3. Clark JH, Farmer TJ, Herrero-Davila L, Sherwood J (2016) Circular economy design considerations for research and process development in the chemical sciences. Green Chem
18:3914–3934
4. Grignard B, Gennen S, Jérôme C, Kleij AW, Detrembleur C (2019) Advances in the use of
CO 2 as a renewable feedstock for the synthesis of polymers. Chem Soc Rev 48:4466–4514
5. Martens JA, Bogaerts A, De Kimpe N, Jacobs PA, Marin GB, Rabaey K, Saeys M, Verhelst S
(2017) The chemical route to a carbon dioxide neutral world. ChemSusChem 10:1039–1055
6. Klankermayer J, Wesselbaum S, Beydoun K, Leitner W (2016) Selective catalytic synthesis
using the combination of carbon dioxide and hydrogen: catalytic chess at the Interface of
energy and chemistry. Angew Chem Int Ed 55:7296–7343
7. Liu Q, Wu L, Jackstell R, Beller M (2015) Using carbon dioxide as a building block in organic
synthesis. Nat Commun 6:5933
8. Das Neves Gomes C, Jacquet O, Villiers C, Thuéry P, Ephritikhine M, Cantat T (2012) A
diagonal approach to chemical recycling of carbon dioxide: organocatalytic transformation for
the reductive functionalization of CO 2 . Angew Chem Int Ed 51:187–190
9. Jessop PG, Joó F, Tai C-C (2004) Recent advances in the homogeneous hydrogenation of
carbon dioxide. Coord Chem Rev 248:2425–2442
10. Wang W-H, Himeda Y, Muckerman JT, Manbeck GF, Fujita E (2015) CO 2 hydrogenation to
formate and methanol as an alternative to photo- and electrochemical CO 2 reduction. Chem
Rev 115:12936–12973
11. Cokoja M, Bruckmeier C, Rieger B, Herrmann WA, Kühn FE (2011) Transformation of
carbon dioxide with homogeneous transition-metal catalysts: a molecular solution to a global
challenge? Angew Chem Int Ed 50:8510–8537
12. Peters M, Köhler B, Kuckshinrichs W, Leitner W, Markewitz P, Müller TE (2011) Chemical
technologies for exploiting and recycling carbon dioxide into the value chain. ChemSusChem
4:1216–1240
13. Aresta M, Dibenedetto A, Angelini A (2014) Catalysis for the valorization of exhaust carbon:
from CO 2 to chemicals, materials, and fuels. Technological use of CO 2 . Chem Rev
114:1709–1742
14. Goeppert A, Zhang H, Czaun M, May RB, Prakash GKS, Olah GA, Narayanan SR (2014)
Easily regenerable solid adsorbents based on polyamines for carbon dioxide capture from the
air. ChemSusChem 7:1386–1397
15. Sakakura T, Choi J-C, Yasuda H (2007) Transformation of carbon dioxide. Chem Rev
107:2365–2387
16. Centi G, Quadrelli EA, Perathoner S (2013) Catalysis for CO 2 conversion: a key technology
for rapid introduction of renewable energy in the value chain of chemical industries. Energ
Environ Sci 6:1711–1731
17. Ronda-Lloret M, Rothenberg G, Shiju NR (2019) A critical look at direct catalytic hydrogenation of carbon dioxide to olefins. ChemSusChem 12:3896–3914
18. Onishi N, Laurenzcy G, Beller M, Himeda Y (2018) Recent Progress for reversible homogeneous catalytic hydrogen storage in formic acid and in methanol. Coord Chem Rev
373:317–332
19. Jia J, Qian C, Dong Y, Li YF, Wang H, Ghoussoub M, Butler KT, Walsh A, Ozin GA (2017)
Heterogeneous catalytic hydrogenation of CO 2 by metal oxides: defect engineering –
perfecting imperfection. Chem Soc Rev 46:4631–4644
20. Prieto G (2017) Carbon dioxide hydrogenation into higher hydrocarbons and oxygenates:
thermodynamic and kinetic bounds and Progress with heterogeneous and homogeneous
catalysis. ChemSusChem 10:1056–1070
21. Wang W, Wang S, Ma X, Gong J (2011) Recent advances in catalytic hydrogenation of carbon
dioxide. Chem Soc Rev 40:3703–3727
22. Fernández-Alvarez FJ, Oro LA (2018) Homogeneous catalytic reduction of CO 2 with siliconhydrides, state of the art. ChemCatChem 10:4783–4796
Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon. . .
