193. Polyansky DE, Muckerman JT, Rochford J, Zong R, Thummel RP, Fujita E (2011) Water
oxidation by a mononuclear ruthenium catalyst: characterization of the intermediates. J Am
Chem Soc 133(37):14649–14665
194. Badiei YM, Polyansky DE, Muckerman JT, Szalda DJ, Haberdar R, Zong R, Thummel RP,
Fujita E (2013) Water oxidation with mononuclear ruthenium(II) polypyridine complexes
involving a direct Ru(IV) horizontal lineO pathway in neutral and alkaline media. Inorg Chem
52(15):8845–8850
195. Wasylenko DJ, Ganesamoorthy C, Koivisto BD, Henderson MA, Berlinguette CP (2010)
Insight into water oxidation by mononuclear polypyridyl Ru catalysts. Inorg Chem 49
(5):2202–2209
196. Masaoka S, Sakai K (2009) Clear evidence showing the robustness of a highly active oxygenevolving mononuclear ruthenium complex with an aqua ligand. Chem Lett 38(2):182–183
197. Wasylenko DJ, Ganesamoorthy C, Henderson MA, Koivisto BD, Osthoff HD, Berlinguette
CP (2010) Electronic modification of the [Ru(II)(tpy)(bpy)(OH(2))](2+) scaffold: effects on
catalytic water oxidation. J Am Chem Soc 132(45):16094–16106
198. Wasylenko DJ, Ganesamoorthy C, Henderson MA, Berlinguette CP (2011) Unraveling the
roles of the acid medium, experimental probes, and terminal oxidant, (NH4)2[Ce(NO3)6], in
the study of a homogeneous water oxidation catalyst. Inorg Chem 50(8):3662–3672
199. Yoshida M, Masaoka S, Abe J, Sakai K (2010) Catalysis of mononuclear aquaruthenium
complexes in oxygen evolution from water: a new radical coupling path using hydroxocerium
(IV) species. Chem Asian J 5(11):2369–2378
200. Ikeda-Ohno A, Tsushima S, Hennig C, Yaita T, Bernhard G (2012) Dinuclear complexes of
tetravalent cerium in an aqueous perchloric acid solution. Dalton Trans 41(24):7190–7192
201. Concepcion JJ, Jurss JW, Norris MR, Chen Z, Templeton JL, Meyer TJ (2010) Catalytic water
oxidation by single-site ruthenium catalysts. Inorg Chem 49(4):1277–1279
202. Chen Z, Concepcion JJ, Meyer TJ (2011) Rapid catalytic water oxidation by a single site, Ru
carbene catalyst. Dalton Trans 40(15):3789–3792
203. Ashford DL, Stewart DJ, Glasson CR, Binstead RA, Harrison DP, Norris MR, Concepcion JJ,
Fang Z, Templeton JL, Meyer TJ (2012) An amide-linked chromophore-catalyst assembly for
water oxidation. Inorg Chem 51(12):6428–6430
204. Concepcion JJ, Jurss JW, Hoertz PG, Meyer TJ (2009) Catalytic and surface-electrocatalytic
water oxidation by redox mediator-catalyst assemblies. Angew Chem Int Ed Engl 48
(50):9473–9476
205. Ashford DL, Song W, Concepcion JJ, Glasson CR, Brennaman MK, Norris MR, Fang Z,
Templeton JL, Meyer TJ (2012) Photoinduced electron transfer in a chromophore-catalyst
assembly anchored to TiO2. J Am Chem Soc 134(46):19189–19198
206. Ashford DL, Lapides AM, Vannucci AK, Hanson K, Torelli DA, Harrison DP, Templeton JL,
Meyer TJ (2014) Water oxidation by an electropolymerized catalyst on derivatized
mesoporous metal oxide electrodes. J Am Chem Soc 136(18):6578–6581
207. Chen Z, Concepcion JJ, Jurss JW, Meyer TJ (2009) Single-site, catalytic water oxidation on
oxide surfaces. J Am Chem Soc 131(43):15580–15581
208. Chen Z, Concepcion JJ, Hull JF, Hoertz PG, Meyer TJ (2010) Catalytic water oxidation on
derivatized nanoITO. Dalton Trans 39(30):6950–6952
209. Chen Z, Concepcion JJ, Luo H, Hull JF, Paul A, Meyer TJ (2010) Nonaqueous catalytic water
oxidation. J Am Chem Soc 132(50):17670–17673
210. Hoertz PG, Chen Z, Kent CA, Meyer TJ (2010) Application of high surface area tin-doped
indium oxide nanoparticle films as transparent conducting electrodes. Inorg Chem 49
(18):8179–8181
211. Chen Z, Concepcion JJ, Hu X, Yang W, Hoertz PG, Meyer TJ (2010) Concerted O atomproton transfer in the O-O bond forming step in water oxidation. Proc Natl Acad Sci U S A 107
