jansen A, Görls H, Pitter S (2000) trans-[Ru
II
Cl(MeCN) 5 ][Ru
III Cl 4 (MeCN) 2 ]: a reactive
intermediate in the homogeneous catalyzed hydrosilylation of carbon dioxide. Organometallics 19:135–138
84. Deglmann P, Ember E, Hofmann P, Pitter S, Walter O (2007) Experimental and theoretical
investigations on the catalytic hydrosilylation of carbon dioxide with ruthenium nitrile complexes. Chem A Eur J 13:2864–2879
85. Scheuermann ML, Semproni SP, Pappas I, Chirik PJ (2014) Carbon dioxide hydrosilylation
promoted by cobalt pincer complexes. Inorg Chem 53:9463–9465
86. Itagaki S, Yamaguchi K, Mizuno N (2013) Catalytic synthesis of silyl formates with 1 atm of
CO 2 and their utilization for synthesis of formyl compounds and formic acid. J Mol Catal A
Chem 366:347–352
87. Takaya J, Iwasawa N (2017) Synthesis, structure, and catalysis of palladium complexes
bearing a group 13 metalloligand: remarkable effect of an aluminum-metalloligand in
hydrosilylation of CO 2 . J Am Chem Soc 139:6074–6077
88. Rios P, Díez J, López-Serrano J, Rodríguez A, Conejero S (2016) Cationic platinum(II) σ-SiH
complexes in carbon dioxide hydrosilation. Chem A Eur J 22:16791–16795
89. Motokura K, Kashiwame D, Takahashi N, Miyaji A, Baba T (2013) Highly active and
selective catalysis of copper diphosphine complexes for the transformation of carbon dioxide
into silyl formate. Chem A Eur J 19:10030–10037
90. Zhang L, Cheng J, Hou Z (2013) Highly efficient catalytic hydrosilylation of carbon dioxide
by an N-heterocyclic carbene copper catalyst. ChemCommun 49:4782–4784
91. Sattler W, Parkin G (2012) Zinc catalysts for on-demand hydrogen generation and carbon
dioxide functionalization. J Am Chem Soc 134:17462–17465
92. Specklin D, Fliedel C, Gourlaouen C, Bruyere J-C, Avilés T, Boudon C, Ruhlmann L,
Dagorne S (2017) N-heterocyclic carbene based tri-organyl-Zn–alkyl cations: synthesis,
structures, and use in CO 2 functionalization. Chem A Eur J 23:5509–5519
93. Morris DS, Weetman C, Wennmacher JTC, Cokoja M, Drees M, Kühn FE, Love JB (2017)
Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the
perrhenate anion. Cat Sci Technol 7:2838–2845
94. Specklin D, Hild F, Fliedel C, Gourlaouen C, Veiros LF, Dagorne S (2017) Accessing
two-coordinate Zn
II Organocations by NHC coordination: synthesis, structure, and use as
π-Lewis acids in alkene, alkyne, and CO 2 hydrosilylation. Chem A Eur J 23:15908–15912
95. Riduan SN, Zhang Y, Ying JY (2009) Conversion of carbon dioxide into methanol with
silanes over N-heterocyclic carbene catalysts. Angew Chem Int Ed 48:3322–3325
96. Matsuo T, Kawaguchi H (2006) From carbon dioxide to methane: homogeneous reduction of
carbon dioxide with hydrosilanes catalyzed by zirconiumÀborane complexes. J Am Chem Soc
128:12362–12363
97. Luconi L, Rossin A, Tuci G, Gafurov Z, Lyubov DM, Trifonov AA, Cicchi S, Ba H, PhamHuu C, Yakhvarov D, Giambastiani G (2019) Benzoimidazole-pyridylamido zirconium and
hafnium alkyl complexes as homogeneous catalysts for tandem carbon dioxide hydrosilylation
to methane. ChemCatChem 11:495–510
98. Park S, Bézier D, Brookhart M (2012) An efficient iridium catalyst for reduction of carbon
dioxide to methane with trialkylsilanes. J Am Chem Soc 134:11404–11407
99. Mitton SJ, Turculet L (2012) Mild reduction of carbon dioxide to methane with tertiary silanes
catalyzed by platinum and palladium silyl pincer complexes. Chem A Eur J 18:15258–15262
Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon. . .
323