68
3 Confinement Effects on the Reactivity in Ultrathin …
13. Jeong U, Kim HC, Rodriguez RL, Tsai IY, Stafford CM, Kim JK, Hawker CJ, Russell TP (2002)
Asymmetric block copolymers homopolymers: routes to multiple length scale nanostructures.
Adv Mater 14:274–276
14. Schönherr H, Frank CW (2003) Ultrathin films of poly(ethylene oxides) on oxidized silicon. 1.
Spectroscopic characterization of films structure and crystallization kinetics. Macromolecules
36:1188–1198
15. Mengel C, Esker AR, Meyer WH, Wegner G (2002) Preparation and modification of
poly(methacrylic acid) and poly(acrylic acid) multilayers. Langmuir 18:6365–6372
16. Laibinis PE, Bain CD, Nuzzo RG, Whitesides GM (1995) Structure and Wetting Properties of
omega.-Alkoxy-n-alkanethiolate Monolayers on Gold and Silver. J Phys Chem 99:7663–7676
17. Israelachvili JN, Gee ML (1989) Contact angles on chemically heterogeneous surfaces.
Langmuir 5:288–289
18. Dordi B, Schönherr H, Vancso GJ (2003) Reactivity in the confinement of self-assembled
monolayers: chain length effects on the hydrolysis of N-hydroxysuccinimide ester disulfides
on gold. Langmuir 19:5780–5786
19. Pan S, Castner DG, Ratner BD (1998) Langmuir 14:3545–3550
20. Schönherr H, Feng CL, Shovsky A (2003) Interfacial reactions in confinement: kinetics and
temperature dependence of reactions in self-assembled monolayers compared to ultrathin
polymer films. Langmuir 19:10843–10851
21. Besselink GAJ, Beugeling T, Bantjes A (1993) N-Hydroxysussinimide-activated glycinesepharose. Appl Biochem Biotech 43:227
22. Elbs H, Fukunaga K, Stadler R, Sauer G, Magerle R, Krausch G (1999) Microdomain
morphology of thin ABC triblock copolymer films. Macromolecules 32:1204–1211
23. Liu Z, Pappacena K, Cerise J, Kim J, Durning CJ, O´Shaughnessy B, Levicky R (2002)
Organization of nanoparticles on soft polymer surfaces. Nano Lett 2:219–224
24. Camillone N III, Chidsey CED, Liu GY, Putvinski TM, Scoles G (1991) Surface structure and
thermal motion of n-alkane thiols self-assembled on Au(111) studied by low energy helium
diffraction. J Chem Phys 94:8493–8502
25. Fernández-García M, de la Fuente JL, Cerrada ML, Madruga EL (2002) Preparation of
poly(tert-butyl acrylate-g-styrene) as precursors of amphiphilic graft copolymer. 1. Kinetic
study and thermal properties. Polymer 43:3173–3179
26. Lu Z, Liu G, Duncan S (2004) Polysulfone-graft-poly(tert-butyl acrylate): synthesis, nanophase
separation, poly(tert-butyl acrylate) hydrolysis, and pH-dependent iridescene. Macromolecues
37:174–180
27. Fasolka MJ, Banerjee P, Mayes AM, Pickett G, Balazs AC (2000) Morphology of ultrathin
supported diblock copolymer films: theory and experiment. Macromolecules 33:5702–5712
28. Schönherr H, Vancso GJ (1998) Surface properties of oxidized LDPE by scanning force
microscopy with chemically modified probes. J Polym Sci B Polym Phys 36:2483–2492
29. Andersen TH, Tougaard S, Larsen NB, Almdal K, Johannsen I (2001) Surface morphology of
PS-PDMS diblock copolymer films. J Electron Spectro Related Phenom 121:93–110
30. Kim JH, Park DS, Kim CKJ (2000) Polymer Sci B Polymer Phys 38:2666–2677
31. Bunnett JF (1961) Kinetics of reactions in moderately concentrated aqueous acids. 1.
Classification of reactions. J Am Chem Soc 83:4956–4967
32. Batz HG, Franzmann G, Ringsdorf H (1973) Pharmakologisch active polymere, 5. Modellreaktionen zur umsetzung von pharmaka und enzyme mit monomeren und polymeren reactive
estern. Makromol Chem 172:27–47
33. Davis KA, Matyjaszewski K (2000) Atom transfer radical polymerization of tert-butyl acrylate
and preparation of block copolymers. Macromolecules 33:4039–4047
34. Ron H, Rubinstein I (1994) Alkanethiol monolayers on preoxidized gold. Encapsulation of
gold oxide under an organic monolayer. Langmuir 10:4566–4573
35. Lee JN, Park C, Whitesides GM (2003) Anal Chem 75:6544–6554
36. Reilman RF, Msezane A, Manson ST (1976) Relative intensities in photoelectron-spectroscopy
of atoms and molecules. J Electron Spectrosc 8:389–394
3 Confinement Effects on the Reactivity in Ultrathin …
13. Jeong U, Kim HC, Rodriguez RL, Tsai IY, Stafford CM, Kim JK, Hawker CJ, Russell TP (2002)
Asymmetric block copolymers homopolymers: routes to multiple length scale nanostructures.
