30
B. Schmidt
Table 1
(continued)
Entry
Stagonolide
Status of structure elucidation after
total synthesis
Confirmed or revised structure
based on synthesis
Source of chirality in total syntheses Ref.
31
Stagonolide G (99)
Originally assigned structure 90
was
revised to 99
d-Glucose (published structure
confirmed)
[120]
32
Asymmetric allylboration (revision
to 99
proposed)
[99]
33
d-Glyceraldehyde; asymmetric
dihydroxylation (published structure
confirmed)
[121]
34
d-Glyceraldehyde (revised structure
99
confirmed)
[122]
35
Co-salen cat. epoxide hydrolytic
resolution; asymmetric
dihydroxylation (revised structure 99
confirmed)
[123]
36
Stagonolide H (91)
No synthesis reported
–
–
–
37
Stagonolide I (92)
No synthesis reported
–
–
–
38
Stagonolide J (93)
No synthesis reported
–
–
–
39
Stagonolide K (94)
Absolute configuration assigned
based on previous synthesis
d-Ribose
[124]