reacts with oxygen transfer reagent (Oxone) to form an active intermediate of
Mn
V Mn
V
¼O; Then water molecules attack the intermediate nucleophilically and
O-O bond is formed, which are further oxidized to release oxygen; Or Mn
V Mn
V
¼O
species reacts with another HSO 5 (Oxone) molecule to produce oxygen.
In 2012, Llobet and Stahl synthesized Co-based compounds O137–138 (Fig. 47)
containing peroxide bridge [250], mimicking the previously studied binuclear
Ru-Hbpp catalyst O8. Co-Pi has been found to be a stable and efficient heterogeneous catalyst for water oxidation [251–255]. Calculation supported that the key
Fig. 45 Structures of [(H 2 O)(NNN)Mn
III
(μ-O) 2 Mn
IV (NNN)(OH 2 )]
3+ -type catalysts O117–133
The Application of Pincer Ligand in Catalytic Water Splitting
433
Mn
V Mn
V
¼O; Then water molecules attack the intermediate nucleophilically and
O-O bond is formed, which are further oxidized to release oxygen; Or Mn
V Mn
V
¼O
species reacts with another HSO 5 (Oxone) molecule to produce oxygen.
In 2012, Llobet and Stahl synthesized Co-based compounds O137–138 (Fig. 47)
containing peroxide bridge [250], mimicking the previously studied binuclear
Ru-Hbpp catalyst O8. Co-Pi has been found to be a stable and efficient heterogeneous catalyst for water oxidation [251–255]. Calculation supported that the key
Fig. 45 Structures of [(H 2 O)(NNN)Mn
III
(μ-O) 2 Mn
IV (NNN)(OH 2 )]
3+ -type catalysts O117–133
The Application of Pincer Ligand in Catalytic Water Splitting
433