45
195. Aguado R, Olazar M, Jose MJS, Aguirre G, Bilbao J (2000) Pyrolysis of sawdust in a conical
spouted bed reactor. Yields and product composition. Ind Eng Chem Res 39(6):1925–1933
196. Nie L, Resasco DE (2012) Improving carbon retention in biomass conversion by alkylation
of phenolics with small oxygenates. Appl Catal A Gen 447:14–21
197. Zapata PA, Faria J, Ruiz MP, Resasco DE (2012) Condensation/hydrogenation of biomassderived oxygenates in water/oil emulsions stabilized by nanohybrid catalysts. Top Catal
55(1–2):38–52
198. Gliński M, Kijeński J (2000) Decarboxylative coupling of heptanoic acid. Manganese,
cerium and zirconium oxides as catalysts. Appl Catal Gen 190(1–2):87–91
199. Okumura K, Iwasawa Y (1996) Zirconium oxides dispersed on silica derived from Cp2ZrCl2,
[(i-PrCp)2ZrH(μ-H)]2, and Zr(OEt)4 characterized by x-ray absorption fine structure and
catalytic ketonization of acetic acid. J Catal 164(2):440–448
200. Gliński M, Kijeński J (2000) Catalytic ketonization of carboxylic acids synthesis of saturated
and unsaturated ketones. React Kinet Catal L 69(1):123–128
201. Parida KM, Samal A, Das NN (1998) Catalytic ketonization of monocarboxylic acids over
Indian Ocean manganese nodules. Appl Catal Gen 166(1):201–205
202. Randery SD, Warren JS, Dooley KM (2002) Cerium oxide-based catalysts for production of
ketones by acid condensation. Appl Catal A Gen 226(1–2):265–280
203. Dooley KM, Bhat AK, Plaisance CP, Roy AD (2007) Ketones from acid condensation using
supported CeO2 catalysts: effect of additives. Appl Catal A Gen 320:122–133
204. Nagashima O, Sato S, Takahashi R, Sodesawa T (2005) Ketonization of carboxylic acids over
CeO2-based composite oxides. J Mol Catal A Chem 227(1–2):231–239
205. Pestman R, Koster RM, vanDuijne A, Pieterse JAZ, Ponec V (1997) Reactions of carboxylic
acids on oxides 0.2. Bimolecular reaction of aliphatic acids to ketones. J Catal 168(2):265–272
206. Zaki MI, Hasan MA, Pasupulety L (2001) Surface reactions of acetone on Al2O3, TiO2,
ZrO2, and CeO2: IR spectroscopic assessment of impacts of the surface acid-base properties.
Langmuir 17(3):768–774
207. Zaki MI, Hasan MA, Al-Sagheer FA, Pasupulety L (2001) In situ FTIR spectra of pyridine
adsorbed on SiO2-Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides. Colloid Surf A 190(3):261–274
208. Martin D, Duprez D (1997) Evaluation of the acid-base surface properties of several
oxides and supported metal catalysts by means of model reactions. J Mol Catal A Chem
118(1):113–128
209. Jahangiri H, Osatiashtiani A, Bennett JA, Isaacs MA, Gu S, Lee AF et al (2018) Zirconia
catalysed acetic acid ketonisation for pre-treatment of biomass fast pyrolysis vapours. Cat Sci
Technol 8(4):1134–1141
210. Pham TN, Sooknoi T, Crossley SP, Resasco DE (2013) Ketonization of carboxylic acids:
mechanisms, catalysts, and implications for biomass conversion. ACS Catal 3(11):2456–2473
211. Vervecken M, Servotte Y, Wydoodt M, Jacobs L, Martens JA, Jacobs PA (1986) Zeoliteinduced selectivity in the conversion of the lower aliphatic carboxylic acids. In: Setton R
(ed) chemical reactions in organic and inorganic constrained systems. Springer, Dordrecht,
pp 95–114
212. Jahangiri H, Osatiashtiani A, Ouadi M, Hornung A, Lee AF, Wilson K (2019) Ga/HZSM-5
catalysed acetic acid ketonisation for upgrading of biomass pyrolysis vapours. Catalysts
9(10):841
213. Danon B, Marcotullio G, de Jong W (2014) Mechanistic and kinetic aspects of pentose dehydration towards furfural in aqueous media employing homogeneous catalysis. Green Chem
16(1):39–54
214. Zeitsch KJ (2000) Furfural production needs chemical innovation. Chem Innov 30(4):29–32
215. Panagiotopoulou P, Vlachos DG (2014) Liquid phase catalytic transfer hydrogenation of furfural over a Ru/C catalyst. Appl Catal A Gen 480:17–24
216. Dias AS, Pillinger M, Valente AA (2005) Dehydration of xylose into furfural over micromesoporous sulfonic acid catalysts. J Catal 229(2):414–423
Thermochemical Conversion of Biomass and Upgrading of Bio-Products to Produce…
