Structural, Morphological, and Catalytic Properties …
75
11. Li X, Ma J, Yang L et al (2018) Oxygen vacancies induced by transition metal doping in
γ-MnO 2 for highly efficient ozone decomposition. Environ Sci Technol 52:12685−12696.
https://www.ncbi.nlm.nih.gov/pubmed/30346750
12. Gopi T, Swetha G, Shekar SC et al (2017) Catalytic decomposition of ozone on nanostructured
potassium and proton containing δ-MnO 2 catalysts. Catal Commun 92:51–55. https://doi.org/
10.1016/j.catcom.2017.01.002
13. Liu Y, Yang W, Zhang P et al (2018) Nitric acid-treated birnessite-type MnO 2 : an efficient and
hydrophobic material for humid ozone decomposition. Appl Surf Sci 442:640–649. https://doi.
org/10.1016/j.apsusc.2018.02.204
14. Zhang J, Li Y, Wang L et al (2015) Catalytic oxidation of formaldehyde over manganese oxides
with different crystal structures. Catal Sci Technol 5:2305–2313. https://doi.org/10.1039/c4c
y01461h
15. Jia J, Zhang P, Chen L (2016) The effect of morphology of α-MnO 2 on catalytic decomposition
of gaseous ozone. Catal Sci Technol 6:5841–5847. https://doi.org/10.1039/c6cy00301j
16. Suib SL (2008) Structure, porosity, and redox in porous manganese oxide octahedral layer and
molecular sieve materials. J Mater Chem 18:1623–1631. https://doi.org/10.1039/b714966m
17. Tian H, He J, Liu L et al (2013) Effects of textural parameters and noble metal loading on
the catalytic activity of cryptomelane-type manganese oxides for formaldehyde oxidation.
Ceramics Internsh 39:315–321. https://doi.org/10.1016/j.ceramint.2012.06.027
18. Dhandapani B, Oyama ST (1997) Gas phase ozone decomposition catalysts. Appl Catal B
Environ 11:129–166. https://doi.org/10.1016/S0926-3373(96)00044-6
19. Zhu G, Zhu J, Jiang W et al (2017) Surface oxygen vacancy induced α-MnO 2 nanofiber for
highly efficient ozone elimination. Appl Catal B Environ 209:729−737. http://dx.doi.org/doi:
10.1016/j.apcatb.2017.02.068
20. Zhu G, Zhu J, Li W (2018) Tuning the K + concentration in the tunnels of α-MnO 2 to increase
the content of oxygen vacancy for ozone elimination. Environ Sci Technol 52:8684–8692.
https://doi.org/10.1021/acs.est.8b01594
21. Spasova I, Nikolov P, Mehandjiev D (2007) Ozone decomposition over alumina-supported
copper, manganese and copper-manganese catalysts. Ozone Sci Eng 29:41−45. http://dx.doi.
org/10.1080/01919510601111665
22. Liu Y, Zhang P (2017) Removing surface hydroxyl groups of Ce-modified MnO 2 to significantly
improve its stability for gaseous ozone decomposition. J Phys Chem C 121:23488–23497.
https://doi.org/10.1021/acs.jpcc.7b07931
23. Yang Y, Jia J, Liu Y et al (2018) The effect of tungsten doping on the catalytic activity of
α-MnO2 nanomaterial for ozone decomposition under humid condition. Appl Catal A Gen
562:132–141. https://doi.org/10.1016/j.apcata.2018.06.006
24. Luo J, Zhang Q, Garcia-Martinez J et al (2008) Adsorptive and acidic properties, reversible
lattice oxygen evolution, and catalytic mechanism of cryptomelane-type manganese oxides as
oxidation catalysts. J Am Chem Soc 130:3198–3207. https://doi.org/10.1021/ja077706e
25. Özacar M, Poyraz AS, Genuino HC et al (2013) Influence of silver on the catalytic properties
of the cryptomelane and Ag-hollandite types manganese oxides OMS-2 in the low-temperature
CO oxidation. Appl Catal A Gen 462–463:64–74. https://doi.org/10.1016/j.apcata.2013.04.027
26. Jia J, Yang W, Zhang P et al (2017) Facile synthesis of Fe-modified manganese oxide with
high content of oxygen vacancies for efficient airborne ozone destruction. Appl Catal A Gen
546:79−86. http://dx.doi.org/doi:10.1016/j.apcata.2017.08.013
27. Jiang C, Zhang P, Zhang B (2013) Facile synthesis of activated carbon-supported porous
manganese oxide via in situ reduction of permanganate for ozone decomposition. Ozone Sci
Eng 35:308–315. https://doi.org/10.1080/01919512.2013.795854
28. Rao Y, Zeng D, Cao X et al (2019) Synthesis of doped MnO x /diatomite composites for
catalyzing ozone decomposition. Ceramics Internsh 45:6966–6971. https://doi.org/10.1016/
j.ceramint.2018.12.195
29. Rakitskaya T, Truba A, Dzhyga G et al (2018) Water vapor adsorption by some manganese
oxide forms. Colloids Interfaces 2:61. https://doi.org/10.3390/colloids2040061
75
11. Li X, Ma J, Yang L et al (2018) Oxygen vacancies induced by transition metal doping in
γ-MnO 2 for highly efficient ozone decomposition. Environ Sci Technol 52:12685−12696.
