28 Copper Nucleation on Nickel from Pyrophosphate-Based Polyligand Electrolyte
451
Fig. 28.7 Numerical fit line calculated according to Eqs. (28.7), (28.8), and (28.9) of the
experimental current transients (dots) recorded at −0.6 V (a), −0.7 V (b), −0.8 V (c), −0.9 V (d),
−1.0 V (e), and −1.1 V (f)
Table 28.1 Parameters of
2DI copper nucleation and
growth
k 2D 1
k 2D 2
Q 2D
k 2
disk N 0
E, V mAcm −2 s −1 s −2
mC cm −2 mol 2 cm −6 s −2
−0.6 172
77.21 1.11
0.485
−0.7
24.3
4.81 2.51
0.030
−0.8 205.2
17.48 5.87
0.110
−0.9 487.4
25.38 9.60
0.159
−1
606
31.14 9.73
0.196
−1.1 521
39.88 6.53
0.251
451
Fig. 28.7 Numerical fit line calculated according to Eqs. (28.7), (28.8), and (28.9) of the
experimental current transients (dots) recorded at −0.6 V (a), −0.7 V (b), −0.8 V (c), −0.9 V (d),
−1.0 V (e), and −1.1 V (f)
Table 28.1 Parameters of
2DI copper nucleation and
growth
k 2D 1
k 2D 2
Q 2D
k 2
disk N 0
E, V mAcm −2 s −1 s −2
mC cm −2 mol 2 cm −6 s −2
−0.6 172
77.21 1.11
0.485
−0.7
24.3
4.81 2.51
0.030
−0.8 205.2
17.48 5.87
0.110
−0.9 487.4
25.38 9.60
0.159
−1
606
31.14 9.73
0.196
−1.1 521
39.88 6.53
0.251