195. Aguado R, Olazar M, Jose MJS, Aguirre G, Bilbao J (2000) Pyrolysis of sawdust in a conical
spouted bed reactor. Yields and product composition. Ind Eng Chem Res 39(6):1925–1933
196. Nie L, Resasco DE (2012) Improving carbon retention in biomass conversion by alkylation
of phenolics with small oxygenates. Appl Catal A Gen 447:14–21
197. Zapata PA, Faria J, Ruiz MP, Resasco DE (2012) Condensation/hydrogenation of biomassderived oxygenates in water/oil emulsions stabilized by nanohybrid catalysts. Top Catal
55(1–2):38–52
198. Gliński M, Kijeński J (2000) Decarboxylative coupling of heptanoic acid. Manganese,
cerium and zirconium oxides as catalysts. Appl Catal Gen 190(1–2):87–91
199. Okumura K, Iwasawa Y (1996) Zirconium oxides dispersed on silica derived from Cp2ZrCl2,
[(i-PrCp)2ZrH(μ-H)]2, and Zr(OEt)4 characterized by x-ray absorption fine structure and
catalytic ketonization of acetic acid. J Catal 164(2):440–448
200. Gliński M, Kijeński J (2000) Catalytic ketonization of carboxylic acids synthesis of saturated
and unsaturated ketones. React Kinet Catal L 69(1):123–128
201. Parida KM, Samal A, Das NN (1998) Catalytic ketonization of monocarboxylic acids over
Indian Ocean manganese nodules. Appl Catal Gen 166(1):201–205
202. Randery SD, Warren JS, Dooley KM (2002) Cerium oxide-based catalysts for production of
ketones by acid condensation. Appl Catal A Gen 226(1–2):265–280
203. Dooley KM, Bhat AK, Plaisance CP, Roy AD (2007) Ketones from acid condensation using
supported CeO2 catalysts: effect of additives. Appl Catal A Gen 320:122–133
204. Nagashima O, Sato S, Takahashi R, Sodesawa T (2005) Ketonization of carboxylic acids over
CeO2-based composite oxides. J Mol Catal A Chem 227(1–2):231–239
205. Pestman R, Koster RM, vanDuijne A, Pieterse JAZ, Ponec V (1997) Reactions of carboxylic
acids on oxides 0.2. Bimolecular reaction of aliphatic acids to ketones. J Catal 168(2):265–272
206. Zaki MI, Hasan MA, Pasupulety L (2001) Surface reactions of acetone on Al2O3, TiO2,
ZrO2, and CeO2: IR spectroscopic assessment of impacts of the surface acid-base properties.
Langmuir 17(3):768–774
207. Zaki MI, Hasan MA, Al-Sagheer FA, Pasupulety L (2001) In situ FTIR spectra of pyridine
adsorbed on SiO2-Al2O3, TiO2, ZrO2 and CeO2: general considerations for the identification of acid sites on surfaces of finely divided metal oxides. Colloid Surf A 190(3):261–274
208. Martin D, Duprez D (1997) Evaluation of the acid-base surface properties of several
oxides and supported metal catalysts by means of model reactions. J Mol Catal A Chem
118(1):113–128
209. Jahangiri H, Osatiashtiani A, Bennett JA, Isaacs MA, Gu S, Lee AF et al (2018) Zirconia
catalysed acetic acid ketonisation for pre-treatment of biomass fast pyrolysis vapours. Cat Sci
Technol 8(4):1134–1141
210. Pham TN, Sooknoi T, Crossley SP, Resasco DE (2013) Ketonization of carboxylic acids:
mechanisms, catalysts, and implications for biomass conversion. ACS Catal 3(11):2456–2473
211. Vervecken M, Servotte Y, Wydoodt M, Jacobs L, Martens JA, Jacobs PA (1986) Zeoliteinduced selectivity in the conversion of the lower aliphatic carboxylic acids. In: Setton R
(ed) chemical reactions in organic and inorganic constrained systems. Springer, Dordrecht,
pp 95–114
212. Jahangiri H, Osatiashtiani A, Ouadi M, Hornung A, Lee AF, Wilson K (2019) Ga/HZSM-5
catalysed acetic acid ketonisation for upgrading of biomass pyrolysis vapours. Catalysts
9(10):841
213. Danon B, Marcotullio G, de Jong W (2014) Mechanistic and kinetic aspects of pentose dehydration towards furfural in aqueous media employing homogeneous catalysis. Green Chem
16(1):39–54
214. Zeitsch KJ (2000) Furfural production needs chemical innovation. Chem Innov 30(4):29–32
215. Panagiotopoulou P, Vlachos DG (2014) Liquid phase catalytic transfer hydrogenation of furfural over a Ru/C catalyst. Appl Catal A Gen 480:17–24
216. Dias AS, Pillinger M, Valente AA (2005) Dehydration of xylose into furfural over micromesoporous sulfonic acid catalysts. J Catal 229(2):414–423
Thermochemical Conversion of Biomass and Upgrading of Bio-Products to Produce…