47. Gassner F, Leitner W (1993) Hydrogenation of carbon-dioxide to formic-acid using
water-soluble rhodium catalysts. J Chem Soc Chem Commun 1993:1465–1466
48. Jessop PG, Ikariya T, Noyori R (1995) Homogeneous hydrogenation of carbon-dioxide.
Chem Rev 95:259–272
49. Leitner W (1995) Carbon dioxide as a raw material: synthesis of formic acid and its
derivatives from CO 2 . Angew Chem 34:2207–2221
50. Munshi P, Main AD, Linehan JC, Tai CC, Jessop PG (2002) Hydrogenation of carbon
dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of
certain alcohols and amines. J Am Chem Soc 124:7963–7971
51. Jessop PG, Joó F, Tai CC (2004) Recent advances in the homogeneous hydrogenation of
carbon dioxide. Coord Chem Rev 248:2425–2442
52. Enthaler S (2008) Carbon dioxide—the hydrogen-storage material of the future?
Chemsuschem 1:801–804
53. Fukuzumi S (2008) Bioinspired energy conversion systems for hydrogen production and
storage. Eur J Inorg Chem 2008:1351–1362
54. Federsel C, Jackstell R, Boddien A, Laurenczy G, Beller M (2010) Ruthenium-catalyzed
hydrogenation of bicarbonate in water. Chemsuschem 3:1048–1050
55. Loges B, Boddien A, Gartner F, Junge H, Beller M (2010) Catalytic generation of hydrogen
from formic acid and its derivatives: useful hydrogen storage materials. Top Catal 53:902–
914
56. Himeda Y, Miyazawa S, Hirose T (2011) Interconversion between formic acid and H 2 /CO 2
using rhodium and ruthenium catalysts for CO 2 fixation and H 2 storage. Chemsuschem
4:487–493
57. Langer R, Diskin-Posner Y, Leitus G, Shimon LJW, Ben-David Y, Milstein D (2011)
Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex
exhibiting noble metal activity. Angew Chem 50:9948–9952
58. Schmeier TJ, Dobereiner GE, Crabtree RH, Hazari N (2011) Secondary coordination sphere
interactions facilitate the insertion step in an iridium(iii) CO 2 reduction catalyst. J Am Chem
Soc 133:9274–9277
59. Wang W, Wang S, Ma X, Gong J (2011) Recent advances in catalytic hydrogenation of
carbon dioxide. Chem Soc Rev 40:3703–3727
60. Hull JF, Himeda Y, Wang W-H, Hashiguchi B, Periana R, Szalda DJ, Muckerman JT,
Fujita E (2012) Reversible hydrogen storage using CO 2 and a proton-switchable iridium
catalyst in aqueous media under mild temperatures and pressures. Nat Chem 4:383–388
61. Maenaka Y, Suenobu T, Fukuzumi S (2012) Catalytic interconversion between hydrogen
and formic acid at ambient temperature and pressure. Energy Environ Sci 5:7360–7367
62. Yadav M, Xu Q (2012) Liquid-phase chemical hydrogen storage materials Energy. Environ
Sci 5:9698–9725
63. Wesselbaum S, Hintermair U, Leitner W (2012) Continuous-flow hydrogenation of carbon
dioxide to pure formic acid using an integrated scCO 2 process with immobilized catalyst and
base. Angew Chem 51:8585–8588
64. Huff CA, Sanford MS (2013) Catalytic CO 2 hydrogenation to formate by a ruthenium pincer
complex. ACS Catal 3:2412–2416
65. Jeletic MS, Mock MT, Appel AM, Linehan JCA (2013) Cobalt-based catalyst for the
hydrogenation of CO 2 under ambient conditions. J Am Chem Soc 135:11533–11536
66. Muller K, Sun Y, Thiel WR (2013) Ruthenium(II) phosphite complexes as catalysts for the
hydrogenation of carbon dioxide. ChemCatChem 5:1340–1343
67. Wang W-H, Muckerman JT, Fujita E, Himeda Y (2013) Mechanistic insight through factors
controlling effective hydrogenation of CO 2 catalyzed by bioinspired proton-responsive
iridium(iii) complexes. ACS Catal 3:856–860
68. Bays JT, Priyadarshani N, Jeletic MS, Hulley EB, Miller DL, Linehan JC, Shaw WJ (2014)
The influence of the second and outer coordination spheres on Rh(diphosphine) 2 CO 2
