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T. Rakitskaya et al.
30. Wang C, Ma J, Liu F et al (2015) The effects of Mn 2+ precursors on the structure and ozone
decomposition activity of cryptomelane-type manganese oxide (OMS-2) catalysts. J Phys
Chem C 119:23119–23126. https://doi.org/10.1021/acs.jpcc.5b08095
31. Ma J, Wang C, He H (2017) Transition metal doped cryptomelane-type manganese oxidecatalysts for ozone decomposition. Appl Catal B Environ 201:503–510. https://doi.org/10.1016/
j.apcatb.2016.08.050
32. Liu Y, Zhang P, Zhan J et al (2018) Heat treatment of MnCO 3 : an easy way to obtain efficient
and stable MnO 2 for humid O 3 decomposition. Appl Surf Sci 463:374–385. https://doi.org/10.
1016/j.apsusc.2018.08.226
33. Rakitskaya TL, Khitrich VF, Raskola LA et al (2004) Razlozheniye mikrokontsentratsiy ozona
melkodispersnym MnO 2 -katalizatorom. Visn. Odes’k. nats. un-tu. 9:117–124 (Rakitskaya TL,
Khitrich VF, Raskola LA et al (2004) Decomposition of ozone microconcentrations by finedispersed MnO 2 catalyst. Herald ONU. Chemistry. 9:117–124)
34. Zheng H, Feng C, Kim SJ et al (2013) Synthesis and electrochemical properties of KMn 8 O 16
nanorods for Lithium ion batteries. Electrochim Acta 88:225–230. https://doi.org/10.1016/j.
electacta.2012.09.119
35. DeGuzman RN, Shen YF, Neth EJ et al (1994) Synthesis and characterization of octahedral
molecular sieves (OMS-2) having the hollandite structure. Chem Mater 6:815−821. https://
doi.org/10.1021/cm00042a019
36. Sui N, Duan Y, Jiao X et al (2009) Large-scale preparation and catalytic properties of onedimensional α/β-MnO 2 nanostructures. J Phys Chem 113:8560−8565. https://doi.org/10.1021/
jp810452k
37. Gregg SJ, Sing KSW (1982) Adsorption, surface area, and porosity. Academic Press, London,
New York. (ISBN: 0-12-300956-1)
38. Kolta GA, Kerim FMA, Azim AAA (1971) Infrared absorption spectra of some manganese
dioxide modifications and their thermal products. Z Anorg Allg Chem 384:260–266. https://
doi.org/10.1002/zaac.19713840311
39. Julien CM, Massot M, Poinsignon C (2004) Lattice vibrations of manganese oxides. Part I.
Periodic structures. Spectrochim Acta Part A 60:689–700. https://doi.org/10.1016/S1386-142
5(03)00279-8
40. Yang R, Wang Z, Dai L et al (2005) Synthesis and characterization of single-crystalline
nanorods of α-MnO 2 and γ-MnOOH. Mater Chem Phys 93:149–153. https://doi.org/10.1016/
j.matchemphys.2005.03.006
41. Tian H, He J, Zhang X et al (2011) Facile synthesis of porous manganese oxide K-OMS-2
materials and their catalytic activity for formaldehyde oxidation. Micropor Mesopor Mater
138:118–122. https://doi.org/10.1016/j.micromeso.2010.09.022
42. Li Z, Xu J (2016) Facile hydrothermal synthesis of flowerlike MnO 2 constructed by ultrathin
nanosheets for supercapacitors. Biointerface Res Appl Chem 6:1070–1074
43. Chen Y, Hong Y, Ma Y et al (2010) Synthesis and formation mechanism of urchin-like
nano/micro-hybrid α-MnO 2 . J Alloys Compd 490:331–335. https://doi.org/10.1016/j.jallcom.
2009.10.004
44. Musil M, Choi B, Tsutsumi A (2015) Morphology and electrochemical properties of α-, β-, γ-,
and δ-MnO 2 synthesized by redox method. J Electrochem Soc 162:A2058–A2065. https://iop
science.iop.org/article/10.1149/2.0201510jes
45. Wang X, Li Y (2003) Synthesis and formation mechanism of manganese dioxide
nanowires/nanorods. Chem Eur J 9:300–306. https://doi.org/10.1002/chem.200390024
46. Li D, Shen G, Tang W et al (2014) Large-scale synthesis of hierarchical MnO 2 for benzene
catalytic oxidation. Particuology 14:71–75. https://doi.org/10.1016/j.partic.2013.06.010
47. Santos VP, Soares OSGP, Bakker JJW et al (2012) Structural and chemical disorder of cryptomelane promoted by alkali doping: Influence on catalytic properties. J Catal 293:165–174.
