52
B. Schmidt
48. Yadav JS, Avuluri S, Kattela SS, Das S (2013) First total synthesis of pinolide. Eur J Org
Chem 6967
49. Liu D, Kozmin SA (2002) Synthesis of (−)-pinolidoxin: divergent synthetic strategy
exploiting a common silacyclic precursor. Org Lett 4:3005
50. de Napoli L, Messere A, Palomba D, Piccialli V, Evidente A, Piccialli G (2000) Studies toward
the synthesis of pinolidoxin, a phytotoxic nonenolide from the fungus Ascochyta pinodes.
Determination of the configuration at the C-7, C-8, and C-9 chiral centers and stereoselective
synthesis of the C-6-C-18 fragment. J Org Chem 65:3432
51. Mohapatra DK, Ramesh DK, Giardello MA, Chorghade MS, Gurjar MK, Grubbs RH (2007)
Protecting group directed ring-closing metathesis (RCM): the first total synthesis of an antimalarial nonenolide. Tetrahedron Lett 48:2621
52. Meshram HM, Kumar DA, Ramesh P (2010) Total synthesis of nonenolide. Helv Chim Acta
93:1422
53. Sabitha G, Padmaja P, Sudhakar K, Yadav JS (2009) Total synthesis of the Z-isomers of
nonenolide and desmethyl nonenolide. Tetrahedron Asymmetry 20:1330
54. Sudina PR, Motati DR, Seema A (2018) Stereocontrolled total synthesis of nonenolide. J Nat
Prod 81:1399
55. Chatterjee S, Guchhait S, Goswami RK (2014) Stereoselective total synthesis of cytospolide
P. J Org Chem 79:7689
56. Chatterjee S, Kuilya TK, Goswami RK (2018) Studies directed toward the stereoselective
synthesis of cytospolide E. ACS Omega 3:1041
57. ˙
Zukowska K, Grela K (2014) Cross metathesis. In: Molander GA, Knochel P (eds)
Comprehensive organic synthesis II, vol 5, 2nd edn. Elsevier, Amsterdam, p 1257
58. Chatterjee AK, Choi T-L, Sanders DP, Grubbs RH (2003) A general model for selectivity in
olefin cross metathesis. J Am Chem Soc 125:11360
59. Vadhadiya PM, Rout JK, Ramana CV (2015) Studies toward the total synthesis of cytospolide
E. Tetrahedron 71:9088
60. Rej RK, Jana A, Nanda S (2014) Asymmetric synthesis of naturally occurring nonenolide
xyolide through cross metathesis and macrolactonization reaction. Tetrahedron 70:2634
61. Götz K, Liermann JC, Thines E, Anke H, Opatz T (2010) Structure elucidation of hypocreolide
A by enantioselective total synthesis. Org Biomol Chem 8:2123
62. Bisterfeld C, Holec C, Böse D, Marx P, Pietruszka J (2017) Chemoenzymatic total synthesis
of the proposed structures of putaminoxins B and D. J Nat Prod 80:1563
63. Dickmann D, Diekmann M, Holec C, Pietruszka J (2019) The first chemoenzymatic
total synthesis of the phytotoxic nonenolide putaminoxin and its (5S,6E,9S)-diastereomer.
Tetrahedron 75:689
64. Shimada A, Kusano M, Matsumoto K, Nishibe M, Kawano T, Kimura Y (2002) Pollen growth
regulator, fusanolide A, and a related metabolite from Fusarium sp. Z Naturforsch B 57b:239
65. Schmidt B, Kunz O (2012) One-flask tethered ring closing metathesis–electrocyclic ring
opening for the highly stereoselective synthesis of conjugated Z/E-dienes. Eur J Org Chem
1008
66. Schmidt B, Kunz O (2013) Bidirectional cross metathesis and ring-closing metathesis/ring
opening of a C 2 -symmetric building block: a strategy for the synthesis of decanolide natural
products. Beilstein J Org Chem 9:2544
67. Trisuwan K, Rukachaisirikul V, Phongpaichit S, Preedanon S, Sakayaroj J (2011) Modiolide
and pyrone derivatives from the sea fan-derived fungus Curvularia sp. PSU-F22. Arch Pharm
Res 34:709
68. Tsuda M, Mugishima T, Komatsu K, Sone T, Tanaka M, Mikami Y, Kobayashi J (2003)
Modiolides A and B, two new 10-membered macrolides from a marine-derived fungus. J Nat
Prod 66:412
69. Capon RJ (2020) Extracting value: mechanistic insights into the formation of natural product
artifacts—case studies in marine natural products. Nat Prod Rep 37:55
70. Venditti A (2020) What is and what should never be: artifacts, improbable phytochemicals,
contaminants and natural products. Nat Prod Res 34:1014
B. Schmidt
48. Yadav JS, Avuluri S, Kattela SS, Das S (2013) First total synthesis of pinolide. Eur J Org
Chem 6967
49. Liu D, Kozmin SA (2002) Synthesis of (−)-pinolidoxin: divergent synthetic strategy
exploiting a common silacyclic precursor. Org Lett 4:3005
50. de Napoli L, Messere A, Palomba D, Piccialli V, Evidente A, Piccialli G (2000) Studies toward
the synthesis of pinolidoxin, a phytotoxic nonenolide from the fungus Ascochyta pinodes.
