62. Ribeiro APC, Martins LMDRS, Pombeiro AJL (2017) Carbon dioxide-to-methanol single-pot
conversion using a C-scorpionate iron(II) catalyst. Green Chem 19:4811–4815
63. Thenert K, Beydoun K, Wiesenthal J, Leitner W, Klankermayer J (2016) Ruthenium-catalyzed
synthesis of dialkoxymethane ethers utilizing carbon dioxide and molecular hydrogen. Angew
Chem Int Ed 55:12266–12269
64. Siebert M, Seibicke M, Siegle AF, Kräh S, Trapp O (2019) Selective ruthenium-catalyzed
transformation of carbon dioxide: an alternative approach toward formaldehyde. J Am Chem
Soc 141:334–341
65. Seibicke M, Siebert M, Siegle AF, Gutenthaler SM, Trapp O (2019) Application of heterotriphos ligands in the selective ruthenium-catalyzed transformation of carbon dioxide to the
formaldehyde oxidation state. Organometallics 38:1809–1814
66. Westhues N, Belleflamme M, Klankermayer J (2019) Base-free hydrogenation of carbon
dioxide to methyl formate with a molecular ruthenium-phosphine catalyst. ChemCatChem
11:5269–5274
67. Zhang Y, Zhang T, Das S (2020) Catalytic transformation of CO 2 into C1 chemicals using
hydrosilanes as reducing agents. Green Chem 22:1800–1820
68. Addis D, Das S, Junge K, Beller M (2011) Selective reduction of carboxylic acid derivatives
by catalytic hydrosilylation. Angew Chem Int Ed 50:6004–6011
69. Garcés K, Fernández-Alvarez FJ, Polo V, Lalrempuia R, Pérez-Torrente JJ, Oro LA (2014)
Iridium-catalyzed hydrogen production from hydrosilanes and water. ChemCatChem
6:1691–1697
70. Aliaga-Lavrijsen M, Iglesias M, Cebollada A, Garcés K, García N, Sanz Miguel PJ,
Fernández-Alvarez FJ, Pérez-Torrente JJ, Oro LA (2015) Hydrolysis and methanolysis of
silanes catalyzed by iridium(III) bis-N-heterocyclic carbene complexes: influence of the
wingtip groups. Organometallics 34:2378–2385
71. Guzmán J, García-Orduña P, Lahoz FJ, Fernández-Alvarez FJ (2020) Unprecedent formation
of methylsilylcarbonates from iridium-catalyzed reduction of CO 2 with hydrosilanes. RSC
Adv 10:9582–9586
72. Koinuma H, Kawakami F, Kato H, Hirai H (1981) Hydrosilylation of carbon dioxide catalysed
by ruthenium complexes. J Chem Soc Chem Commun:213–214
73. Süss-Fink G, Reiner J (1981) Anionische Rutheniumcluster als Katalysatoren bei der
Hydrosilylierung von Kohlendioxid. J Organomet Chem 221:C36–C38
74. Eisenschmid TC, Eisenberg R (1989) The iridium complex catalyzed reduction of carbon
dioxide to methoxide by alkylsilanes. Organometallics 8:1822–1824
75. Motokura K, Nakagawa C, Pramudita RA, Manaka Y (2019) Formate-catalyzed selective
reduction of carbon dioxide to formate products using hydrosilanes. ACS Sustain Chem Eng
7:11056–11061
76. Lalrempuia R, Iglesias M, Polo V, Sanz Miguel PJ, Fernández-Alvarez FJ, Pérez-Torrente JJ,
Oro LA (2012) Effective fixation of CO 2 by iridium-catalyzed hydrosilylation. Angew Chem
Int Ed 51:12824–12827
77. Jaseer EA, Akhtar MN, Osman M, Al-Shammari A, Oladipo HB, Garcés K, FernándezAlvarez FJ, Al-Khattaf S, Oro LA (2015) Solvent-free iridium-catalyzed CO 2 hydrosilylation:
experiments and kinetic modeling. Cat Sci Technol 5:274–279
78. Oladipo HB, Jaseer EA, Julián A, Fernández-Alvarez FJ, Al-Khattaf S, Oro LA (2015) Effect
of the CO 2 -pressure on the hydrosilylation of CO 2 catalyzed by [Ir (NSiN)] species. J CO 2
Utilization 12:21–26
79. Julián A, Jaseer EA, Garcés K, Fernández-Alvarez FJ, García-Orduña P, Lahoz FJ, Oro LA
(2016) Tuning the activity and selectivity of iridium-NSiN catalyzed CO 2 hydrosilylation
processes. Cat Sci Technol 6:4410–4417
80. Julián A, Guzmán J, Jaseer EA, Fernández-Alvarez FJ, Royo R, Polo V, García-Orduña P,
Lahoz FJ, Oro LA (2017) Mechanistic insights on the reduction of CO 2 to silylformates
catalyzed by Ir-NSiN species. Chem A Eur J 23:11898–11907