https://doi.org/10.1016/j.jcat.2012.06.020
48. Jaroniec M, Kruk M, Olivier JP (1999) Standard nitrogen adsorption data for characterization
of nanoporous silicas. Langmuir 15:5410–5413. https://doi.org/10.1021/la990136e
T. Rakitskaya et al.
30. Wang C, Ma J, Liu F et al (2015) The effects of Mn 2+ precursors on the structure and ozone
decomposition activity of cryptomelane-type manganese oxide (OMS-2) catalysts. J Phys
Chem C 119:23119–23126. https://doi.org/10.1021/acs.jpcc.5b08095
31. Ma J, Wang C, He H (2017) Transition metal doped cryptomelane-type manganese oxidecatalysts for ozone decomposition. Appl Catal B Environ 201:503–510. https://doi.org/10.1016/
j.apcatb.2016.08.050
32. Liu Y, Zhang P, Zhan J et al (2018) Heat treatment of MnCO 3 : an easy way to obtain efficient
and stable MnO 2 for humid O 3 decomposition. Appl Surf Sci 463:374–385. https://doi.org/10.
1016/j.apsusc.2018.08.226
33. Rakitskaya TL, Khitrich VF, Raskola LA et al (2004) Razlozheniye mikrokontsentratsiy ozona
melkodispersnym MnO 2 -katalizatorom. Visn. Odes’k. nats. un-tu. 9:117–124 (Rakitskaya TL,
Khitrich VF, Raskola LA et al (2004) Decomposition of ozone microconcentrations by finedispersed MnO 2 catalyst. Herald ONU. Chemistry. 9:117–124)
34. Zheng H, Feng C, Kim SJ et al (2013) Synthesis and electrochemical properties of KMn 8 O 16
nanorods for Lithium ion batteries. Electrochim Acta 88:225–230. https://doi.org/10.1016/j.
electacta.2012.09.119
35. DeGuzman RN, Shen YF, Neth EJ et al (1994) Synthesis and characterization of octahedral
molecular sieves (OMS-2) having the hollandite structure. Chem Mater 6:815−821. https://
doi.org/10.1021/cm00042a019
36. Sui N, Duan Y, Jiao X et al (2009) Large-scale preparation and catalytic properties of onedimensional α/β-MnO 2 nanostructures. J Phys Chem 113:8560−8565. https://doi.org/10.1021/
jp810452k
37. Gregg SJ, Sing KSW (1982) Adsorption, surface area, and porosity. Academic Press, London,
New York. (ISBN: 0-12-300956-1)
38. Kolta GA, Kerim FMA, Azim AAA (1971) Infrared absorption spectra of some manganese
dioxide modifications and their thermal products. Z Anorg Allg Chem 384:260–266. https://
doi.org/10.1002/zaac.19713840311
39. Julien CM, Massot M, Poinsignon C (2004) Lattice vibrations of manganese oxides. Part I.
Periodic structures. Spectrochim Acta Part A 60:689–700. https://doi.org/10.1016/S1386-142
5(03)00279-8
40. Yang R, Wang Z, Dai L et al (2005) Synthesis and characterization of single-crystalline
nanorods of α-MnO 2 and γ-MnOOH. Mater Chem Phys 93:149–153. https://doi.org/10.1016/
j.matchemphys.2005.03.006
41. Tian H, He J, Zhang X et al (2011) Facile synthesis of porous manganese oxide K-OMS-2
materials and their catalytic activity for formaldehyde oxidation. Micropor Mesopor Mater
138:118–122. https://doi.org/10.1016/j.micromeso.2010.09.022
42. Li Z, Xu J (2016) Facile hydrothermal synthesis of flowerlike MnO 2 constructed by ultrathin
nanosheets for supercapacitors. Biointerface Res Appl Chem 6:1070–1074
43. Chen Y, Hong Y, Ma Y et al (2010) Synthesis and formation mechanism of urchin-like
nano/micro-hybrid α-MnO 2 . J Alloys Compd 490:331–335. https://doi.org/10.1016/j.jallcom.
2009.10.004
44. Musil M, Choi B, Tsutsumi A (2015) Morphology and electrochemical properties of α-, β-, γ-,
and δ-MnO 2 synthesized by redox method. J Electrochem Soc 162:A2058–A2065. https://iop
science.iop.org/article/10.1149/2.0201510jes
45. Wang X, Li Y (2003) Synthesis and formation mechanism of manganese dioxide
nanowires/nanorods. Chem Eur J 9:300–306. https://doi.org/10.1002/chem.200390024
46. Li D, Shen G, Tang W et al (2014) Large-scale synthesis of hierarchical MnO 2 for benzene
catalytic oxidation. Particuology 14:71–75. https://doi.org/10.1016/j.partic.2013.06.010
47. Santos VP, Soares OSGP, Bakker JJW et al (2012) Structural and chemical disorder of cryptomelane promoted by alkali doping: Influence on catalytic properties. J Catal 293:165–174.
https://doi.org/10.1016/j.jcat.2012.06.020
48. Jaroniec M, Kruk M, Olivier JP (1999) Standard nitrogen adsorption data for characterization
of nanoporous silicas. Langmuir 15:5410–5413. https://doi.org/10.1021/la990136e