427
119. Liu T, Myers MC, Yu JQ (2017) Copper‐catalyzed bromination of C(sp
3
)−H bonds distal to
functional groups. Angew Chem Int Ed 56:306–309
120. Kumar J, Gupta A, Bhadra S (2019) PdII-catalyzed methoxylation of C(sp
3
)–H bonds adjacent to benzoxazoles and benzothiazoles. Org Biomol Chem 17:3314–3318
121. Wei Y, Deb I, Yoshikai N (2012) Palladium-catalyzed aerobic oxidative cyclization of N-aryl
imines: Indole synthesis from anilines and ketones. J Am Chem Soc 134:9098–9101
122. Shi Z, Suri M, Glorius F (2013) Aerobic synthesis of pyrroles and dihydropyrroles from
imines: Palladium(II)‐catalyzed intramolecular C–H dehydrogenative cyclization. Angew
Chem Int Ed 52:4892–4896
123. Gupta A, Rahaman A, Bhadra S (2019) Direct α-chalcogenation of aliphatic carboxylic acid
equivalents. Org Lett 21:6164–6168
124. Hirano M, Fukumoto Y, Matsubara N, Chatani N (2018) A cationic iridium-catalyzed
C(sp
3 )–H silylation of 2-alkyl-1,3-azoles at the α-position in the 2-alkyl group leading to
2-(1-silylalkyl)-1,3-azoles. Chem Lett 47:385–388
125. Dohi T, Takenaga N, Goto A, Maruyama A, Kita Y (2007) Direct lactone formation by using
hypervalent iodine(III) reagents with KBr viaselective C−H abstraction protocol. Org Lett
9:3129–3132
126. Liu H, Feng W, Kee CW, Zhao Y, Leow D, Pan Y, Tan CH (2010) Organic dye photocatalyzed
α-oxyamination through irradiation with visible light. Green Chem 12:953–956
127. Koike T, Yasu Y, Akita M (2012) Visible-light-driven oxidation of 1,3-dicarbonyl compounds
via catalytic disproportionation of TEMPO by photoredox catalysis. Chem Lett 41:999–1001
128. Im H, Kang D, Choi S, Shin S, Hong S (2018) Visible-light-induced C–O bond formation for
the construction of five- and six-membered cyclic ethers and lactones. Org Lett 20:7437–7441
129. Gonçalves CR, Lemmerer M, Teskey CJ, Adler P, Kaiser D, Maryasin B, González L,
Maulide N (2019) Unified approach to the chemoselective α-functionalization of amides with
heteroatom nucleophiles. J Am Chem Soc 141:18437–18443
C(sp
3
)–H Bond Hetero-functionalization of Aliphatic Carboxylic Acid Equivalents…
119. Liu T, Myers MC, Yu JQ (2017) Copper‐catalyzed bromination of C(sp
3
)−H bonds distal to
functional groups. Angew Chem Int Ed 56:306–309
120. Kumar J, Gupta A, Bhadra S (2019) PdII-catalyzed methoxylation of C(sp
3
)–H bonds adjacent to benzoxazoles and benzothiazoles. Org Biomol Chem 17:3314–3318
121. Wei Y, Deb I, Yoshikai N (2012) Palladium-catalyzed aerobic oxidative cyclization of N-aryl
imines: Indole synthesis from anilines and ketones. J Am Chem Soc 134:9098–9101
122. Shi Z, Suri M, Glorius F (2013) Aerobic synthesis of pyrroles and dihydropyrroles from
imines: Palladium(II)‐catalyzed intramolecular C–H dehydrogenative cyclization. Angew
Chem Int Ed 52:4892–4896
123. Gupta A, Rahaman A, Bhadra S (2019) Direct α-chalcogenation of aliphatic carboxylic acid
equivalents. Org Lett 21:6164–6168
124. Hirano M, Fukumoto Y, Matsubara N, Chatani N (2018) A cationic iridium-catalyzed
C(sp
3 )–H silylation of 2-alkyl-1,3-azoles at the α-position in the 2-alkyl group leading to
2-(1-silylalkyl)-1,3-azoles. Chem Lett 47:385–388
125. Dohi T, Takenaga N, Goto A, Maruyama A, Kita Y (2007) Direct lactone formation by using
hypervalent iodine(III) reagents with KBr viaselective C−H abstraction protocol. Org Lett
9:3129–3132
126. Liu H, Feng W, Kee CW, Zhao Y, Leow D, Pan Y, Tan CH (2010) Organic dye photocatalyzed
α-oxyamination through irradiation with visible light. Green Chem 12:953–956
127. Koike T, Yasu Y, Akita M (2012) Visible-light-driven oxidation of 1,3-dicarbonyl compounds
via catalytic disproportionation of TEMPO by photoredox catalysis. Chem Lett 41:999–1001
128. Im H, Kang D, Choi S, Shin S, Hong S (2018) Visible-light-induced C–O bond formation for
the construction of five- and six-membered cyclic ethers and lactones. Org Lett 20:7437–7441
129. Gonçalves CR, Lemmerer M, Teskey CJ, Adler P, Kaiser D, Maryasin B, González L,
Maulide N (2019) Unified approach to the chemoselective α-functionalization of amides with
heteroatom nucleophiles. J Am Chem Soc 141:18437–18443
C(sp
3
)–H Bond Hetero-functionalization of Aliphatic Carboxylic Acid Equivalents…