322
F. J. Fernández-Alvarez and L. A. Oro
conversion using a C-scorpionate iron(II) catalyst. Green Chem 19:4811–4815
63. Thenert K, Beydoun K, Wiesenthal J, Leitner W, Klankermayer J (2016) Ruthenium-catalyzed
synthesis of dialkoxymethane ethers utilizing carbon dioxide and molecular hydrogen. Angew
Chem Int Ed 55:12266–12269
64. Siebert M, Seibicke M, Siegle AF, Kräh S, Trapp O (2019) Selective ruthenium-catalyzed
transformation of carbon dioxide: an alternative approach toward formaldehyde. J Am Chem
Soc 141:334–341
65. Seibicke M, Siebert M, Siegle AF, Gutenthaler SM, Trapp O (2019) Application of heterotriphos ligands in the selective ruthenium-catalyzed transformation of carbon dioxide to the
formaldehyde oxidation state. Organometallics 38:1809–1814
66. Westhues N, Belleflamme M, Klankermayer J (2019) Base-free hydrogenation of carbon
dioxide to methyl formate with a molecular ruthenium-phosphine catalyst. ChemCatChem
11:5269–5274
67. Zhang Y, Zhang T, Das S (2020) Catalytic transformation of CO 2 into C1 chemicals using
hydrosilanes as reducing agents. Green Chem 22:1800–1820
68. Addis D, Das S, Junge K, Beller M (2011) Selective reduction of carboxylic acid derivatives
by catalytic hydrosilylation. Angew Chem Int Ed 50:6004–6011
69. Garcés K, Fernández-Alvarez FJ, Polo V, Lalrempuia R, Pérez-Torrente JJ, Oro LA (2014)
Iridium-catalyzed hydrogen production from hydrosilanes and water. ChemCatChem
6:1691–1697
70. Aliaga-Lavrijsen M, Iglesias M, Cebollada A, Garcés K, García N, Sanz Miguel PJ,
Fernández-Alvarez FJ, Pérez-Torrente JJ, Oro LA (2015) Hydrolysis and methanolysis of
silanes catalyzed by iridium(III) bis-N-heterocyclic carbene complexes: influence of the
wingtip groups. Organometallics 34:2378–2385
71. Guzmán J, García-Orduña P, Lahoz FJ, Fernández-Alvarez FJ (2020) Unprecedent formation
of methylsilylcarbonates from iridium-catalyzed reduction of CO 2 with hydrosilanes. RSC
Adv 10:9582–9586
72. Koinuma H, Kawakami F, Kato H, Hirai H (1981) Hydrosilylation of carbon dioxide catalysed
by ruthenium complexes. J Chem Soc Chem Commun:213–214
73. Süss-Fink G, Reiner J (1981) Anionische Rutheniumcluster als Katalysatoren bei der
Hydrosilylierung von Kohlendioxid. J Organomet Chem 221:C36–C38
74. Eisenschmid TC, Eisenberg R (1989) The iridium complex catalyzed reduction of carbon
dioxide to methoxide by alkylsilanes. Organometallics 8:1822–1824
75. Motokura K, Nakagawa C, Pramudita RA, Manaka Y (2019) Formate-catalyzed selective
reduction of carbon dioxide to formate products using hydrosilanes. ACS Sustain Chem Eng
7:11056–11061
76. Lalrempuia R, Iglesias M, Polo V, Sanz Miguel PJ, Fernández-Alvarez FJ, Pérez-Torrente JJ,
Oro LA (2012) Effective fixation of CO 2 by iridium-catalyzed hydrosilylation. Angew Chem
Int Ed 51:12824–12827
77. Jaseer EA, Akhtar MN, Osman M, Al-Shammari A, Oladipo HB, Garcés K, FernándezAlvarez FJ, Al-Khattaf S, Oro LA (2015) Solvent-free iridium-catalyzed CO 2 hydrosilylation:
experiments and kinetic modeling. Cat Sci Technol 5:274–279
78. Oladipo HB, Jaseer EA, Julián A, Fernández-Alvarez FJ, Al-Khattaf S, Oro LA (2015) Effect
of the CO 2 -pressure on the hydrosilylation of CO 2 catalyzed by [Ir (NSiN)] species. J CO 2
Utilization 12:21–26
79. Julián A, Jaseer EA, Garcés K, Fernández-Alvarez FJ, García-Orduña P, Lahoz FJ, Oro LA
(2016) Tuning the activity and selectivity of iridium-NSiN catalyzed CO 2 hydrosilylation
processes. Cat Sci Technol 6:4410–4417
80. Julián A, Guzmán J, Jaseer EA, Fernández-Alvarez FJ, Royo R, Polo V, García-Orduña P,
Lahoz FJ, Oro LA (2017) Mechanistic insights on the reduction of CO 2 to silylformates
catalyzed by Ir-NSiN species. Chem A Eur J 23:11898–11907
322
F. J. Fernández-Alvarez and L. A. Oro