Determination of the configuration at the C-7, C-8, and C-9 chiral centers and stereoselective
synthesis of the C-6-C-18 fragment. J Org Chem 65:3432
51. Mohapatra DK, Ramesh DK, Giardello MA, Chorghade MS, Gurjar MK, Grubbs RH (2007)
Protecting group directed ring-closing metathesis (RCM): the first total synthesis of an antimalarial nonenolide. Tetrahedron Lett 48:2621
52. Meshram HM, Kumar DA, Ramesh P (2010) Total synthesis of nonenolide. Helv Chim Acta
93:1422
53. Sabitha G, Padmaja P, Sudhakar K, Yadav JS (2009) Total synthesis of the Z-isomers of
nonenolide and desmethyl nonenolide. Tetrahedron Asymmetry 20:1330
54. Sudina PR, Motati DR, Seema A (2018) Stereocontrolled total synthesis of nonenolide. J Nat
Prod 81:1399
55. Chatterjee S, Guchhait S, Goswami RK (2014) Stereoselective total synthesis of cytospolide
P. J Org Chem 79:7689
56. Chatterjee S, Kuilya TK, Goswami RK (2018) Studies directed toward the stereoselective
synthesis of cytospolide E. ACS Omega 3:1041
57. ˙
Zukowska K, Grela K (2014) Cross metathesis. In: Molander GA, Knochel P (eds)
Comprehensive organic synthesis II, vol 5, 2nd edn. Elsevier, Amsterdam, p 1257
58. Chatterjee AK, Choi T-L, Sanders DP, Grubbs RH (2003) A general model for selectivity in
olefin cross metathesis. J Am Chem Soc 125:11360
59. Vadhadiya PM, Rout JK, Ramana CV (2015) Studies toward the total synthesis of cytospolide
E. Tetrahedron 71:9088
60. Rej RK, Jana A, Nanda S (2014) Asymmetric synthesis of naturally occurring nonenolide
xyolide through cross metathesis and macrolactonization reaction. Tetrahedron 70:2634
61. Götz K, Liermann JC, Thines E, Anke H, Opatz T (2010) Structure elucidation of hypocreolide
A by enantioselective total synthesis. Org Biomol Chem 8:2123
62. Bisterfeld C, Holec C, Böse D, Marx P, Pietruszka J (2017) Chemoenzymatic total synthesis
of the proposed structures of putaminoxins B and D. J Nat Prod 80:1563
63. Dickmann D, Diekmann M, Holec C, Pietruszka J (2019) The first chemoenzymatic
total synthesis of the phytotoxic nonenolide putaminoxin and its (5S,6E,9S)-diastereomer.
Tetrahedron 75:689
64. Shimada A, Kusano M, Matsumoto K, Nishibe M, Kawano T, Kimura Y (2002) Pollen growth
regulator, fusanolide A, and a related metabolite from Fusarium sp. Z Naturforsch B 57b:239
65. Schmidt B, Kunz O (2012) One-flask tethered ring closing metathesis–electrocyclic ring
opening for the highly stereoselective synthesis of conjugated Z/E-dienes. Eur J Org Chem
1008
66. Schmidt B, Kunz O (2013) Bidirectional cross metathesis and ring-closing metathesis/ring
opening of a C 2 -symmetric building block: a strategy for the synthesis of decanolide natural
products. Beilstein J Org Chem 9:2544
67. Trisuwan K, Rukachaisirikul V, Phongpaichit S, Preedanon S, Sakayaroj J (2011) Modiolide
and pyrone derivatives from the sea fan-derived fungus Curvularia sp. PSU-F22. Arch Pharm
Res 34:709
68. Tsuda M, Mugishima T, Komatsu K, Sone T, Tanaka M, Mikami Y, Kobayashi J (2003)
Modiolides A and B, two new 10-membered macrolides from a marine-derived fungus. J Nat
Prod 66:412
69. Capon RJ (2020) Extracting value: mechanistic insights into the formation of natural product
artifacts—case studies in marine natural products. Nat Prod Rep 37:55
70. Venditti A (2020) What is and what should never be: artifacts, improbable phytochemicals,
contaminants and natural products. Nat Prod Res 34:1014