230. Singh A, Spiccia L (2013) Water oxidation catalysts based on abundant 1st row transition
metals. Coord Chem Rev 257(17–18):2607–2622
231. Su XJ, Zheng C, Hu QQ, Du HY, Liao RZ, Zhang MT (2018) Bimetallic cooperative effect on
O-O bond formation: copper polypyridyl complexes as water oxidation catalyst. Dalton Trans
47(26):8670–8675
232. Su X-J, Gao M, Jiao L, Liao R-Z, Siegbahn PEM, Cheng J-P, Zhang M-T (2015)
Electrocatalytic water oxidation by a dinuclear copper complex in a neutral aqueous solution.
Angew Chem 127(16):4991–4996
233. Du HY, Chen SC, Su XJ, Jiao L, Zhang MT (2018) Redox-active ligand assisted multielectron
catalysis: a case of Co(III) complex as water oxidation catalyst. J Am Chem Soc 140
(4):1557–1565
234. Karkas MD, Akermark B (2016) Water oxidation using earth-abundant transition metal
catalysts: opportunities and challenges. Dalton Trans 45(37):14421–14461
235. Limburg J, Vrettos JS, Liable-Sands LM, Rheingold AL, Crabtree RH, Brudvig GW (1999) A
functional model for O-O bond formation by the O2-evolving complex in photosystem
II. Science 283(5407):1524–1527
236. Limburg J, Vrettos JS, Chen H, de Paula JC, Crabtree RH, Brudvig GW (2001) Characterization of the O2-evolving reaction catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)]
(NO3)3(terpy ¼ 2,2
0 :6,2
0 ‘-Terpyridine). J Am Chem Soc 123(3):423–430
237. Chen H, Tagore R, Olack G, Vrettos JS, Weng TC, Penner-Hahn J, Crabtree RH, Brudvig GW
(2007) Speciation of the catalytic oxygen evolution system: [MnIII/IV2(mu-O)2(terpy)2
(H2O)2](NO3)3 + HSO5. Inorg Chem 46(1):34–43
238. Tagore R, Crabtree RH, Brudvig GW (2008) Oxygen evolution catalysis by a dimanganese
complex and its relation to photosynthetic water oxidation. Inorg Chem 47(6):1815–1823
239. Tagore R, Chen H, Zhang H, Crabtree RH, Brudvig GW (2007) Homogenous water oxidation
by a Di-mu-Oxo dimanganese complex in the presence of Ce. Inorg Chim Acta 360
(9):2983–2989
240. Kurz P, Berggren G, Anderlund MF, Styring S (2007) Oxygen evolving reactions catalysed by
synthetic manganese complexes: a systematic screening. Dalton Trans 38:4258–4261
241. Baffert C, Romain S, Richardot A, Lepretre JC, Lefebvre B, Deronzier A, Collomb MN (2005)
Electrochemical and chemical formation of [Mn4(IV)O5(terpy)4(H2O)2]6+, in relation with
the photosystem II oxygen-evolving center model [Mn2(III,IV)O2(terpy)2(H2O)2]3+. J Am
Chem Soc 127(39):13694–13704
242. Yagi M, Narita K (2004) Catalytic O2 evolution from water induced by adsorption of [(OH2)
(terpy)Mn(mu-O)2Mn(terpy)(OH2)]3+ complex onto clay compounds. J Am Chem Soc 126
(26):8084–8085
243. Chen H, Faller JW, Crabtree RH, Brudvig GW (2004) Dimer-of-dimers model for the oxygenevolving complex of photosystem II. Synthesis and properties of [MnIV4O5(terpy)4(H2O)2]
(ClO4)6. J Am Chem Soc 126(23):7345–7349
244. Chen H, Collomb MN, Duboc C, Blondin G, Riviere E, Faller JW, Crabtree RH, Brudvig GW
(2005) New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygenevolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn
(IV). Inorg Chem 44(25):9567–9573
245. Gao Y, Crabtree RH, Brudvig GW (2012) Water oxidation catalyzed by the tetranuclear Mn
complex [Mn(IV)4O5(terpy)4(H2O)2](ClO4)6. Inorg Chem 51(7):4043–4050
246. Chen H, Tagore R, Das S, Incarvito C, Faller JW, Crabtree RH, Brudvig GW (2005) General
synthesis of di-mu-oxo dimanganese complexes as functional models for the oxygen evolving
complex of photosystem II. Inorg Chem 44(21):7661–7670
247. Yamazaki H, Igarashi S, Nagata T, Yagi M (2012) Substituent effects on core structures and
heterogeneous catalytic activities of Mn(III)(mu-O)2Mn(IV) dimers with 2,2
0 :6
0 ,200 -terpyridine derivative ligands for water oxidation. Inorg Chem 51(3):1530–1539
448
H.-T. Zhang and M.-T. Zhang
metals. Coord Chem Rev 257(17–18):2607–2622
231. Su XJ, Zheng C, Hu QQ, Du HY, Liao RZ, Zhang MT (2018) Bimetallic cooperative effect on
O-O bond formation: copper polypyridyl complexes as water oxidation catalyst. Dalton Trans
47(26):8670–8675
232. Su X-J, Gao M, Jiao L, Liao R-Z, Siegbahn PEM, Cheng J-P, Zhang M-T (2015)
Electrocatalytic water oxidation by a dinuclear copper complex in a neutral aqueous solution.
