501
132. Babu MS, Srivani A, Parameswaram G, Veerabhadram G, Lingaiah N (2015) Understanding
the role of tantalum in heteropoly tungstate catalysts for the synthesis of glycerol carbonate
from glycerol and urea. Catal Lett 145:1784–1791
133. Nguyen-Phu H, Shin EW (2018) Investigating time-dependent Zn species over Zn-based
catalysts in glycerol carbonylation with urea and their roles in the reaction mechanism. Appl
Catal A 561:28–40
134. Luo W, Sun L, Yang Y, Chen Y, Zhou Z, Liua J, Wang F (2018) Cu-Mn composite oxides:
a highly efficient and reusable acid-base catalysts for the carbonylation reaction of glycerol
with urea. Cat Sci Technol 8:6468–6477
135. Chaves DM, Da Silva MJ (2019) A selective synthesis of glycerol carbonate from glycerol and urea over Sn(OH) 2 : a solid and recyclable in situ generated catalyst. New J Chem
43:3698–3706
136. Jagadeeswaraiah K, Kumar CR, Rajashekar A, Srivani A, Lingaiah N (2016) The role of
tungsten oxide species supported on titania catalysts for the synthesis of glycerol carbonate
from glycerol and urea. Catal Lett 146:692–700
137. Li Q, Zhang W, Zhao N, Wei W, Sun Y (2006) Synthesis of cyclic carbonates from urea and
diols over metal oxides. Today 115:111–116
138. Patel A, Singh S (2014) A green and sustainable approach for esterification of glycerol using
12-tungstophosphoric acid anchored to different supports: kinetics and effect of support. Fuel
118:358–364
139. Hammond C, Sanchez JAL, Rahim MHA, Dimitratos N, Jenkins RL, Carley AF, He Q, Kiely
CJ, Knight DW, Hutchings GJ (2011) Synthesis of glycerol carbonate from glycerol and urea
with gold-based catalysts. Dalton Trans 40:3927–3937
140. Jagadeeswaraiah K, Kumar CR, Prasad PSS, Lingaiah N (2014) Incorporation of Zn2+ ions
into the secondary structure of heteropoly tungstate: catalytic efficiency for synthesis of glycerol carbonate from glycerol and urea. Cat Sci Technol 4:2969–2977
141. Ferreira P, Fonseca IM, Ramos AM, Vital J, Castanheiro JE (2009) Esterification of glycerol with acetic acid over dodecamolybdophosphoric acid encaged in USY zeolite. Catal
Commun 10:481–484
142. Liao X, Zhu Y, Wang SG, Li Y (2009) Producing triacetylglycerol with glycerol by two steps:
esterification and acetylation. Fuel Process Technol 90:988–993
143. Zhou L, Nguyen TH, Adesina A (2012) The acetylation of glycerol over amberlyst-15: kinetic
and product distribution. Fuel Process Technol 104:310–318
144. Melero JA, Grieken RV, Morales G, Paniagua M (2007) Acidic mesoporous silica for the
acetylation of glycerol: synthesis of bioadditives to petrol fuel. Energy Fuel 21:1782–1791
145. Khayoon MS, Hameed BH (2012) Synthesis of hybrid SBA-15 functionalized with molybdophosphoric acid as efficient catalyst for glycerol esterification to fuel additives. Appl Catal
A Gen 433–434:152–161
146. Stawicka K, Trejda M, Ziolek M (2013) The production of biofuels additives on sulphonated
MCF materials modified with Nb and Ta—towards efficient solid catalysts of esterification.