https://www.ncbi.nlm.nih.gov/pubmed/30346750
12. Gopi T, Swetha G, Shekar SC et al (2017) Catalytic decomposition of ozone on nanostructured
potassium and proton containing δ-MnO 2 catalysts. Catal Commun 92:51–55. https://doi.org/
10.1016/j.catcom.2017.01.002
13. Liu Y, Yang W, Zhang P et al (2018) Nitric acid-treated birnessite-type MnO 2 : an efficient and
hydrophobic material for humid ozone decomposition. Appl Surf Sci 442:640–649. https://doi.
org/10.1016/j.apsusc.2018.02.204
14. Zhang J, Li Y, Wang L et al (2015) Catalytic oxidation of formaldehyde over manganese oxides
with different crystal structures. Catal Sci Technol 5:2305–2313. https://doi.org/10.1039/c4c
y01461h
15. Jia J, Zhang P, Chen L (2016) The effect of morphology of α-MnO 2 on catalytic decomposition
of gaseous ozone. Catal Sci Technol 6:5841–5847. https://doi.org/10.1039/c6cy00301j
16. Suib SL (2008) Structure, porosity, and redox in porous manganese oxide octahedral layer and
molecular sieve materials. J Mater Chem 18:1623–1631. https://doi.org/10.1039/b714966m
17. Tian H, He J, Liu L et al (2013) Effects of textural parameters and noble metal loading on
the catalytic activity of cryptomelane-type manganese oxides for formaldehyde oxidation.
Ceramics Internsh 39:315–321. https://doi.org/10.1016/j.ceramint.2012.06.027
18. Dhandapani B, Oyama ST (1997) Gas phase ozone decomposition catalysts. Appl Catal B
Environ 11:129–166. https://doi.org/10.1016/S0926-3373(96)00044-6
19. Zhu G, Zhu J, Jiang W et al (2017) Surface oxygen vacancy induced α-MnO 2 nanofiber for
highly efficient ozone elimination. Appl Catal B Environ 209:729−737. http://dx.doi.org/doi:
10.1016/j.apcatb.2017.02.068
20. Zhu G, Zhu J, Li W (2018) Tuning the K + concentration in the tunnels of α-MnO 2 to increase
the content of oxygen vacancy for ozone elimination. Environ Sci Technol 52:8684–8692.
https://doi.org/10.1021/acs.est.8b01594
21. Spasova I, Nikolov P, Mehandjiev D (2007) Ozone decomposition over alumina-supported
copper, manganese and copper-manganese catalysts. Ozone Sci Eng 29:41−45. http://dx.doi.
org/10.1080/01919510601111665
22. Liu Y, Zhang P (2017) Removing surface hydroxyl groups of Ce-modified MnO 2 to significantly
improve its stability for gaseous ozone decomposition. J Phys Chem C 121:23488–23497.
https://doi.org/10.1021/acs.jpcc.7b07931
23. Yang Y, Jia J, Liu Y et al (2018) The effect of tungsten doping on the catalytic activity of
α-MnO2 nanomaterial for ozone decomposition under humid condition. Appl Catal A Gen
562:132–141. https://doi.org/10.1016/j.apcata.2018.06.006
24. Luo J, Zhang Q, Garcia-Martinez J et al (2008) Adsorptive and acidic properties, reversible
lattice oxygen evolution, and catalytic mechanism of cryptomelane-type manganese oxides as
oxidation catalysts. J Am Chem Soc 130:3198–3207. https://doi.org/10.1021/ja077706e
25. Özacar M, Poyraz AS, Genuino HC et al (2013) Influence of silver on the catalytic properties
of the cryptomelane and Ag-hollandite types manganese oxides OMS-2 in the low-temperature
CO oxidation. Appl Catal A Gen 462–463:64–74. https://doi.org/10.1016/j.apcata.2013.04.027
26. Jia J, Yang W, Zhang P et al (2017) Facile synthesis of Fe-modified manganese oxide with
high content of oxygen vacancies for efficient airborne ozone destruction. Appl Catal A Gen
546:79−86. http://dx.doi.org/doi:10.1016/j.apcata.2017.08.013
27. Jiang C, Zhang P, Zhang B (2013) Facile synthesis of activated carbon-supported porous
manganese oxide via in situ reduction of permanganate for ozone decomposition. Ozone Sci
Eng 35:308–315. https://doi.org/10.1080/01919512.2013.795854
28. Rao Y, Zeng D, Cao X et al (2019) Synthesis of doped MnO x /diatomite composites for
catalyzing ozone decomposition. Ceramics Internsh 45:6966–6971. https://doi.org/10.1016/
j.ceramint.2018.12.195
29. Rakitskaya T, Truba A, Dzhyga G et al (2018) Water vapor adsorption by some manganese
oxide forms. Colloids Interfaces 2:61. https://doi.org/10.3390/colloids2040061