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(2019) N,N,O pincer ligand with a deprotonatable site that promotes redox-leveling, high Mn
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250. Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS (2012) Cobalt analogs of
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Structure and phase transitions of the hydroxides. Electrochim Acta 9(3):275–280
253. Benson P, Briggs GWD, Wynne-Jones WFK (1964) The cobalt hydroxide electrode—II.
Electrochemical behaviour. Electrochim Acta 9(3):281–288
254. Kanan MW, Nocera DG (2008) In situ formation of an oxygen-evolving catalyst in neutral
water containing phosphate and Co2+. Science 321(5892):1072–1075
255. Surendranath Y, Dinca M, Nocera DG (2009) Electrolyte-dependent electrosynthesis and
activity of cobalt-based water oxidation catalysts. J Am Chem Soc 131(7):2615–2620
256. Wang L-P, Van Voorhis T (2011) Direct-coupling O2 bond forming a pathway in cobalt oxide
water oxidation catalysts. J Phys Chem Lett 2(17):2200–2204
257. Gimbert-Surinach C, Moonshiram D, Francas L, Planas N, Bernales V, Bozoglian F, Guda A,
Mognon L, Lopez I, Hoque MA, Gagliardi L, Cramer CJ, Llobet A (2016) Structural and
spectroscopic characterization of reaction intermediates involved in a dinuclear co-Hbpp water
oxidation catalyst. J Am Chem Soc 138(47):15291–15294
258. Barnett SM, Goldberg KI, Mayer JM (2012) A soluble copper-bipyridine water-oxidation
electrocatalyst. Nat Chem 4(6):498–502
259. Zhang MT, Chen Z, Kang P, Meyer TJ (2013) Electrocatalytic water oxidation with a copper
(II) polypeptide complex. J Am Chem Soc 135(6):2048–2051
260. Chen F, Wang N, Lei H, Guo D, Liu H, Zhang Z, Zhang W, Lai W, Cao R (2017)
Electrocatalytic water oxidation by a water-soluble copper(II) complex with a copper-bound
carbonate group acting as a potential proton shuttle. Inorg Chem 56(21):13368–13375
The Application of Pincer Ligand in Catalytic Water Splitting
449
GW, Crabtree RH (2016) Catalytic oxygen evolution from manganese complexes with an
oxidation-resistant N,N, O-donor ligand. ChemPlusChem 81(10):1129–1132
249. Lant HMC, Michaelos TK, Sharninghausen LS, Mercado BQ, Crabtree RH, Brudvig GW
(2019) N,N,O pincer ligand with a deprotonatable site that promotes redox-leveling, high Mn
oxidation states, and a Mn2 O2 dimer competent for catalytic oxygen evolution. Eur J Inorg
Chem 2019(15):2115–2123
250. Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS (2012) Cobalt analogs of
Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability
to achieve electrocatalytic O2 evolution. Chem Sci 3(10)
251. El Wakkad SES, Hickling A (1950) The anodic behaviour of metals. Part VI.—cobalt. Trans
Faraday Soc 46:820
252. Benson P, Briggs GWD, Wynne-Jones WFK (1964) The cobalt hydroxide electrode—I.
Structure and phase transitions of the hydroxides. Electrochim Acta 9(3):275–280
253. Benson P, Briggs GWD, Wynne-Jones WFK (1964) The cobalt hydroxide electrode—II.
Electrochemical behaviour. Electrochim Acta 9(3):281–288
254. Kanan MW, Nocera DG (2008) In situ formation of an oxygen-evolving catalyst in neutral
water containing phosphate and Co2+. Science 321(5892):1072–1075
255. Surendranath Y, Dinca M, Nocera DG (2009) Electrolyte-dependent electrosynthesis and
activity of cobalt-based water oxidation catalysts. J Am Chem Soc 131(7):2615–2620
256. Wang L-P, Van Voorhis T (2011) Direct-coupling O2 bond forming a pathway in cobalt oxide
water oxidation catalysts. J Phys Chem Lett 2(17):2200–2204
257. Gimbert-Surinach C, Moonshiram D, Francas L, Planas N, Bernales V, Bozoglian F, Guda A,
Mognon L, Lopez I, Hoque MA, Gagliardi L, Cramer CJ, Llobet A (2016) Structural and
spectroscopic characterization of reaction intermediates involved in a dinuclear co-Hbpp water
oxidation catalyst. J Am Chem Soc 138(47):15291–15294
258. Barnett SM, Goldberg KI, Mayer JM (2012) A soluble copper-bipyridine water-oxidation
electrocatalyst. Nat Chem 4(6):498–502
259. Zhang MT, Chen Z, Kang P, Meyer TJ (2013) Electrocatalytic water oxidation with a copper
(II) polypeptide complex. J Am Chem Soc 135(6):2048–2051
260. Chen F, Wang N, Lei H, Guo D, Liu H, Zhang Z, Zhang W, Lai W, Cao R (2017)
Electrocatalytic water oxidation by a water-soluble copper(II) complex with a copper-bound
carbonate group acting as a potential proton shuttle. Inorg Chem 56(21):13368–13375
The Application of Pincer Ligand in Catalytic Water Splitting
449