Appl Catal A Gen 467:325–334
147. Kale S, Umbarkar SB, Dongare MK, Eckelt R, Armbruster U, Martin A (2015) Selective
formation of triacetin by glycerol acetylation using acidic ion-exchange resins as catalyst and
toluene as an entrainer. Appl Catal A Gen 490:10–16
148. Reddy PS, Sudarsanam P, Raju G, Reddy BM (2012) Selective acetylation of glycerol over
CeO 2 –M and SO 4
2−
/CeO 2 –M (M = ZrO 2 and Al 2 O 3 ) catalysts for synthesis of bioadditives. J
Ind Eng Chem 18:648–654
149. Zhu S, Zhu Y, Gao X, Mo T, Zhu Y, Li Y (2013) Production of bioadditives from glycerol
esterification over zirconia supported heteropolyacids. Bioresour Technol 130:45–51
150. Zhu S, Gao X, Dong F, Zhu Y, Zheng H, Li Y (2013) Design of a highly active silverexchanged phosphotungstic acid catalyst for glycerol esterification with acetic acid. J Catal
306:155–163
Catalytic Conversion of Biomass-Derived Glycerol to Value-Added Chemicals
132. Babu MS, Srivani A, Parameswaram G, Veerabhadram G, Lingaiah N (2015) Understanding
the role of tantalum in heteropoly tungstate catalysts for the synthesis of glycerol carbonate
from glycerol and urea. Catal Lett 145:1784–1791
133. Nguyen-Phu H, Shin EW (2018) Investigating time-dependent Zn species over Zn-based
catalysts in glycerol carbonylation with urea and their roles in the reaction mechanism. Appl
Catal A 561:28–40
134. Luo W, Sun L, Yang Y, Chen Y, Zhou Z, Liua J, Wang F (2018) Cu-Mn composite oxides:
a highly efficient and reusable acid-base catalysts for the carbonylation reaction of glycerol
with urea. Cat Sci Technol 8:6468–6477
135. Chaves DM, Da Silva MJ (2019) A selective synthesis of glycerol carbonate from glycerol and urea over Sn(OH) 2 : a solid and recyclable in situ generated catalyst. New J Chem
43:3698–3706
136. Jagadeeswaraiah K, Kumar CR, Rajashekar A, Srivani A, Lingaiah N (2016) The role of
tungsten oxide species supported on titania catalysts for the synthesis of glycerol carbonate
from glycerol and urea. Catal Lett 146:692–700
137. Li Q, Zhang W, Zhao N, Wei W, Sun Y (2006) Synthesis of cyclic carbonates from urea and
diols over metal oxides. Today 115:111–116
138. Patel A, Singh S (2014) A green and sustainable approach for esterification of glycerol using
12-tungstophosphoric acid anchored to different supports: kinetics and effect of support. Fuel
118:358–364
139. Hammond C, Sanchez JAL, Rahim MHA, Dimitratos N, Jenkins RL, Carley AF, He Q, Kiely
CJ, Knight DW, Hutchings GJ (2011) Synthesis of glycerol carbonate from glycerol and urea
with gold-based catalysts. Dalton Trans 40:3927–3937
140. Jagadeeswaraiah K, Kumar CR, Prasad PSS, Lingaiah N (2014) Incorporation of Zn2+ ions
into the secondary structure of heteropoly tungstate: catalytic efficiency for synthesis of glycerol carbonate from glycerol and urea. Cat Sci Technol 4:2969–2977
141. Ferreira P, Fonseca IM, Ramos AM, Vital J, Castanheiro JE (2009) Esterification of glycerol with acetic acid over dodecamolybdophosphoric acid encaged in USY zeolite. Catal
Commun 10:481–484
142. Liao X, Zhu Y, Wang SG, Li Y (2009) Producing triacetylglycerol with glycerol by two steps:
esterification and acetylation. Fuel Process Technol 90:988–993
143. Zhou L, Nguyen TH, Adesina A (2012) The acetylation of glycerol over amberlyst-15: kinetic
and product distribution. Fuel Process Technol 104:310–318
144. Melero JA, Grieken RV, Morales G, Paniagua M (2007) Acidic mesoporous silica for the
acetylation of glycerol: synthesis of bioadditives to petrol fuel. Energy Fuel 21:1782–1791
145. Khayoon MS, Hameed BH (2012) Synthesis of hybrid SBA-15 functionalized with molybdophosphoric acid as efficient catalyst for glycerol esterification to fuel additives. Appl Catal
A Gen 433–434:152–161
146. Stawicka K, Trejda M, Ziolek M (2013) The production of biofuels additives on sulphonated
MCF materials modified with Nb and Ta—towards efficient solid catalysts of esterification.
Appl Catal A Gen 467:325–334
147. Kale S, Umbarkar SB, Dongare MK, Eckelt R, Armbruster U, Martin A (2015) Selective
formation of triacetin by glycerol acetylation using acidic ion-exchange resins as catalyst and
toluene as an entrainer. Appl Catal A Gen 490:10–16
148. Reddy PS, Sudarsanam P, Raju G, Reddy BM (2012) Selective acetylation of glycerol over
CeO 2 –M and SO 4
2−
/CeO 2 –M (M = ZrO 2 and Al 2 O 3 ) catalysts for synthesis of bioadditives. J
Ind Eng Chem 18:648–654
149. Zhu S, Zhu Y, Gao X, Mo T, Zhu Y, Li Y (2013) Production of bioadditives from glycerol
esterification over zirconia supported heteropolyacids. Bioresour Technol 130:45–51
150. Zhu S, Gao X, Dong F, Zhu Y, Zheng H, Li Y (2013) Design of a highly active silverexchanged phosphotungstic acid catalyst for glycerol esterification with acetic acid. J Catal
306:155–163
Catalytic Conversion of Biomass-Derived Glycerol to Value-Added Chemicals