319
18:3914–3934
4. Grignard B, Gennen S, Jérôme C, Kleij AW, Detrembleur C (2019) Advances in the use of
CO 2 as a renewable feedstock for the synthesis of polymers. Chem Soc Rev 48:4466–4514
5. Martens JA, Bogaerts A, De Kimpe N, Jacobs PA, Marin GB, Rabaey K, Saeys M, Verhelst S
(2017) The chemical route to a carbon dioxide neutral world. ChemSusChem 10:1039–1055
6. Klankermayer J, Wesselbaum S, Beydoun K, Leitner W (2016) Selective catalytic synthesis
using the combination of carbon dioxide and hydrogen: catalytic chess at the Interface of
energy and chemistry. Angew Chem Int Ed 55:7296–7343
7. Liu Q, Wu L, Jackstell R, Beller M (2015) Using carbon dioxide as a building block in organic
synthesis. Nat Commun 6:5933
8. Das Neves Gomes C, Jacquet O, Villiers C, Thuéry P, Ephritikhine M, Cantat T (2012) A
diagonal approach to chemical recycling of carbon dioxide: organocatalytic transformation for
the reductive functionalization of CO 2 . Angew Chem Int Ed 51:187–190
9. Jessop PG, Joó F, Tai C-C (2004) Recent advances in the homogeneous hydrogenation of
carbon dioxide. Coord Chem Rev 248:2425–2442
10. Wang W-H, Himeda Y, Muckerman JT, Manbeck GF, Fujita E (2015) CO 2 hydrogenation to
formate and methanol as an alternative to photo- and electrochemical CO 2 reduction. Chem
Rev 115:12936–12973
11. Cokoja M, Bruckmeier C, Rieger B, Herrmann WA, Kühn FE (2011) Transformation of
carbon dioxide with homogeneous transition-metal catalysts: a molecular solution to a global
challenge? Angew Chem Int Ed 50:8510–8537
12. Peters M, Köhler B, Kuckshinrichs W, Leitner W, Markewitz P, Müller TE (2011) Chemical
technologies for exploiting and recycling carbon dioxide into the value chain. ChemSusChem
4:1216–1240
13. Aresta M, Dibenedetto A, Angelini A (2014) Catalysis for the valorization of exhaust carbon:
from CO 2 to chemicals, materials, and fuels. Technological use of CO 2 . Chem Rev
114:1709–1742
14. Goeppert A, Zhang H, Czaun M, May RB, Prakash GKS, Olah GA, Narayanan SR (2014)
Easily regenerable solid adsorbents based on polyamines for carbon dioxide capture from the
air. ChemSusChem 7:1386–1397
15. Sakakura T, Choi J-C, Yasuda H (2007) Transformation of carbon dioxide. Chem Rev
107:2365–2387
16. Centi G, Quadrelli EA, Perathoner S (2013) Catalysis for CO 2 conversion: a key technology
for rapid introduction of renewable energy in the value chain of chemical industries. Energ
Environ Sci 6:1711–1731
17. Ronda-Lloret M, Rothenberg G, Shiju NR (2019) A critical look at direct catalytic hydrogenation of carbon dioxide to olefins. ChemSusChem 12:3896–3914
18. Onishi N, Laurenzcy G, Beller M, Himeda Y (2018) Recent Progress for reversible homogeneous catalytic hydrogen storage in formic acid and in methanol. Coord Chem Rev
373:317–332
19. Jia J, Qian C, Dong Y, Li YF, Wang H, Ghoussoub M, Butler KT, Walsh A, Ozin GA (2017)
Heterogeneous catalytic hydrogenation of CO 2 by metal oxides: defect engineering –
perfecting imperfection. Chem Soc Rev 46:4631–4644
20. Prieto G (2017) Carbon dioxide hydrogenation into higher hydrocarbons and oxygenates:
thermodynamic and kinetic bounds and Progress with heterogeneous and homogeneous
catalysis. ChemSusChem 10:1056–1070
21. Wang W, Wang S, Ma X, Gong J (2011) Recent advances in catalytic hydrogenation of carbon
dioxide. Chem Soc Rev 40:3703–3727
22. Fernández-Alvarez FJ, Oro LA (2018) Homogeneous catalytic reduction of CO 2 with siliconhydrides, state of the art. ChemCatChem 10:4783–4796
Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon. . .
319