(e).
CONHC 18 H 37
N
N
N
SO 3 H
12. The following molecules are identical except
for the structure of dipolar headgroups. Place
the molecules in order of increasing headgroup dipole moment and discuss the differences in the way these molecules aggregate
into a monolayer at the air–water interface, if
any difference exists.
O (CH 2 ) 10
SO 3
–
O (CH 2 ) 10
SO 3
–
O (CH 2 ) 10
SO 3
–
N
C
N
N N
N
NC
N
O
H 3 C
O 2 N
References and recommended reading
Israelachvili, J. Intermolecular and Surface Forces, 3rd ed.
2011, Academic Press, San Diego, pp. 31–139. This is a
classic textbook on the subject, but is probably for the
more advanced student. Chapters 3 through 8 are particularly relevant to this text.
Kuhn, H.Kuhn, C. Chromophore coupling effects. In JAggregation, Kobayashi, T., Ed., 1996, World Scientific,
Singapore, 1–140. This is an excellent book for those
interested in H- and J-aggregation.
Lowe, J. P. Quantum Chemistry, 2nd ed. 1993, Academic
Press, San Diego. This book is for the advanced student.
Chapter 2 contains some excellent applications of the
particle-in-a-box model.
Onsager, L. Electric moments of molecules in liquids.
Journal of the American Chemical Society. 1936, 58: 1486–
1493. A detailed derivation of the Onsager model and
discussion of its assumptions is found in this 1936 paper.
Pavia, D., Lampman, G., and Kriz, G. Introduction to
Spectroscopy, 2nd ed. 1996, Saunders College Publishing,
Orlando, FL. The chapter on electronic spectroscopy
provides some useful background on MO diagrams of
organic molecules. This book is an excellent read for
those interested in the kinds of electronic excitations
discussed in Section 5.4.2.
Purcell, E. MMorin, D. J. 2013, Electricity and Magnetism,
3rd ed. Cambridge University Press, Cambridge, UK. This
is an excellent general introduction to electrostatics and
dynamics.
Reichardt, C. Solvatochromic dyes as solvent polarity
indicators. Chemical Reviews. 1994, 94: 2319–2358. This
paper provides a good review of solvatochromism,
including common dyes and their solvatochromic shifts.
CHAPTER 5: Intermolecular Interactions and Self-Assembly
180
CONHC 18 H 37
N
N
N
SO 3 H
12. The following molecules are identical except
for the structure of dipolar headgroups. Place
the molecules in order of increasing headgroup dipole moment and discuss the differences in the way these molecules aggregate
into a monolayer at the air–water interface, if
any difference exists.
O (CH 2 ) 10
SO 3
–
O (CH 2 ) 10
SO 3
–
O (CH 2 ) 10
SO 3
–
N
C
N
N N
N
NC
N
O
H 3 C
O 2 N
References and recommended reading
Israelachvili, J. Intermolecular and Surface Forces, 3rd ed.
2011, Academic Press, San Diego, pp. 31–139. This is a
classic textbook on the subject, but is probably for the
more advanced student. Chapters 3 through 8 are particularly relevant to this text.
Kuhn, H.Kuhn, C. Chromophore coupling effects. In JAggregation, Kobayashi, T., Ed., 1996, World Scientific,
Singapore, 1–140. This is an excellent book for those
interested in H- and J-aggregation.
Lowe, J. P. Quantum Chemistry, 2nd ed. 1993, Academic
Press, San Diego. This book is for the advanced student.
Chapter 2 contains some excellent applications of the
particle-in-a-box model.
Onsager, L. Electric moments of molecules in liquids.
Journal of the American Chemical Society. 1936, 58: 1486–
1493. A detailed derivation of the Onsager model and
discussion of its assumptions is found in this 1936 paper.
Pavia, D., Lampman, G., and Kriz, G. Introduction to
Spectroscopy, 2nd ed. 1996, Saunders College Publishing,
Orlando, FL. The chapter on electronic spectroscopy
provides some useful background on MO diagrams of
organic molecules. This book is an excellent read for
those interested in the kinds of electronic excitations
discussed in Section 5.4.2.
Purcell, E. MMorin, D. J. 2013, Electricity and Magnetism,
3rd ed. Cambridge University Press, Cambridge, UK. This
is an excellent general introduction to electrostatics and
dynamics.
Reichardt, C. Solvatochromic dyes as solvent polarity
indicators. Chemical Reviews. 1994, 94: 2319–2358. This
paper provides a good review of solvatochromism,
including common dyes and their solvatochromic shifts.
CHAPTER 5: Intermolecular Interactions and Self-Assembly
180