Epoxy Molecular Structure Alteration in Graphene …
481
33. Prolongo SG, Jiménez-Suárez A, Moriche R, Ureña A (2014) Graphene nanoplatelets thickness
and lateral size influence on the morphology and behavior of epoxy composites. Eur Polym J
53:292–301. https://doi.org/10.1016/j.eurpolymj.2014.01.019
34. Ribeiro H, Silva WM, Rodrigues M-TF, Neves JC, Paniago R, Fantini C, Calado HDR, Seara
LM, Silva GG (2013) Glass transition improvement in epoxy-graphene composites. J Mater
Sci 48:7883–7892. https://doi.org/10.1007/s10853-013-7478-3
35. Gresil M, Wang Z, Poutrel Q-A, Soutis C (2017) Thermal diffusivity mapping of graphene
based polymer nanocomposites. Sci Rep 7:5536. https://doi.org/10.1038/s41598-017-05866-0
36. Zaman I, Phan TT, Kuan H, Meng Q, La LTB, Luong L, Youssf O, Ma J (2011) Epoxy/graphene
platelets nanocomposites with two levels of interface strength. Polymer 52(7):1603–1611.
https://doi.org/10.1016/j.polymer.2011.02.003
37. Ma J, Meng Q, Michelmore A, Kawashima N, Izzuddin Z, Bengtsson C, Kuan H (2013)
Covalently bonded interfaces for polymer/graphene composites. J Mater Chem A 1(13):4255–
4264. https://doi.org/10.1039/C3TA01277H
38. Edwards RS, Coleman KS (2013) Graphene synthesis: relationship to applications. Nanoscale
5:38–51. https://doi.org/10.1039/C2NR32629A
39. Mao S, Pu H, Chen J (2012) Graphene oxide and its reduction: modeling and experimental
progress. RSC Adv 2:2643–2662. https://doi.org/10.1039/C2RA00663D
40. Chang DW, Choi H-J, Jeon I-Y, Baek J-B (2013) Edge-selectively functionalized graphene
nanoplatelets. Chem Rec 13(2):224–238. https://doi.org/10.1002/tcr.201200032
41. Xia ZY, Pezzini S, Treossi E, Giambastiani G, Corticelli F, Morandi V, Zanelli A, Bellani V,
Palermo V (2013) The exfoliation of graphene in liquids by electrochemical, chemical, and
sonication-assisted techniques: a nanoscale study. Adv Funct Mater 23(37):4684–4693. https://
doi.org/10.1002/adfm.201370188
42. Bratychak M, Chopyk N (2013) Synthesis and application of oligoesteric mixtures of ED20 epoxy resin peroxide derivative during cross-linking. Chem Chem Technol 7(4):435–440.
https://doi.org/10.23939/chcht07.04.435
43. Bratychak M, Ivashkiv O, Astakhova O (2014) Chemical modification of ED-20 epoxy
oligomer by 1,4-butanediol. Dopovidi Nats Acad Nauk Ukrainy 8:97–102. https://doi.org/
10.15407/dopovidi2014.08.097
44. Bouvet G, Nguyen Dang S, Cohendoz X, Feaugas S, Mallarino S Touzain (2016) Impact of
polar groups concentration and free volume on water sorption in model epoxy free films and
coatings. Prog Org Coat 96:32–41. https://doi.org/10.1016/j.porgcoat.2015.12.011
45. Kremer F, Schonhals A, Luck W (2003) Broadband dielectric spectroscopy. Springer-Verlag
Berlin Heidelberg. https://doi.org/10.1007/978-3-642-56120-7
46. Gorelov BM, Gorb AM, Polovina OI, Wacke S, Czapla Z, Kosrtzewa M, Ingram A (2018)
Filler’s impact on structure and physical properties in polyester resin–oxide nanocomposites.
Adsorpt Sci Technol 36(1–2):549–570. https://doi.org/10.1177/0263617417706797
47. Pokrovsky VA (2000) Temperature-programmed desorption mass spectrometry. J Therm Anal
Calorim 62(2):407–415. https://doi.org/10.1023/A:1010177813557
48. Gorelov B, Gorb A, Korotchenkov O, Nadtochiy A, Polovina O, Sigareva N (2015) Impact of
nanosized oxide fillers on elastic properties and thermal destruction of a styrene cross-linked
polyester resin. J Appl Polym Sci 132(22):42010/1-10. https://doi.org/10.1002/app.42010
49. Gorelov BM, Gorb AM, Czapla Z, Wacke S, Nadtochiy AB, Kuryliuk VV, Kostrzewa M, Ingram
A, Starokadomskiy DL, Korotchenkov OO, Polovina OI, Sigareva NV (2019) Impact of multilayered graphene nanoplatelets on 3D-molecular network of an epoxy resin. In: Proceedings
of the 2019 IEEE 9th International Conference on Nanomaterials: Applications and Properties
