Nanostructured Electrolytic Composites Based on Cobalt Alloys …
753
molybdenum, and zirconium that are characterized by the different stable oxidation
states and the affinity to oxygen. Hence, a high catalytic activity and corrosion resistance of Co–Mo–Zr coatings allow us to view them as promising electrode materials
for chemical current sources, in particular fuel cells.
Data Availability
The data used to support the findings of this study are available from the
corresponding author upon request.
Acknowledgments This research was conducted with the support of the Ministry of Education
and Science of Ukraine within the confines of the project (Registration Number 0118U002051).
Conflict of Interests
The authors certify that they have no conflicts of interest.
References
1. Averkov IS, Baykov AV, Yanovskiy LS, Volokhov VM (2017) Modeling of electrochemical
processes in solid oxide fuel cells. Russ Chem Bull 65(10):2375–2380. https://doi.org/10.1007/
s11172-016-1592-8
2. Korovin NV, Sedlov AS, Slavnov YA et al (2007) Calculating the efficiency of a hybrid power
station employing a high-temperature fuel cell. Therm Eng 54:137. https://doi.org/10.1134/
S0040601507020115
3. Mench MM (2008) Fuel cell engines. Wiley, Hoboken, New Jersey
4. Liu L, Corma A (2018) Metal catalysts for heterogeneous catalysis: from single atoms to
nanoclusters and nanoparticles. Chem Rev 118(10):4981–5079. https://doi.org/10.1021/acs.
chemrev.7b00776
5. Greeley J, Nørskov JK, Mavrikakis M (2002) Electronic structure and catalysis on metal
surfaces. Annu Rev Phys Chem 53(1):319–348
6. Tarasevich MR, Bogdanovskaya VA (2017) Degradation mechanism of membrane fuel
cells with monoplatinum and multicomponent cathode catalysts. In: Electrocatalysts for low
temperature fuel cells: fundamentals and recent trends. https://doi.org/10.1002/978352780387
3.ch6
7. Ved M, Glushkova M, Sakhnenko N (2013) Catalytic properties of binary and ternary alloys
based on silver. Funct Mater 20(1):87–91. http://dx.doi.org/10.15407/fm20.01.087
8. Sakhnenko ND, Ved MV, Hapon YK, Nenastina TA (2015) Functional coatings of ternary
alloys of cobalt with refractory metals. Russ J Appl Chem 88(12):1941. https://doi.org/10.
1134/S1070427215012006X
9. Yar-Mukhamedova G, Ved’ M, Sakhnenko N, Nenastina T (2018) Electrodeposition and properties of binary and ternary cobalt alloys with molybdenum and tungsten. Appl Surf Sci 445:298.
http://doi.org/10.1016/j.apsusc.2018.03.171
10. Ved’ MV, Koziar MA, Sakhnenko ND, Slavkova MA (2016) Functional properties of electrolytic alloys of cobalt with molybdenum and zirconium. Funct Mater 23(3):420. http://dx.
doi.org/10.15407/fm23.03.420
11. Yapontseva YS, Dikusar AI, Kyblanovskii VS (2014) Study of the composition, corrosion, and
catalytic properties of Co-W alloys electrodeposited from a citrate pyrophosphate electrolyte.
Surf Eng Appl Electrochem 50:330. https://doi.org/10.3103/S1068375514040139
753
molybdenum, and zirconium that are characterized by the different stable oxidation
states and the affinity to oxygen. Hence, a high catalytic activity and corrosion resistance of Co–Mo–Zr coatings allow us to view them as promising electrode materials
for chemical current sources, in particular fuel cells.
Data Availability
The data used to support the findings of this study are available from the
corresponding author upon request.
Acknowledgments This research was conducted with the support of the Ministry of Education
and Science of Ukraine within the confines of the project (Registration Number 0118U002051).
Conflict of Interests
The authors certify that they have no conflicts of interest.
References
1. Averkov IS, Baykov AV, Yanovskiy LS, Volokhov VM (2017) Modeling of electrochemical
processes in solid oxide fuel cells. Russ Chem Bull 65(10):2375–2380. https://doi.org/10.1007/
s11172-016-1592-8
2. Korovin NV, Sedlov AS, Slavnov YA et al (2007) Calculating the efficiency of a hybrid power
station employing a high-temperature fuel cell. Therm Eng 54:137. https://doi.org/10.1134/
S0040601507020115
3. Mench MM (2008) Fuel cell engines. Wiley, Hoboken, New Jersey
4. Liu L, Corma A (2018) Metal catalysts for heterogeneous catalysis: from single atoms to
nanoclusters and nanoparticles. Chem Rev 118(10):4981–5079. https://doi.org/10.1021/acs.
chemrev.7b00776
5. Greeley J, Nørskov JK, Mavrikakis M (2002) Electronic structure and catalysis on metal
surfaces. Annu Rev Phys Chem 53(1):319–348
6. Tarasevich MR, Bogdanovskaya VA (2017) Degradation mechanism of membrane fuel
cells with monoplatinum and multicomponent cathode catalysts. In: Electrocatalysts for low
temperature fuel cells: fundamentals and recent trends. https://doi.org/10.1002/978352780387
3.ch6
7. Ved M, Glushkova M, Sakhnenko N (2013) Catalytic properties of binary and ternary alloys
based on silver. Funct Mater 20(1):87–91. http://dx.doi.org/10.15407/fm20.01.087
8. Sakhnenko ND, Ved MV, Hapon YK, Nenastina TA (2015) Functional coatings of ternary
alloys of cobalt with refractory metals. Russ J Appl Chem 88(12):1941. https://doi.org/10.
1134/S1070427215012006X
9. Yar-Mukhamedova G, Ved’ M, Sakhnenko N, Nenastina T (2018) Electrodeposition and properties of binary and ternary cobalt alloys with molybdenum and tungsten. Appl Surf Sci 445:298.
http://doi.org/10.1016/j.apsusc.2018.03.171
10. Ved’ MV, Koziar MA, Sakhnenko ND, Slavkova MA (2016) Functional properties of electrolytic alloys of cobalt with molybdenum and zirconium. Funct Mater 23(3):420. http://dx.
doi.org/10.15407/fm23.03.420
11. Yapontseva YS, Dikusar AI, Kyblanovskii VS (2014) Study of the composition, corrosion, and
catalytic properties of Co-W alloys electrodeposited from a citrate pyrophosphate electrolyte.
Surf Eng Appl Electrochem 50:330. https://doi.org/10.3103/S1068375514040139