Angew Chem 127(16):4991–4996
233. Du HY, Chen SC, Su XJ, Jiao L, Zhang MT (2018) Redox-active ligand assisted multielectron
catalysis: a case of Co(III) complex as water oxidation catalyst. J Am Chem Soc 140
(4):1557–1565
234. Karkas MD, Akermark B (2016) Water oxidation using earth-abundant transition metal
catalysts: opportunities and challenges. Dalton Trans 45(37):14421–14461
235. Limburg J, Vrettos JS, Liable-Sands LM, Rheingold AL, Crabtree RH, Brudvig GW (1999) A
functional model for O-O bond formation by the O2-evolving complex in photosystem
II. Science 283(5407):1524–1527
236. Limburg J, Vrettos JS, Chen H, de Paula JC, Crabtree RH, Brudvig GW (2001) Characterization of the O2-evolving reaction catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)]
(NO3)3(terpy ¼ 2,2
0 :6,2
0 ‘-Terpyridine). J Am Chem Soc 123(3):423–430
237. Chen H, Tagore R, Olack G, Vrettos JS, Weng TC, Penner-Hahn J, Crabtree RH, Brudvig GW
(2007) Speciation of the catalytic oxygen evolution system: [MnIII/IV2(mu-O)2(terpy)2
(H2O)2](NO3)3 + HSO5. Inorg Chem 46(1):34–43
238. Tagore R, Crabtree RH, Brudvig GW (2008) Oxygen evolution catalysis by a dimanganese
complex and its relation to photosynthetic water oxidation. Inorg Chem 47(6):1815–1823
239. Tagore R, Chen H, Zhang H, Crabtree RH, Brudvig GW (2007) Homogenous water oxidation
by a Di-mu-Oxo dimanganese complex in the presence of Ce. Inorg Chim Acta 360
(9):2983–2989
240. Kurz P, Berggren G, Anderlund MF, Styring S (2007) Oxygen evolving reactions catalysed by
synthetic manganese complexes: a systematic screening. Dalton Trans 38:4258–4261
241. Baffert C, Romain S, Richardot A, Lepretre JC, Lefebvre B, Deronzier A, Collomb MN (2005)
Electrochemical and chemical formation of [Mn4(IV)O5(terpy)4(H2O)2]6+, in relation with
the photosystem II oxygen-evolving center model [Mn2(III,IV)O2(terpy)2(H2O)2]3+. J Am
Chem Soc 127(39):13694–13704
242. Yagi M, Narita K (2004) Catalytic O2 evolution from water induced by adsorption of [(OH2)
(terpy)Mn(mu-O)2Mn(terpy)(OH2)]3+ complex onto clay compounds. J Am Chem Soc 126
(26):8084–8085
243. Chen H, Faller JW, Crabtree RH, Brudvig GW (2004) Dimer-of-dimers model for the oxygenevolving complex of photosystem II. Synthesis and properties of [MnIV4O5(terpy)4(H2O)2]
(ClO4)6. J Am Chem Soc 126(23):7345–7349
244. Chen H, Collomb MN, Duboc C, Blondin G, Riviere E, Faller JW, Crabtree RH, Brudvig GW
(2005) New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygenevolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn
(IV). Inorg Chem 44(25):9567–9573
245. Gao Y, Crabtree RH, Brudvig GW (2012) Water oxidation catalyzed by the tetranuclear Mn
complex [Mn(IV)4O5(terpy)4(H2O)2](ClO4)6. Inorg Chem 51(7):4043–4050
246. Chen H, Tagore R, Das S, Incarvito C, Faller JW, Crabtree RH, Brudvig GW (2005) General
synthesis of di-mu-oxo dimanganese complexes as functional models for the oxygen evolving
complex of photosystem II. Inorg Chem 44(21):7661–7670
247. Yamazaki H, Igarashi S, Nagata T, Yagi M (2012) Substituent effects on core structures and
heterogeneous catalytic activities of Mn(III)(mu-O)2Mn(IV) dimers with 2,2
0 :6
0 ,200 -terpyridine derivative ligands for water oxidation. Inorg Chem 51(3):1530–1539
448
H.-T. Zhang and M.-T. Zhang