(16):7225–7229
446
H.-T. Zhang and M.-T. Zhang
oxidation by a mononuclear ruthenium catalyst: characterization of the intermediates. J Am
Chem Soc 133(37):14649–14665
194. Badiei YM, Polyansky DE, Muckerman JT, Szalda DJ, Haberdar R, Zong R, Thummel RP,
Fujita E (2013) Water oxidation with mononuclear ruthenium(II) polypyridine complexes
involving a direct Ru(IV) horizontal lineO pathway in neutral and alkaline media. Inorg Chem
52(15):8845–8850
195. Wasylenko DJ, Ganesamoorthy C, Koivisto BD, Henderson MA, Berlinguette CP (2010)
Insight into water oxidation by mononuclear polypyridyl Ru catalysts. Inorg Chem 49
(5):2202–2209
196. Masaoka S, Sakai K (2009) Clear evidence showing the robustness of a highly active oxygenevolving mononuclear ruthenium complex with an aqua ligand. Chem Lett 38(2):182–183
197. Wasylenko DJ, Ganesamoorthy C, Henderson MA, Koivisto BD, Osthoff HD, Berlinguette
CP (2010) Electronic modification of the [Ru(II)(tpy)(bpy)(OH(2))](2+) scaffold: effects on
catalytic water oxidation. J Am Chem Soc 132(45):16094–16106
198. Wasylenko DJ, Ganesamoorthy C, Henderson MA, Berlinguette CP (2011) Unraveling the
roles of the acid medium, experimental probes, and terminal oxidant, (NH4)2[Ce(NO3)6], in
the study of a homogeneous water oxidation catalyst. Inorg Chem 50(8):3662–3672
199. Yoshida M, Masaoka S, Abe J, Sakai K (2010) Catalysis of mononuclear aquaruthenium
complexes in oxygen evolution from water: a new radical coupling path using hydroxocerium
(IV) species. Chem Asian J 5(11):2369–2378
200. Ikeda-Ohno A, Tsushima S, Hennig C, Yaita T, Bernhard G (2012) Dinuclear complexes of
tetravalent cerium in an aqueous perchloric acid solution. Dalton Trans 41(24):7190–7192
201. Concepcion JJ, Jurss JW, Norris MR, Chen Z, Templeton JL, Meyer TJ (2010) Catalytic water
oxidation by single-site ruthenium catalysts. Inorg Chem 49(4):1277–1279
202. Chen Z, Concepcion JJ, Meyer TJ (2011) Rapid catalytic water oxidation by a single site, Ru
carbene catalyst. Dalton Trans 40(15):3789–3792
203. Ashford DL, Stewart DJ, Glasson CR, Binstead RA, Harrison DP, Norris MR, Concepcion JJ,
Fang Z, Templeton JL, Meyer TJ (2012) An amide-linked chromophore-catalyst assembly for
water oxidation. Inorg Chem 51(12):6428–6430
204. Concepcion JJ, Jurss JW, Hoertz PG, Meyer TJ (2009) Catalytic and surface-electrocatalytic
water oxidation by redox mediator-catalyst assemblies. Angew Chem Int Ed Engl 48
(50):9473–9476
205. Ashford DL, Song W, Concepcion JJ, Glasson CR, Brennaman MK, Norris MR, Fang Z,
Templeton JL, Meyer TJ (2012) Photoinduced electron transfer in a chromophore-catalyst
assembly anchored to TiO2. J Am Chem Soc 134(46):19189–19198
206. Ashford DL, Lapides AM, Vannucci AK, Hanson K, Torelli DA, Harrison DP, Templeton JL,
Meyer TJ (2014) Water oxidation by an electropolymerized catalyst on derivatized
mesoporous metal oxide electrodes. J Am Chem Soc 136(18):6578–6581
207. Chen Z, Concepcion JJ, Jurss JW, Meyer TJ (2009) Single-site, catalytic water oxidation on
oxide surfaces. J Am Chem Soc 131(43):15580–15581
208. Chen Z, Concepcion JJ, Hull JF, Hoertz PG, Meyer TJ (2010) Catalytic water oxidation on
derivatized nanoITO. Dalton Trans 39(30):6950–6952
209. Chen Z, Concepcion JJ, Luo H, Hull JF, Paul A, Meyer TJ (2010) Nonaqueous catalytic water
oxidation. J Am Chem Soc 132(50):17670–17673
210. Hoertz PG, Chen Z, Kent CA, Meyer TJ (2010) Application of high surface area tin-doped
indium oxide nanoparticle films as transparent conducting electrodes. Inorg Chem 49
(18):8179–8181
211. Chen Z, Concepcion JJ, Hu X, Yang W, Hoertz PG, Meyer TJ (2010) Concerted O atomproton transfer in the O-O bond forming step in water oxidation. Proc Natl Acad Sci U S A 107
(16):7225–7229
446
H.-T. Zhang and M.-T. Zhang