(NAP-2019), pp 01SSAN07-1–01SSAN07-5
50. Kansy J (1996) Microcomputer program for analysis of positron annihilation lifetime spectra.
Nucl Instrum Methods A374(2):235–244. https://doi.org/10.1016/0168-9002(96)00075-7
51. Schrader DM, Jean YC (1988) Positron and positron chemistry. Study in physical and
theoretical chemistry. Elsevier, Amsterdam-Oxford-New York-Tokyo, p 120
52. Jean YC, Van Horn JD, Wei-Song H (2013) Perspective of positron annihilation spectroscopy
in polymers. Macromolecules 46(18):7133–7145. https://doi.org/10.1021/ma401309x
481
33. Prolongo SG, Jiménez-Suárez A, Moriche R, Ureña A (2014) Graphene nanoplatelets thickness
and lateral size influence on the morphology and behavior of epoxy composites. Eur Polym J
53:292–301. https://doi.org/10.1016/j.eurpolymj.2014.01.019
34. Ribeiro H, Silva WM, Rodrigues M-TF, Neves JC, Paniago R, Fantini C, Calado HDR, Seara
LM, Silva GG (2013) Glass transition improvement in epoxy-graphene composites. J Mater
Sci 48:7883–7892. https://doi.org/10.1007/s10853-013-7478-3
35. Gresil M, Wang Z, Poutrel Q-A, Soutis C (2017) Thermal diffusivity mapping of graphene
based polymer nanocomposites. Sci Rep 7:5536. https://doi.org/10.1038/s41598-017-05866-0
36. Zaman I, Phan TT, Kuan H, Meng Q, La LTB, Luong L, Youssf O, Ma J (2011) Epoxy/graphene
platelets nanocomposites with two levels of interface strength. Polymer 52(7):1603–1611.
https://doi.org/10.1016/j.polymer.2011.02.003
37. Ma J, Meng Q, Michelmore A, Kawashima N, Izzuddin Z, Bengtsson C, Kuan H (2013)
Covalently bonded interfaces for polymer/graphene composites. J Mater Chem A 1(13):4255–
4264. https://doi.org/10.1039/C3TA01277H
38. Edwards RS, Coleman KS (2013) Graphene synthesis: relationship to applications. Nanoscale
5:38–51. https://doi.org/10.1039/C2NR32629A
39. Mao S, Pu H, Chen J (2012) Graphene oxide and its reduction: modeling and experimental
progress. RSC Adv 2:2643–2662. https://doi.org/10.1039/C2RA00663D
40. Chang DW, Choi H-J, Jeon I-Y, Baek J-B (2013) Edge-selectively functionalized graphene
nanoplatelets. Chem Rec 13(2):224–238. https://doi.org/10.1002/tcr.201200032
41. Xia ZY, Pezzini S, Treossi E, Giambastiani G, Corticelli F, Morandi V, Zanelli A, Bellani V,
Palermo V (2013) The exfoliation of graphene in liquids by electrochemical, chemical, and
sonication-assisted techniques: a nanoscale study. Adv Funct Mater 23(37):4684–4693. https://
doi.org/10.1002/adfm.201370188
42. Bratychak M, Chopyk N (2013) Synthesis and application of oligoesteric mixtures of ED20 epoxy resin peroxide derivative during cross-linking. Chem Chem Technol 7(4):435–440.
https://doi.org/10.23939/chcht07.04.435
43. Bratychak M, Ivashkiv O, Astakhova O (2014) Chemical modification of ED-20 epoxy
oligomer by 1,4-butanediol. Dopovidi Nats Acad Nauk Ukrainy 8:97–102. https://doi.org/
10.15407/dopovidi2014.08.097
44. Bouvet G, Nguyen Dang S, Cohendoz X, Feaugas S, Mallarino S Touzain (2016) Impact of
polar groups concentration and free volume on water sorption in model epoxy free films and
coatings. Prog Org Coat 96:32–41. https://doi.org/10.1016/j.porgcoat.2015.12.011
45. Kremer F, Schonhals A, Luck W (2003) Broadband dielectric spectroscopy. Springer-Verlag
Berlin Heidelberg. https://doi.org/10.1007/978-3-642-56120-7
46. Gorelov BM, Gorb AM, Polovina OI, Wacke S, Czapla Z, Kosrtzewa M, Ingram A (2018)
Filler’s impact on structure and physical properties in polyester resin–oxide nanocomposites.
Adsorpt Sci Technol 36(1–2):549–570. https://doi.org/10.1177/0263617417706797
47. Pokrovsky VA (2000) Temperature-programmed desorption mass spectrometry. J Therm Anal
Calorim 62(2):407–415. https://doi.org/10.1023/A:1010177813557
48. Gorelov B, Gorb A, Korotchenkov O, Nadtochiy A, Polovina O, Sigareva N (2015) Impact of
nanosized oxide fillers on elastic properties and thermal destruction of a styrene cross-linked
polyester resin. J Appl Polym Sci 132(22):42010/1-10. https://doi.org/10.1002/app.42010
49. Gorelov BM, Gorb AM, Czapla Z, Wacke S, Nadtochiy AB, Kuryliuk VV, Kostrzewa M, Ingram
A, Starokadomskiy DL, Korotchenkov OO, Polovina OI, Sigareva NV (2019) Impact of multilayered graphene nanoplatelets on 3D-molecular network of an epoxy resin. In: Proceedings
of the 2019 IEEE 9th International Conference on Nanomaterials: Applications and Properties
(NAP-2019), pp 01SSAN07-1–01SSAN07-5
50. Kansy J (1996) Microcomputer program for analysis of positron annihilation lifetime spectra.
Nucl Instrum Methods A374(2):235–244. https://doi.org/10.1016/0168-9002(96)00075-7
51. Schrader DM, Jean YC (1988) Positron and positron chemistry. Study in physical and
theoretical chemistry. Elsevier, Amsterdam-Oxford-New York-Tokyo, p 120
52. Jean YC, Van Horn JD, Wei-Song H (2013) Perspective of positron annihilation spectroscopy
in polymers. Macromolecules 46(18):7133–7145. https://doi.org/10.1021/ma401309x