Adv Mater 14:274–276
14. Schönherr H, Frank CW (2003) Ultrathin films of poly(ethylene oxides) on oxidized silicon. 1.
Spectroscopic characterization of films structure and crystallization kinetics. Macromolecules
36:1188–1198
15. Mengel C, Esker AR, Meyer WH, Wegner G (2002) Preparation and modification of
poly(methacrylic acid) and poly(acrylic acid) multilayers. Langmuir 18:6365–6372
16. Laibinis PE, Bain CD, Nuzzo RG, Whitesides GM (1995) Structure and Wetting Properties of
omega.-Alkoxy-n-alkanethiolate Monolayers on Gold and Silver. J Phys Chem 99:7663–7676
17. Israelachvili JN, Gee ML (1989) Contact angles on chemically heterogeneous surfaces.
Langmuir 5:288–289
18. Dordi B, Schönherr H, Vancso GJ (2003) Reactivity in the confinement of self-assembled
monolayers: chain length effects on the hydrolysis of N-hydroxysuccinimide ester disulfides
on gold. Langmuir 19:5780–5786
19. Pan S, Castner DG, Ratner BD (1998) Langmuir 14:3545–3550
20. Schönherr H, Feng CL, Shovsky A (2003) Interfacial reactions in confinement: kinetics and
temperature dependence of reactions in self-assembled monolayers compared to ultrathin
polymer films. Langmuir 19:10843–10851
21. Besselink GAJ, Beugeling T, Bantjes A (1993) N-Hydroxysussinimide-activated glycinesepharose. Appl Biochem Biotech 43:227
22. Elbs H, Fukunaga K, Stadler R, Sauer G, Magerle R, Krausch G (1999) Microdomain
morphology of thin ABC triblock copolymer films. Macromolecules 32:1204–1211
23. Liu Z, Pappacena K, Cerise J, Kim J, Durning CJ, O´Shaughnessy B, Levicky R (2002)
Organization of nanoparticles on soft polymer surfaces. Nano Lett 2:219–224
24. Camillone N III, Chidsey CED, Liu GY, Putvinski TM, Scoles G (1991) Surface structure and
thermal motion of n-alkane thiols self-assembled on Au(111) studied by low energy helium
diffraction. J Chem Phys 94:8493–8502
25. Fernández-García M, de la Fuente JL, Cerrada ML, Madruga EL (2002) Preparation of
poly(tert-butyl acrylate-g-styrene) as precursors of amphiphilic graft copolymer. 1. Kinetic
study and thermal properties. Polymer 43:3173–3179
26. Lu Z, Liu G, Duncan S (2004) Polysulfone-graft-poly(tert-butyl acrylate): synthesis, nanophase
separation, poly(tert-butyl acrylate) hydrolysis, and pH-dependent iridescene. Macromolecues
37:174–180
27. Fasolka MJ, Banerjee P, Mayes AM, Pickett G, Balazs AC (2000) Morphology of ultrathin
supported diblock copolymer films: theory and experiment. Macromolecules 33:5702–5712
28. Schönherr H, Vancso GJ (1998) Surface properties of oxidized LDPE by scanning force
microscopy with chemically modified probes. J Polym Sci B Polym Phys 36:2483–2492
29. Andersen TH, Tougaard S, Larsen NB, Almdal K, Johannsen I (2001) Surface morphology of
PS-PDMS diblock copolymer films. J Electron Spectro Related Phenom 121:93–110
30. Kim JH, Park DS, Kim CKJ (2000) Polymer Sci B Polymer Phys 38:2666–2677
31. Bunnett JF (1961) Kinetics of reactions in moderately concentrated aqueous acids. 1.
Classification of reactions. J Am Chem Soc 83:4956–4967
32. Batz HG, Franzmann G, Ringsdorf H (1973) Pharmakologisch active polymere, 5. Modellreaktionen zur umsetzung von pharmaka und enzyme mit monomeren und polymeren reactive
estern. Makromol Chem 172:27–47
33. Davis KA, Matyjaszewski K (2000) Atom transfer radical polymerization of tert-butyl acrylate
and preparation of block copolymers. Macromolecules 33:4039–4047
34. Ron H, Rubinstein I (1994) Alkanethiol monolayers on preoxidized gold. Encapsulation of
gold oxide under an organic monolayer. Langmuir 10:4566–4573
35. Lee JN, Park C, Whitesides GM (2003) Anal Chem 75:6544–6554
36. Reilman RF, Msezane A, Manson ST (1976) Relative intensities in photoelectron-spectroscopy
of atoms and molecules. J Electron Spectrosc 8:389–394