hydrogenation catalysts. ACS Catal 4:3663–3670
Carbon Dioxide Utilisation—The Formate Route
69
water-soluble rhodium catalysts. J Chem Soc Chem Commun 1993:1465–1466
48. Jessop PG, Ikariya T, Noyori R (1995) Homogeneous hydrogenation of carbon-dioxide.
Chem Rev 95:259–272
49. Leitner W (1995) Carbon dioxide as a raw material: synthesis of formic acid and its
derivatives from CO 2 . Angew Chem 34:2207–2221
50. Munshi P, Main AD, Linehan JC, Tai CC, Jessop PG (2002) Hydrogenation of carbon
dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of
certain alcohols and amines. J Am Chem Soc 124:7963–7971
51. Jessop PG, Joó F, Tai CC (2004) Recent advances in the homogeneous hydrogenation of
carbon dioxide. Coord Chem Rev 248:2425–2442
52. Enthaler S (2008) Carbon dioxide—the hydrogen-storage material of the future?
Chemsuschem 1:801–804
53. Fukuzumi S (2008) Bioinspired energy conversion systems for hydrogen production and
storage. Eur J Inorg Chem 2008:1351–1362
54. Federsel C, Jackstell R, Boddien A, Laurenczy G, Beller M (2010) Ruthenium-catalyzed
hydrogenation of bicarbonate in water. Chemsuschem 3:1048–1050
55. Loges B, Boddien A, Gartner F, Junge H, Beller M (2010) Catalytic generation of hydrogen
from formic acid and its derivatives: useful hydrogen storage materials. Top Catal 53:902–
914
56. Himeda Y, Miyazawa S, Hirose T (2011) Interconversion between formic acid and H 2 /CO 2
using rhodium and ruthenium catalysts for CO 2 fixation and H 2 storage. Chemsuschem
4:487–493
57. Langer R, Diskin-Posner Y, Leitus G, Shimon LJW, Ben-David Y, Milstein D (2011)
Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex
exhibiting noble metal activity. Angew Chem 50:9948–9952
58. Schmeier TJ, Dobereiner GE, Crabtree RH, Hazari N (2011) Secondary coordination sphere
interactions facilitate the insertion step in an iridium(iii) CO 2 reduction catalyst. J Am Chem
Soc 133:9274–9277
59. Wang W, Wang S, Ma X, Gong J (2011) Recent advances in catalytic hydrogenation of
carbon dioxide. Chem Soc Rev 40:3703–3727
60. Hull JF, Himeda Y, Wang W-H, Hashiguchi B, Periana R, Szalda DJ, Muckerman JT,
Fujita E (2012) Reversible hydrogen storage using CO 2 and a proton-switchable iridium
catalyst in aqueous media under mild temperatures and pressures. Nat Chem 4:383–388
61. Maenaka Y, Suenobu T, Fukuzumi S (2012) Catalytic interconversion between hydrogen
and formic acid at ambient temperature and pressure. Energy Environ Sci 5:7360–7367
62. Yadav M, Xu Q (2012) Liquid-phase chemical hydrogen storage materials Energy. Environ
Sci 5:9698–9725
63. Wesselbaum S, Hintermair U, Leitner W (2012) Continuous-flow hydrogenation of carbon
dioxide to pure formic acid using an integrated scCO 2 process with immobilized catalyst and
base. Angew Chem 51:8585–8588
64. Huff CA, Sanford MS (2013) Catalytic CO 2 hydrogenation to formate by a ruthenium pincer
complex. ACS Catal 3:2412–2416
65. Jeletic MS, Mock MT, Appel AM, Linehan JCA (2013) Cobalt-based catalyst for the
hydrogenation of CO 2 under ambient conditions. J Am Chem Soc 135:11533–11536
66. Muller K, Sun Y, Thiel WR (2013) Ruthenium(II) phosphite complexes as catalysts for the
hydrogenation of carbon dioxide. ChemCatChem 5:1340–1343
67. Wang W-H, Muckerman JT, Fujita E, Himeda Y (2013) Mechanistic insight through factors
controlling effective hydrogenation of CO 2 catalyzed by bioinspired proton-responsive
iridium(iii) complexes. ACS Catal 3:856–860
68. Bays JT, Priyadarshani N, Jeletic MS, Hulley EB, Miller DL, Linehan JC, Shaw WJ (2014)
The influence of the second and outer coordination spheres on Rh(diphosphine) 2 CO 2
hydrogenation catalysts. ACS Catal 4:3663–3670
Carbon Dioxide Utilisation—The Formate Route
69